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11.
The original version of this article was published in Central European Journal of Geosciences volume 1, issue 4 (2009), pp 431–442, DOI:10.2478/v10085-009-0029-0. Unfortunately the original version of this article contains mistakes in authors names which we correct here. Editorial staff of the journal apologise for any inconvenience that may result from the oversight.  相似文献   
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The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO2) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO2 fluxes of several fumaroles were estimated from two-dimensional distributions of SO2. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6 × 1014 molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO2 ratio, calculated from the two-dimensional distributions of SO2 and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.  相似文献   
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High-Na slag-like rocks (paralava) with 4.5–11 % Na2O from the Altyn-Emel mud volcanic field, Kazakhstan, are the products of melting of sediment + salt mixtures by methane flares associated with mud extrusion. The main minerals of the paralavas are diopside and wollastonite which have quench morphologies. Other high-temperature phases (crystallizing from melt and vapour phase) are tridymite, cristobalite, chlorapatite, alkali feldspar, pyrrhotite, native iron and silicon, iron phosphides, titanite, rutile, and carbon. The paralavas lack the Na–Ca silicates devitrite and combeite, but have high-Na and Na–K glasses that have not been homogenized despite low viscosities of <10?3.5 Pa s. The large number of ignition foci in the Altyn-Emel mud volcano field indicates gas venting from small, shallow reservoirs. The methane flares are inferred to have been small and the fire events short-lived. Fires were extinguished once overpressure released during eruption, methane venting stopped and melted rocks rapidly quenched. The periodicity of eruptions and methane flaring most likely depends on the recurrence of earthquakes (M < 5) which are frequent in this tectonically active area.  相似文献   
15.
A steady-state, one-dimensional, mesoscale, non-linear problem of the airflow over a mountain ridge is considered in the framework of the bulk theory in an attempt to develop a meteorological generalisation of the hydraulic problem formulated and solved previously by Houghton and Kasahara. In essence, only three modifications of their formulation are made in the present paper: (a) inversion strength is introduced and considered as an additional dependent variable; (b) the atmosphere above the flow is assumed to be stably stratified with a constant vertical potential temperature gradient; and (c) the condition requiring the flow to return to its initial state after descending and moving away from the ridge is removed.The problem is reduced to a transcendental algebraic equation, the solution of which describes all the possible types of flow, including a discontinuous one. A classification and meteorological criterion graphically presented in the form of a map is proposed for the realisation of each type of flow.If the ridge is higher than some threshold, a jump arises above the windward slope and propagates against the flow. As a result, the initial parameters change to new values for which a secondary steady-state solution exists. An iterative method has been developed to calculate these new initial parameters.The general features of the different types of flow, including those with a jump and secondary flows, are discussed. It is shown that if the ridge height exceeds some second threshold there are no solutions at all, which means that the flow is totally blocked. Concrete calculated examples are presented of all possible types of steady-state flows including secondary ones.It is shown that after introduction of these modifications, the hydraulic model of Houghton and Kasahara acquires more real meteorological meaning.  相似文献   
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A procedure was developed for the determination of element distributions in cross-sections of ferromanganese concretions using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The effects of carrier flow rates, rf forward power, ablation energy, ablation spot size, repetition rate and number of shots per point on analyte intensity were studied. It is shown that different carrier gas flow rates are required in order to obtain maximum sensitivities for different groups of elements, thus complicating the optimisation of ICP parameters. On the contrary, LA parameters have very similar effects on almost all elements studied, thus providing a common optimum parameter set for the entire mass range. However, for selected LA parameters, the use of compromise conditions was necessary in order to compensate for relatively slow data acquisition by ICP-MS and maintain high spatial resolution without sacrificing the multielemental capabilities of the technique. Possible variations in ablation efficiency were corrected for mathematically using the sum of Fe and Mn intensities. Quantification by external calibration against matrix-matched standards was successfully used for more than 50 elements. These standards, in the form of pressed pellets (no binder), were prepared in-house using ferromanganese concentrates from a deep-sea nodule reference material as well as from shallow-marine concretions varying in size and having different proportions of three major phases: aluminosilicates, Fe- and Mn-oxyhydroxides. Element concentrations in each standard were determined by means of conventional solution nebulisation ICP-MS following acid digestion. Examples of selected inter-element correlations in distribution patterns along the cross-section of a concretion are given.  相似文献   
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Summary. Kelvin-Christoffel equations describing plane wave propagation in anisotropic media are generalized to account for the effects of nonlinear elasticity. The polarization and waveform of nonlinear distortions of a transient plane wave are investigated by means of perturbation theory. Detailed analysis for an anisotropic medium with hexagonal symmetry shows that for "pure" shear-waves the polarization vector of the nonlinear component is always perpendicular to that of the linear wave. In the case of a high-amplitude excitation (for instance, in the vicinity of large earthquakes) the influence of nonlinearity may cause distortions of shear-wave polarization, which contains the most reliable information on the presence and characteristics of anisotropy. The solutions presented in this paper make it possible to solve reflection-transmission problems in nonlinear-elastic anisotropic media.  相似文献   
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The objective of this study was to validate the outcomes of a modified decision tree classifier by comparing the produced landslide susceptibility map and the actual landslide occurrence, in an area of intensive landslide manifestation, in Xanthi Perfection, Greece. The values that concerned eight landslide conditioning factors for 163 landslides and 163 non-landslide locations were extracted by using advanced spatial GIS functions. Lithological units, elevation, slope angle, slope aspect, distance from tectonic features, distance from hydrographic network, distance from geological boundaries and distance from road network were among the eight landslide conditioning factors that were included in the landslide database used in the training phase. In the present study, landslide and non-landslide locations were randomly divided into two subsets: 80 % of the data (260 instances) were used for training and 20 % of the data (66 instances) for validating the developed classifier. The outcome of the decision tree classifier was a set of rules that expressed the relationship between landslide conditioning factors and the actual landslide occurrence. The landslide susceptibility belief values were obtained by applying a statistical method, the certainty factor method, and by measuring the belief in each rule that the decision tree classifier produced, transforming the discrete type of result into a continuous value that enabled the generation of a landslide susceptibility belief map. In total, four landslide susceptibility maps were produced using the certainty factor method, the Iterative Dichotomizer version 3 algorithm, the J48 algorithm and the modified Iterative Dichotomizer version 3 model in order to evaluate the performance of the developed classifier. The validation results showed that area under the ROC curves for the models varied from 0.7936 to 0.8397 for success rate curve and 0.7766 to 0.8035 for prediction rate curves, respectively. The success rate and prediction curves showed that the modified Iterative Dichotomizer version 3 model had a slightly higher performance with 0.8397 and 0.8035, respectively. From the outcomes of the study, it was induced that the developed modified decision tree classifier could be efficiently used for landslide susceptibility analysis and in general might be used for classification and estimation purposes in spatial predictive models.  相似文献   
20.
Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO2 through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ11B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ11B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ11B; and (c) to provide well‐constrained consensus δ11B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.  相似文献   
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