Synthesis, properties and stability of end member boromuscovite, KAl2[BSi3O10](OH)2     

Ingo Jung  Werner Schreyer 《Contributions to Mineralogy and Petrology》2002,143(6):684-693

End member boromuscovite, with nearly the ideal composition, was synthesized as a single phase from mixtures of its own composition, or with excess boron and water, at high pressures of between 15 and 30 kbar at 700 °C. The mica synthesized consists of a mixture of 2M₁ and 1M polytypes with the cell dimensions of 2M₁: a=5.071(4), b=8.786(4), c=19.830(89) Å, #=95.84(12)°, V=878.5(1.4) ų; and 1M: a=5.059(5), b=8.819(6), c=10.025(17) Å, #=101.39(57)°, V=438.4(1.3) Å. The IR spectrum shows characteristic differences relative to that of muscovite. DTA registers an endothermic peak due to dehydration breakdown above 680 °C. Seeded experiments indicate that boromuscovite is a high-pressure phase requiring minimum pressures of 3 to 10 kbar at temperatures that concomitantly increase from 300 to 750 °C. At lower pressures, the anhydrous solid assemblage K-feldspar + Al-borate (probably Al₄B₂O₉) coexists with a vapor rich in boric acid. The conversion of this assemblage to boromuscovite is connected with increases in the coordination number of B from [3] to [4], and of Al from [4] to [6]. Above 10 kbar, the boromuscovite stability field is limited along its high-temperature side by congruent (or incongruent?) melting of the mica, starting near 750 °C and 10 kbar and increasing to about 900 °C at 50 kbar, although, at such very high pressures a supercritical fluid may be present. Because, even in the presence of excess-boron fluid, the synthetic mica shows invariable X-ray properties, it is concluded that one B atom per formula unit represents the maximum, and - contrary to olenitic tourmalines - no further substitution of Si by B linked with addition of hydrogen takes place. In contrast to muscovite, KAl₂[AlSi₃O₁₀](OH)₂, end member boromuscovite is not stable under normal P-T conditions of the Continental Crust along a 30 °C/km geotherm, and especially not during the intrusion of acidic igneous rocks including their pegmatites, which may explain its scarcity in nature. However, it may form in the waning hydrothermal stages of deep-seated (>10.5 km) pegmatites and - providing sufficient boron is available - in HP/LT subduction zone environments, where it may carry boron to considerable depths.  相似文献   

State‐Led Innovation at the City Level: Policy Measures to Promote New Energy Vehicles in Shenzhen,China     

Johannes Lauer  Ingo Liefner 《Geographical review》2019,109(3):436-456

Unlike many Western countries, the Chinese state has a much more active role in innovation that includes direct involvement with actors in innovation processes and the use of state capacity, money, and power to attain certain goals. With the rise of China, innovation processes that critically depend on state action, often labeled state‐led innovation, have thus received growing scholarly attention. However, only few contributions study the specific sector of new energy vehicles (NEV) and policy measures applied at the city level. This paper examines policy and planning tools used in Shenzhen, China, to assert innovation in the NEV industry, using an evaluation of documents and interviews. The paper finds that a city can play a decisive role in the implementation of innovation policy, and Chinese cities in particular make use of a broad set of innovation support measures ranging from binding quotas, public procurement, and incentives to bans and orders. The findings underline the importance of strong regulatory instruments that do not conform to the Western notion of market‐compliant policy, but nevertheless work effectively in the Chinese context. Moreover, the results highlight how successful policy support for innovation in the NEV can be implemented.  相似文献   

Cosmic ray exposure ages for ureilites—New data and a literature study     

Ingo Leya  Peter C. Stephenson 《Meteoritics & planetary science》2019,54(7):1512-1532

We report newly measured noble gas isotopic concentrations of He, Ne, and Ar for 21 samples from the 10 ureilites, DaG 084, DaG 319, DaG 340, Dho 132, HaH 126, JaH 422, JaH 424, Kenna, NWA 5928, and RaS 247, including the results of both single and stepwise heating extractions. Cosmic ray exposure (CRE) ages calculated using model calculations that fully account for all shielding depths and a wide range of preatmospheric radii, and are tailored to ureilite chemistry, range from 3.7 Ma for Dho 132 to 36.3 Ma for one of several measured Kenna samples. In a Ne‐three‐isotope plot, the data for DaG 340 and JaH 422 plot below the Ne_cos/Ne_ureilite mixing envelope, possibly indicating the presence of Ne produced from solar cosmic rays. In combination with literature data and correcting for pairing, we established a fully consistent database containing 100 samples from 40 different ureilites. The CRE age histogram shows a trend of decreasing meteorite number with increasing CRE age. We speculate that the parent body of the known ureilites is moving closer to a resonance and/or that there is a loss mechanism that acts on ureilites independent of their size. In addition, there is a slight indication for a peak in the range 30 Ma, which might indicate a larger impact on the ureilite daughter body. Finally, we confirm earlier results that the majority of the studied ureilites have relatively small preatmospheric radii less or equal ~20 cm.  相似文献   

Textural and compositional evidence for in situ crystallization of palisade bodies in coarse‐grained Ca‐Al‐rich inclusions     

Mingming Zhang  Yangting Lin  Ingo Leya  Guoqiang Tang  Yu Liu 《Meteoritics & planetary science》2019,54(5):1009-1023

Palisade bodies, mineral assemblages with spinel shells, in coarse‐grained Ca‐, Al‐rich inclusions (CAIs) have been considered either as exotic “mini‐CAIs” captured by their host inclusions (Wark and Lovering 1982 ) or as in situ crystallization products of a bubble‐rich melt (Simon and Grossman 1997 ). In order to clarify their origins, we conducted a comprehensive study of palisade bodies in an Allende Type B CAI (BBA‐7), using electron backscatter diffraction (EBSD), micro‐computed tomography (Micro‐CT), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). New observations support the in situ crystallization mechanism: early/residual melt infiltrated into spinel‐shelled bubbles and crystallized inside. Evidence includes (1) continuous crystallography of anorthite from the interior of the palisade body to the surrounding host; (2) partial consolidation of two individual palisade bodies revealed by micro‐CT; (3) a palisade body was entirely enclosed in a large anorthite crystal, and the anorthite within the palisade body shows the same crystallographic orientation as the anorthite host; and (4) identical chemical and oxygen isotopic compositions of the constituent minerals between the palisade bodies and the surrounding host. Oxygen isotopic compositions of the major minerals in BBA‐7 are bimodal‐distributed. Spinel and fassaite are uniformly ¹⁶O‐rich with ?¹⁷O = ?23.3 ± 1.5‰ (2SD), and melilite and anorthite are homogeneously ¹⁶O‐poor with ?¹⁷O = ?3.2 ± 0.7‰ (2SD). The latter ?¹⁷O value overlaps with that of the Allende matrix (?¹⁷O ~ ?2.87‰) (Clayton and Mayeda 1999 ), which could be explained by secondary alteration with a ¹⁶O‐poor fluid in the parent body. The mobility of fluid could be facilitated by the high porosity (1.56–2.56 vol%) and connectivity (~0.17–0.55 vol%) of this inclusion.  相似文献   

Vodyanitskii mud volcano,Sorokin trough,Black Sea: Geological characterization and quantification of gas bubble streams     

Heiko Sahling  Gerhard Bohrmann  Yuriy G. Artemov  André Bahr  Markus Brüning  Stephan A. Klapp  Ingo Klaucke  Elena Kozlova  Aneta Nikolovska  Thomas Pape  Anja Reitz  Klaus Wallmann 《Marine and Petroleum Geology》2009

Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L⁻¹ at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH₄ = −170.8‰ (SMOW), δ¹³C-CH₄ = −61.0‰ (V-PDB), δ¹³C-C₂H₆ = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 10⁶ mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.  相似文献   

Phytoplankton und Primärproduktion einiger ostschweizerischer Seen und des Bodensees     

Ingo Findenegg 《Aquatic Sciences - Research Across Boundaries》1966,28(2):148-172

Ohne Zusammenfassung  相似文献   

Dust on the Outskirts of the Jovian System     

Alexander V. Krivov  Ingo WardinskiFrank Spahn  Harald KrügerEberhard Grün 《Icarus》2002,157(2):436-455

The outer region of the jovian system between ∼50 and 300 jovian radii from the planet is found to be the host of a previously unknown dust population. We used the data from the dust detector aboard the Galileo spacecraft collected from December 1995 to April 2001 during Galileo's numerous traverses of the outer jovian system. Analyzing the ion amplitudes, calibrated masses and speeds of grains, and impact directions, we found about 100 individual events fully compatible with impacts of grains moving around Jupiter in bound orbits. These grains have moderate eccentricities and a wide range of inclinations—from prograde to retrograde ones. The radial number density profile of the micrometer-sized dust is nearly flat between about 50 and 300 jovian radii. The absolute number density level (∼10 km⁻³ with a factor of 2 or 3 uncertainty) surpasses by an order of magnitude that of the interplanetary background. We identify the sources of the bound grains with outer irregular satellites of Jupiter. Six outer tiny moons are orbiting the planet in prograde and fourteen in retrograde orbits. These moons are subject to continuous bombardment by interplanetary micrometeoroids. Hypervelocity impacts create ejecta, nearly all of which get injected into circumjovian space. Our analytic and numerical study of the ejecta dynamics shows that micrometer-sized particles from both satellite families, although strongly perturbed by solar tidal gravity and radiation pressure, would stay in bound orbits for hundreds of thousands of years as do a fraction of smaller grains, several tenths of a micrometer in radius, ejected from the prograde moons. Different-sized ejecta remain confined to spheroidal clouds embracing the orbits of the parent moons, with appreciable asymmetries created by the radiation pressure and solar gravity perturbations. Spatial location of the impacts, mass distribution, speeds, orbital inclinations, and number density of dust derived from the data are all consistent with the dynamical model.  相似文献   

Petrologic and geochemical investigation of carbonates in peridotite xenoliths from northeastern Tanzania   总被引：5，自引：1，他引：4  

Cin-Ty Lee  Roberta L. Rudnick  William F. McDonough  Ingo Horn 《Contributions to Mineralogy and Petrology》2000,139(4):470-484

Primary carbonates in peridotite xenoliths from the East African Rift in northeastern Tanzania occur as intergranular patches with accessory minerals (olivine and spinel), as patches with accessory magmatic minerals (nepheline), and as round monomineralic inclusions in primary olivine grains. All are characterized by calcitic compositions (Ca/Ca + Mg + Fe from 0.83 to 0.99), extremely low SiO₂ + Al₂O₃ + Na₂O + K₂O, low trace element abundance [total rare-earth element (REE) abundance <25 ppm], uniform extinction, and lack of reaction textures with the host xenolith. Calculated Fe–Mg exchange coefficients between carbonate and primary olivine indicate disequilibrium in most samples. Combined with the lack of significant reaction textures, this suggests that the carbonates were introduced shortly before or during eruption of the host magma. A global compilation of electron microprobe analyses of mantle-derived carbonates (in xenoliths, xenocrysts, and megacrysts) reveals compositional clusters near end member calcite, end member magnesite, and stoichiometric dolomite. Eutectic liquid compositions are less common, suggesting that many carbonate inclusions reported worldwide may be crystalline precipitates. Likewise, the calcites in this study are not interpreted to represent quenched carbonatitic melts, but are interpreted instead to be crystalline cumulates from such melts. These inferences are consistent with recent experiments, which show that carbonatitic melts cannot become more calcitic than CaCO₃∼80 wt%. Low trace element abundance may be a diagnostic feature of cumulate carbonate, and in combination with petrography and major element composition, serve to distinguish it from quenched carbonated liquid. Received: 30 July 1999 / Accepted: 5 February 2000  相似文献   

Cosmogenic neon in mineral separates from Kapoeta: No evidence for an irradiation of its parent body regolith by an early active Sun     

Rainer Wieler  Anselmo Pedroni  Ingo Leya 《Meteoritics & planetary science》2000,35(2):251-257

Abstract— We present Ne data from plagioclase separates from the solar noble‐gas‐rich meteorite Kapoeta, obtained mainly by in vacuo etching. samples rich in solar gases contain an excess of cosmogenic ne compared to solar‐gas‐poor samples, testifying to an exposure to cosmic rays in the parent body regolith. The ²¹Ne/²²Ne ratio of the excess component is slightly lower than that of the Ne acquired during the meteoroid flight. Model calculations indicate that the observed isotopic composition of the excess Ne can be produced by galactic cosmic rays at a reasonable mean shielding of around a hundred to a few hundred grams per square centimeter. No substantial contribution from Ne produced by solar cosmic rays is needed to explain the data. We therefore conclude that they do not offer evidence for a substantially enhanced flux of solar energetic particles early in solar history, contrary to other claims. This conclusion is in agreement with solar flare track data.  相似文献   

What controls equatorial Atlantic winds in boreal spring?     

Ingo Richter  Swadhin K. Behera  Takeshi Doi  Bunmei Taguchi  Yukio Masumoto  Shang-Ping Xie 《Climate Dynamics》2014,43(11):3091-3104

The factors controlling equatorial Atlantic winds in boreal spring are examined using both observations and general circulation model (GCM) simulations from the coupled model intercomparison phase 5. The results show that the prevailing surface easterlies flow against the attendant pressure gradient and must therefore be maintained by other terms in the momentum budget. An important contribution comes from meridional advection of zonal momentum but the dominant contribution is the vertical transport of zonal momentum from the free troposphere to the surface. This implies that surface winds are strongly influenced by conditions in the free troposphere, chiefly pressure gradients and, to a lesser extent, meridional advection. Both factors are linked to the patterns of deep convection. Applying these findings to GCM errors indicates, that, consistent with the results of previous studies, the persistent westerly surface wind bias found in most GCMs is due mostly to precipitation errors, in particular excessive precipitation south of the equator over the ocean and deficient precipitation over equatorial South America. Free tropospheric influences also dominate the interannual variability of surface winds in boreal spring. GCM experiments with prescribed climatological sea-surface temperatures (SSTs) indicate that the free tropospheric influences are mostly associated with internal atmospheric variability. Since the surface wind anomalies in boreal spring are crucial to the development of warm SST events (Atlantic Niños), the results imply that interannual variability in the region may rely far less on coupled air–sea feedbacks than is the case in the tropical Pacific.  相似文献