Serpentinization of abyssal peridotites from the MARK area, Mid-Atlantic Ridge: sulfur geochemistry and reaction modeling   总被引：1，自引：0，他引：1  

Jeffrey C. Alt  Wayne C. Shanks III 《Geochimica et cosmochimica acta》2003,67(4):641-653

The opaque mineralogy and the contents and isotope compositions of sulfur in serpentinized peridotites from the MARK (Mid-Atlantic Ridge, Kane Fracture Zone) area were examined to understand the conditions of serpentinization and evaluate this process as a sink for seawater sulfur. The serpentinites contain a sulfur-rich secondary mineral assemblage and have high sulfur contents (up to 1 wt.%) and elevated δ³⁴S_sulfide (3.7 to 12.7‰). Geochemical reaction modeling indicates that seawater-peridotite interaction at 300 to 400°C alone cannot account for both the high sulfur contents and high δ³⁴S_sulfide. These require a multistage reaction with leaching of sulfide from subjacent gabbro during higher temperature (∼400°C) reactions with seawater and subsequent deposition of sulfide during serpentinization of peridotite at ∼300°C. Serpentinization produces highly reducing conditions and significant amounts of H₂ and results in the partial reduction of seawater carbonate to methane. The latter is documented by formation of carbonate veins enriched in ¹³C (up to 4.5‰) at temperatures above 250°C. Although different processes produce variable sulfur isotope effects in other oceanic serpentinites, sulfur is consistently added to abyssal peridotites during serpentinization. Data for serpentinites drilled and dredged from oceanic crust and from ophiolites indicate that oceanic peridotites are a sink for up to 0.4 to 6.0 × 10¹² g seawater S yr⁻¹. This is comparable to sulfur exchange that occurs in hydrothermal systems in mafic oceanic crust at midocean ridges and on ridge flanks and amounts to 2 to 30% of the riverine sulfate source and sedimentary sulfide sink in the oceans. The high concentrations and modified isotope compositions of sulfur in serpentinites could be important for mantle metasomatism during subduction of crust generated at slow spreading rates.  相似文献   

Hydrochemical Evolution of Sodium-Sulfate and Sodium-Chloride Groundwater Beneath the Northern Chihuahuan Desert, Trans-Pecos, Texas, USA   总被引：15，自引：1，他引：15  

R. Stephen Fisher  William F. Mullican  III 《Hydrogeology Journal》1997,5(2):4-16

  相似文献   

Oxygen isotopic compositions of IVA iron meteorites: implications for the thermal evolution derived from in situ ultraviolet laser microprobe analyses     

Pei-Ling Wang  Douglas Rumble III 《Geochimica et cosmochimica acta》2004,68(5):1159-1171

Oxygen isotopic compositions of silicate inclusions in IVA iron meteorites have been measured with an in situ UV laser microprobe technique. The homogeneity of oxygen isotopic compositions within and among individual mineral grains has also been examined. Oxygen isotope fractionations between coexisting mineral pairs were utilized in oxygen isotope thermometry. Our measured Δ¹⁷O values, ranging from 0.97 to 1.25‰, are characteristic of a single reservoir and fully confirm the oxygen isotopic similarity between IVA irons and L/LL chondrites. Steinbach and São João Nepomuceno, containing inclusions of two silicate minerals in mutual contact, exhibit a mass-dependent fractionation of ¹⁸O/¹⁶O between tridymite and bronzite with apparent oxygen isotopic heterogeneity. The SiO₂-bearing member, Gibeon, gives homogeneous oxygen isotopic compositions without detectable fractionation of ¹⁸O/¹⁶O between tridymite and quartz. Oxygen isotope equilibrium temperatures are estimated for coexisting tridymite and bronzite in the same sample slabs or clusters in Steinbach and São João Nepomuceno. The fractionations of ¹⁸O/¹⁶O between bronzite and tridymite range from 1.6 to 2.3‰ in different sample slabs or clusters. On the basis of the closure temperature concept, cooling rates are estimated at approximately 20 to 1000°C/Myr between 800 and 1000°C, a range of temperatures not accessible to other cooling rate methods. Using the Fast Grain Boundary diffusion model, we have demonstrated that significant oxygen heterogeneity both in tridymite and bronzite is probably due to isotope exchange during cooling between minerals with various grain sizes and mineral abundances in different regions of the samples. The new estimates of cooling rate by oxygen isotope thermometry refine previous cooling curves of IVA irons and support the breakup-reassembly model for the IVA parent body.  相似文献   

Reply to Hooke (2004)     

Jeffrey R. Knott  John C. Tinsley  III  Stephen G. Wells 《Quaternary Research》2004,61(3):344-347

  相似文献   

Intensification of Southern Hemisphere westerly winds 2000–1000 years ago: evidence from the subantarctic Campbell and Auckland Islands (52–50°S)          下载免费PDF全文

Chris S. M. Turney  Matt McGlone  Jonathan Palmer  Christopher Fogwill  Alan Hogg  Zoë A. Thomas  Mathew Lipson  Janet M. Wilmshurst  Pavla Fenwick  Richard T. Jones  Ben Hines  Graeme F. Clark 《第四纪科学杂志》2016,31(1):12-19

  相似文献   

Wind-wave prediction equations for probabilistic offshore hurricane hazard analysis     

Vahid Valamanesh  Andrew T. Myers  Sanjay R. Arwade  Jerome F. Hajjar  Eric Hines  Weichiang Pang 《Natural Hazards》2016,83(1):541-562

  相似文献   

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body          下载免费PDF全文

K. Righter  P. Abell  D. Agresti  E. L. Berger  A. S. Burton  J. S. Delaney  M. D. Fries  E. K. Gibson  M. K. Haba  R. Harrington  G. F. Herzog  L. P. Keller  D. Locke  F. N. Lindsay  T. J. McCoy  R. V. Morris  K. Nagao  K. Nakamura‐Messenger  P. B. Niles  L. E. Nyquist  J. Park  Z. X. Peng  C.‐Y. Shih  J. I. Simon  C. C. Swisher III  M. J. Tappa  B. D. Turrin  R. A. Zeigler 《Meteoritics & planetary science》2015,50(10):1790-1819

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.  相似文献   

Serenitatis multi-ringed basin: Regional geology and basin ring interpretation     

James W. Head III 《Earth, Moon, and Planets》1979,21(4):439-462

New topographic data allow a reassessment of the ring structure of the Serenitatis basin and correlation with the younger Orientale basin. The northern Serenitatis basin is smaller and less well preserved than the southern Serenitatis basin. Three major rings of the main (southern) Serenitatis basin are mapped: ring 1, Linné ring, outlined by mare ridges, average diameter 420 km; ring 2, Haemus ring, outlined by basin-facing scarps and massifs with crenulated borders, 610 km; ring 3, Vitruvius ring, outlined by basin-facing linear scarps and massifs, 880 km. Ring 1 corresponds to the inner Rook Mountain ring of Orientale, ring 2 with the outer Rook ring, and ring 3 with the Cordillera Mountain ring. These ring identifications and assignments indicate that the Serenitatis basin is essentially the same size as the Orientale basin, rather than much larger, as previously proposed. The Apollo 17 site lies near the second ring, which is interpreted as the rim of the transient cavity. Apollo 15 lies at the junction of the Serenitatis and Imbrium third rings; Serenitatis ejecta should be present in significant amounts at the Apollo 15 site. The new reconstruction indicates that portions of the Serenitatis basin are better preserved than previously thought, consistent with recent stratigraphic and sample studies that suggest an age for Serenitatis which is older than, but close to, the time of formation of the Imbrium basin.  相似文献   

Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry     

Donald C. Thornton  Alan R. Bandy  Robert G. Ridgeway  Arthur R. Driedger III  Marija Lalevic 《Journal of Atmospheric Chemistry》1990,11(4):299-308

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.  相似文献   

Modeling basin-scale hydrology in support of physical climate and global biogeochemical studies: An example using the Zambezi River     

Charles J. Vörösmarty  Berrien Moore III 《Surveys in Geophysics》1991,12(1-3):271-311

Human activity is an important agent defining the contemporary hydrologic cycle. We have documented the potential impacts of impoundment, land use change and climate change on the Zambezi River system in southern Africa and found that they can be substantial. A full analysis requires construction and parameterization of a simulation for the entire catchment. This paper develops a strategy for implementing catchment-scale models of the major hydrologic processes operating within the basin. A coherent data set for calibrating the models has also been assembled. The algorithms consist of a Water Balance (WBM) and a Water Transport (WTM) operating at 1/2^o spatial scale and at monthly timesteps. These models transform complex patterns of regional climatology into estimates of soil water, evapotranspiration, runoff, and discharge through rivers of various size. The models are dependent on the characteristics of the terrestrial surface, principally soil texture and land cover. A simulated river network is also required. Additional tabular data sets are essential for model testing and calibration. These include subcatchment areas; observed river discharge at selected points; flooding, storage and loss characteristics of major wetlands; floodwave translation; and, volume, surface area, withdrawal and evaporative losses from impoundments. An important design consideration for the numerous impoundments in the Zambezi requires an understanding of the seasonal variation in discharge, in particular how it might respond to climate and land use change. The research strategy offered here lays a framework for addressing such issues. Although the primary focus of this work is hydrologic, we discuss how the model can be extended to consider constituent transport and biogeochemical cycling issues at the continental scale.  相似文献