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Inorganic carbon measurements made in the late 1980s suggest that alkalinity in the waters surrounding the Hawaiian Archipelago is elevated relative to the oligotrophic waters of the North Pacific. These observations have been interpreted as evidence for a “halo” of elevated carbonate saturation state produced by the dissolution of highly soluble magnesium calcites and aragonite on the island platform or in the water column surrounding the islands. If present, this “halo” has implications for air–sea carbon dioxide exchange in Hawaiian waters and may impact the response of coral reef communities to the acidification of the surface waters of the global ocean. The purpose of this study was to assess the magnitude and extent of the elevated calcium carbonate saturation state observed on previous expeditions to this region. Transects were conducted near several atolls in the Northwestern Hawaiian Islands from shallow water adjacent to the forereef to the open ocean 15 km from the island. Hydrographic profiles were collected at each station, and discrete water samples were collected for the measurement of carbon system parameters necessary to compute calcium carbonate saturation state. Our data were compared with observations made at the Hawaii Ocean Time-series site at Station ALOHA and with hydrographic data collected on the WOCE lines in the North Pacific around the archipelago. We did not detect a carbonate dissolution halo around the islands. We conclude that the previously observed halo was probably an analytical artifact, or possibly a result of extreme variability in carbon chemistry surrounding the islands.  相似文献   
2.
This paper presents a case history of geotextile-reinforced dry cover placement on a reclaimed clay deposit treated by progressive trenching method. In order to investigate the effects of the cover material's characteristic of ensuring trafficability with respect to bearing failure and ground deformation, two types of covers were considered in pilot tests: a layer of weathered granite soil cover and a layer of weathered granite soil over stiff crushed stone. A number of in-situ plate load tests were conducted for various cover conditions to assess the bearing capacity of the reclaimed deposit and to determine the thickness and material compositions that satisfy the bearing capacity requirement. In full-scale pilot tests for cover placement, field monitoring was carried out for the surface settlement and pore pressure that developed in the reclaimed clay layer. The results of plate-loading tests and monitoring during staged cover placements are discussed and compared using numerical predictions obtained from both finite element analyses and undrained stability analyses. The comparison results showed that the drainage condition of the ground surface facing the dry cover is strongly related to the ground response and stability.  相似文献   
3.
Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2-25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   
4.
Imposex was measured in the rock shell, Thais clavigera, from the coast of the Korean peninsula. Frequency of imposex was 0% at two reference sites, but at 47 out of 61 sites, frequency of imposex was recorded as 100%. The degree of imposex was relatively high at the sites near a harbor and a shipyard. Tributyltin (TBT) and triphenyltin (TPT) concentrations in T. clavigera ranged from 5 to 508 ng/g and from 3 to 2460 ng/g, respectively. A significant positive relationship was found between degree of imposex and organotin concentration, whereas a significant negative relationship was obtained between female-to-male sex ratio and the degree of imposex. During a field transplantation of T. clavigera from a pristine area to a port, TBT and TPT were accumulated in T. clavigera, and imposex was induced. T. clavigera shows considerable potential as a bioindicator species of the adverse effects of TBT and TPT contamination.  相似文献   
5.
We have developed a novel miniature in situ microprofiler (NAFRI BelpI) for coastal and deep-sea studies. The BelpI can carry up to three oxygen microsensors, and it allows for simultaneous replicate measurements in a relatively small area. All functions can be controlled and programmed via a small magnetic bar and three reed switches; this feature facilitates the initial setup both onboard and underwater. The large LCD window shows basic information such as the movement intervals of the linear stage, number of replicate measurements, waiting time between measurements, and the pA from the microsensors. From high-resolution vertical profiles of oxygen in coastal sediment measured using the microsensors, the diffusivity boundary layer thicknesses was determined to be in the range 0.30–0.35 mm. In addition, the time-series measurement of oxygen profiles in permeable sandy sediment showed advective transport of oxygen into pore water by tidal agitation. Two examples of in situ measurement using a BelpI suggest that it can be widely applied to the study of the sediment-water interface.  相似文献   
6.
For water resources management, many studies for investigating flow paths from rainfall to subsurface have been conducted for last half century. A hydrograph separation based on end member mixing was carried out to evaluate the importance of the hydrological pathways providing the main sources of a small granitic watershed, Dorim-cheon, Seoul. An analysis of chloride, oxygen-18 and deuterium isotopes from precipitation and stream water during three storms was conducted with high-resolution data using 129 samples. Stream water, collected in advance of rain event, was assumed as a pre-event water (baseflow) component according to its dry condition and isotopic values compared with the values of different time periods. The contribution from vadose water was ignored due to the thin soil layer covering the study area. Using a two-component mixing model, hydrograph separation of the stream water in Dorim-cheon was conducted based on weighted mean values of rain water and pre-event water component with the high-resolution datasets. As a result of the analysis with water isotopes, contribution of groundwater was dominant during the entire study period (73–74%) except of instant dominance of rainfall at the earliest period. Using chloride as a tracer for hydrograph separation, a significant difference for the amount of pre-event water contribution was identified. This might be caused by the large variation of chloride concentration during the rain event and the end member determination.  相似文献   
7.
The Manus Basin to the northeast of Papua New Guinea is an actively spreading/rifting back-arc basin in the Bismarck Sea located between the inactive Manus-Kilinailau trench on the Pacific-plate side and the active New Britain trench on the Solomon-plate side. Spreading/rifting in the Manus Basin takes place in the last 0.78 Myr or so. We present major and trace elements, and Sr–Nd–Pb isotope compositions of rock samples taken from the South East Rift (SER) at the eastern end of the Manus Basin. The strong enrichment of Pb and LILE (large ion lithophile elements) relative to HFSE (high field strength elements) and REE (rare earth elements) in the SER lava is also quite similar to other island arc lavas, suggesting that substantial amount of subduction components were present in its source mantle. To investigate the origin of the subduction components in SER lavas, we compare the geochemical data of SER lavas to published data from New Britain Arc (NBA) and Tabar–Lihir–Tanga–Feni (TLTF) island chain. The volcanism in NBA is related to presently active subduction of the Solomon slab, whereas the TLTF volcanism is located in the forearc area of New Ireland arc which was formed during a former subduction of the Pacific slab. In other words, the NBA and TLTF lavas were influenced by subduction components from the present and former subduction, respectively. We argue that the subduction components in SER lava were incorporated in the mantle lithosphere during the active arc volcanism on New Ireland because the amount of the subduction component in SER decreases with increasing in distance from New Ireland. On the other hand, no relationships are found with respect to New Britain. The Sr–Nd–Pb isotopes indicate that SER lavas contain little sediment component and less amount of fluid component derived from altered oceanic crust compared to the TLTF lavas. This is probably due to the fact that SER is located in backarc settings in contrast to TLTF which is located in forearc setting with respect to the Pacific slab. Thus it is likely that the sediment was removed from the slab in the forearc and/or arc areas, and therefore little or none was introduced in the backarc mantle, which is the source region for SER magmas at present. Fluid derived from altered oceanic crust also may have made its way into the sub-forearc region more effectively than backare region by shallow dehydration process.  相似文献   
8.
In this study we describe measures taken in our laboratory to improve the long-term precision of nitrate and ammonia analysis in seawater using a microflow segmented-flow analyzer. To improve the nitrate reduction efficiency using a flow-through open tube cadmium reactor (OTCR), we compared alternative buffer formulations and regeneration procedures for an OTCR. We improved long-term stability for nitrate with a modified flow scheme and color reagent formulation and for ammonia by isolating samples from the ambient air and purifying the air used for bubble segmentation. We demonstrate the importance of taking into consideration the residual nutrient content of the artificial seawater used for the preparation of calibration standards. We describe how an operating procedure to eliminate errors from that source as well as from the refractive index of the matrix itself can be modified to include the minimization of dynamic refractive index effects resulting from differences between the matrix of the samples, the calibrants, and the wash solution. We compare the data for long-term measurements of certified reference material under two different conditions, using ultrapure water (UPW) and artificial seawater (ASW) for the sampler wash.  相似文献   
9.
10.
Abstract

Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2–25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   
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