Practical considerations for the segmented-flow analysis of nitrate and ammonium in seawater and the avoidance of matrix effects     

Tae Keun Rho  Stephen Coverly  Eun-Soo Kim  Dong-Jin Kang  Sung-Hyun Kahng  Tae-Hee Na  Sung-Rok Cho  Jung-Moo Lee  Cho-Rong Moon 《Ocean Science Journal》2015,50(4):709-720

In this study we describe measures taken in our laboratory to improve the long-term precision of nitrate and ammonia analysis in seawater using a microflow segmented-flow analyzer. To improve the nitrate reduction efficiency using a flow-through open tube cadmium reactor (OTCR), we compared alternative buffer formulations and regeneration procedures for an OTCR. We improved long-term stability for nitrate with a modified flow scheme and color reagent formulation and for ammonia by isolating samples from the ambient air and purifying the air used for bubble segmentation. We demonstrate the importance of taking into consideration the residual nutrient content of the artificial seawater used for the preparation of calibration standards. We describe how an operating procedure to eliminate errors from that source as well as from the refractive index of the matrix itself can be modified to include the minimization of dynamic refractive index effects resulting from differences between the matrix of the samples, the calibrants, and the wash solution. We compare the data for long-term measurements of certified reference material under two different conditions, using ultrapure water (UPW) and artificial seawater (ASW) for the sampler wash.  相似文献   

Assessment of tributyltin contamination in a shipyard area using a mussel transplantation approach     

Kim NS  Shim WJ  Yim UH  Ha SY  Park PS 《Marine pollution bulletin》2008,57(6-12):883-888

Mussels (Mytilus galloprovincialis) were transplanted to seven stations around a large shipyard for 126 days to evaluate tributyltin (TBT) contamination. Although the application of TBT-based paints to ships is totally banned in Korea, butyltin compounds were found to accumulate in mussels following transplantation. Concentrations of TBT and total butyltins in transplanted mussels near the shipyard were in the range of 40-350 ng Sn/g and 74-530 ng Sn/g on a dry weight basis, respectively. Obviously, low TBT concentrations (6.0-53 ng Sn/gdw) were determined in mussels at four stations outside the shipyard. A negative gradient of TBT concentrations and TBT portion to total butyltin concentrations were found in both the surface water and transplanted mussels according to distance from the shipyard. In addition, TBT concentrations in surface water and transplanted mussels showed significant correlation (r(2) = 0.71; p < 0.001). These results indicate that the shipyard still releases fresh TBT into surrounding waters even after TBT regulation in Korea, and mussel transplantation is useful in evaluating TBT contamination in shipyard area.  相似文献   

Dolomitization of Carbonate Periplatform Deposit,Machari Formation (Middle to Late Cambrian),Korea     

Gong Soo 《中国地质大学学报(英文版)》2000,11(2)

The petrography, the geochemistry and the burial history all constrain the origin and modification history of dolomites in an ancient periplatform carbonate slope deposit,the Machari Formation (late Miclclle to early Late Cambrian),Korea. The formation is mainly composed of rhythmic bedding. laminated to bedded lime mudstone alternating with argillaceous lime mudstone. The rhythmic bedding is a product of the deposition of offshore periplatform ooze and hemipelagic clay on a periplatform slope. This formation also shows minor and intermittent influx of other lithofacies including the bioclastic-peloidal packstone, peloidal wackestone, and intraclasts deposited as turbidites. Five types of dolomite occur in the Machari Formation, whose occurrence.texture and geochemistry provide an insight into origin and modification history.  相似文献   

Geology, Mineralogy and Geochemistry of Carbonate Replacement-Type Lead-Zinc-Silver Deposits in Janggun Mine, Republic of Korea     

Lee Hyun Koo Lee Chan Hee Yoo Bong Cheal Lee Jong Chang Department of Geology  Chungnam National University  Taejon  Korea 《中国地质大学学报(英文版)》2000,11(2)

INTRODUCTIONThe Janggun mine,Republic of Korea,is located in thesoutheast of the Seoul,about latitude36°5 1′N and longitude12 9°0 4′E. In this mine area is situated the Bonghwa m ineral-ized zone of the Taebaegsan mining district,Korea.The geo-logic setting of the region was described as the Samgeum riQuadrangle(Kim et al.,196 2 ) .The general and local geolo-gy near the mine area have been studied by L ee (196 7) ,Hwang and Reedman(1975 ) .This mine consists of four min-eral de…  相似文献   

Simulation of the 1953 storm surge in the North Sea     

Byung Ho Choi  Kyeong Ok Kim  Jin-Hee Yuk  Han Soo Lee 《Ocean Dynamics》2018,68(12):1759-1777

The 1953 North Sea floods, the Big Flood, was one of the worst natural disasters in Europe in modern times and is probably one of the most studied severe coastal floods. Several factors led to the devastating storm surge along the southern North Sea coast in combination of strong and sustained northerly winds, invert barometric effect, high spring tide, and an accumulation of the large surge in the Strait of Dover. However, the storm waves and their roles during the 1953 North Sea storm surge are not well investigated. Therefore, the effect of wave setup due to breaking waves in the storm surge processes is investigated through numerical experiments. A coupled process-based tide-wave-surge model was used to investigate and simulate the storm surge in the North Sea during January 31–February 1, 1953 and validated by comparing with historical water level records at tide gauges and wave observations at light vessels in the North Sea. Meteorological forcing inputs for the period, January 27–February 3, 1953 are reproduced from ERA-20C reanalysis data with a constant correction factor for winds. From the simulation results, it is found that, in addition to the high water due to wind setup, wave setup due to breaking waves nearshore play a role of approximately 10% of the storm surge peaks with approximately 0.2 m. The resulting modeling system can be used extensively for the preparedness of the storm surge and wave of extreme condition, and usual barotropic forecast.  相似文献   

Fatigue strength assessment of MARK-III type LNG cargo containment system     

Myung Hyun Kim  Sang Min Lee  Jae Myung Lee  Byung Jae Noh  Wha Soo Kim 《Ocean Engineering》2010,37(14-15):1243-1252

The aim of this paper is to investigate the fatigue strength of the GTT Mark-III type LNG insulation system. The LNG insulation system consists of several composite layers with various connections; plywood, triplex, reinforced polyurethane foam and mastic. Consequently, the LNG insulation system may include mechanical failures such as cracks as well as delaminations within the layers due to sloshing impact loads and fatigue loadings. In addition, these failures may cause a significant decrease of structural integrity. In this study, a series of fatigue tests have been carried out for Mark-III type LNGC insulation systems at room temperature considering the effect of sloshing impact. The load levels have been determined based on the ultimate strength of reinforced polyurethane foam. The aim of the study is to investigate the typical failure characteristics of the MARK-III LNG insulation system and to obtain the S–N data under fatigue loading. A consolidated single S–N curve is obtained based on a systematic finite element procedure. Future use of the S–N data in fatigue analysis requires that the response analysis is carried out using a finite element model with the same mesh density and material properties. This study can be used as a fundamental study for the fatigue assessment of the LNGC insulation system as well as a design guideline.  相似文献   

Numerical analysis of effects of tidal variations on storm surges and waves   总被引：2，自引：0，他引：2  

Soo Youl Kim  Tomohiro Yasuda  Hajime Mase 《Applied Ocean Research》2008,30(4):311-322

This study examines the effects of tides on surges, wave setups and waves, in terms of tidal amplitudes and phases, by using a coupled numerical model of Surge, WAve and Tide (called as SuWAT). The SuWAT model, composed of depth integrated nonlinear shallow water equations and Simulating WAves Nearshore (SWAN) model, is able to simultaneously run with an arbitrary number of nested domains by using the Message Passing Interface. The results for an idealized case indicate that surge and wave setup are increased in the phase of low water and decreased in the high water phase; on the other hand, waves change in a reverse manner. Such changes are enhanced by large tidal variations. The conventional method (e.g., surge plus tide independently) has the possibility of overestimation for the total water level. The hindcast results for Typhoon Ewiniar in 2006 show that the run with tides is more accurate 10% than that without tides in coastal areas of Korea. The nested scheme improves the accuracy up to 40% for the prediction of water levels in the simulations. It is shown that the present coupled model, SuWAT, is capable of predicting both water levels and waves under storm events with reasonable accuracy against the observations.  相似文献   

Prediction of surface ocean pCO2 from observations of salinity, temperature and nitrate: The empirical model perspective     

Hyun -Woo Lee  Kitack Lee  Bang -Yong Lee 《Ocean Science Journal》2008,43(4):195-208

This paper evaluates whether a thermodynamic ocean-carbon model can be used to predict the monthly mean global fields of the surface-water partial pressure of CO₂ (pCO_2SEA) from sea surface salinity (SSS), temperature (SST), and/or nitrate (NO₃) concentration using previously published regional total inorganic carbon (C_T) and total alkalinity (A_T) algorithms. The obtained pCO_2SEA values and their amplitudes of seasonal variability are in good agreement with multi-year observations undertaken at the sites of the Bermuda Atlantic Timeseries Study (BATS) (31°50’N, 60°10’W) and the Hawaiian Ocean Time-series (HOT) (22°45’N, 158°00’W). By contrast, the empirical models predicted C_T less accurately at the Kyodo western North Pacific Ocean Time-series (KNOT) site (44°N, 155°E) than at the BATS and HOT sites, resulting in greater uncertainties in pCO_2SEA predictions. Our analysis indicates that the previously published empirical C_T and A_T models provide reasonable predictions of seasonal variations in surface-water pCO_2SEA within the (sub) tropical oceans based on changes in SSS and SST; however, in high-latitude oceans where ocean biology affects C_T to a significant degree, improved C_T algorithms are required to capture the full biological effect on C_T with greater accuracy and in turn improve the accuracy of predictions of pCO_2SEA.  相似文献   

Recent Primary Production and Small Phytoplankton Contribution in the Yellow Sea during the Summer in 2016     

Hyo Keun Jang  Jae Jung Kang  Jae Hyung Lee  Myungjoon Kim  So Hyun Ahn  Jin-Yong Jeong  Mi Sun Yun  In-Seong Han  Sang Heon Lee 《Ocean Science Journal》2018,53(3):509-519

The high nutrient concentration associated with the mixing dynamics of two warm and cold water masses supports high primary production in the Yellow Sea. Although various environmental changes have been reported, no recent information on small phytoplankton contribution to the total primary production as an important indicator for marine ecosystem changes is currently available in the Yellow Sea. The major objective of this study is to determine the small (< 2 μm) phytoplankton contribution to the total primary production in the Yellow Sea during August, 2016. In this study, we found relatively lower chlorophyll a concentrations in the water column than those previously reported in the central waters of the Yellow Sea. Moreover, the overall contribution of small phytoplankton (53.1%) to the total chlorophyll a concentration was considerably higher in this study than that (10.7%) observed previously. Based on the N/P ratio (67.6 ± 36.6) observed in this study, which is significantly higher than the Redfield ratio (16), we believe that phytoplankton experienced P-limiting conditions during the study period. The average daily carbon uptake rate of total phytoplankton in this study was 291.1 mg C m^-2 d^-1 (± 165.0 mg C m^-2 d^-1) and the rate of small phytoplankton was 205.7 mg C m^-2 d^-1 (± 116.0 mg C m^-2 d^-1) which is 71.9% (± 8.8%) of the total daily carbon uptake rate. This contribution of small phytoplankton observed in this study appears to be higher than that reported previously. Our recent measured primary production is approximately 50% lower than the previous values decades ago. The higher contributions of small phytoplankton to the total chlorophyll a concentration and primary production might be caused by P-limited conditions and this resulted in lower chlorophyll a concentration and total primary production in this study compared to previous studies.  相似文献   

Effects of Temperature and Salinity on the Egg Development and Larval Settlement of Ciona robusta (Ascidiacea,Phlebobranchia, Cionidae)     

Kim  Min Kyung  Kim  Dong Hyun  Park  Ju-un  Kim  Dong Hwan  Yoon  Tae Joong  Kim  Dong Gun  Lee  Yoon  Shin  Sook 《Ocean Science Journal》2019,54(1):97-106

Ocean Science Journal - Ascidians are marine benthic organisms, which attach to the surfaces of both natural and artificial substrates from shallow to deep waters around the world. Invasive...  相似文献