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91.
Holocene pollen and diatom analyses and complementary data from δ18O and δ13C, malacology and sedimentology have provided a detailed record of vegetation history and palaeoenvironmental change at arroyo Las Brusquitas, on the southeastern coast of the pampas of Argentina especially in relation to past sea levels. Holocene palaeosalinity trends were estimated by Detrended Correspondence Analysis and by salinity indexes based on pollen and diatom data. As a consequence of sea‐level rise from the postglacial an extensive wave‐cut platform formed over which Holocene infilling sequences were deposited unconformably. In these sequences, variation in pollen and diatom assemblages occurred in agreement with changes in mollusc diversity and abundance, isotope values, and sediment deposits. Between ca. 6700 and 6190 14C yr BP (6279–6998 cal. yr BP) saline conditions predominated in an environment highly influenced by tides and salt water during the Holocene sea‐level highstand. Between ca. 6200 and 3900 14C yr BP (4235–4608 cal. yr BP) shallow brackish water bodies formed surrounded by saltmarsh vegetation that became more widespread from 5180 14C yr BP (5830–6173 cal. yr BP) to 3900 14C yr BP in relation to a sea‐level stabilisation period within the regression phase. Less saline conditions marked by frequent variations in salinity predominated between ca. 3900 and 2040 yr 14C BP (1830–2160 cal. yr BP). The intertidal saltmarsh environment changed into a brackish marsh dominated by freshwater conditions and sporadic tidal influence. Halophytic vegetation increased towards ca. 200014C yr BP indicating that saline conditions may be due to either desiccation or an unusually high tide range with rare frequency. After ca. 2000 14C yr BP the sedimentary sequences were buried by aeolian sand dunes. Changes in Holocene vegetation and environments in Las Brusquitas area are in agreement with data obtained from various southeastern coastal sites of the Pampa grasslands. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
92.
The understanding of the solid-phase speciation of arsenic in soils and sediments is important in the evaluations of its potential mobility and availability in the environment. The spoil heaps of abandoned mercury mines contain waste materials with high arsenic and heavy metals concentrations. The weathering of these tailings can cause their mobilization to the surroundings. In this work, the mobility and availability of arsenic and some heavy metals were evaluated in sediments from two heavily polluted mercury mining districts in Asturias (NW Spain). For this purpose, a slightly modified version of the Bureau Community of Reference sequential extraction scheme was applied to sediments. The total contents in the operationally defined fractions were analysed by inductively coupled plasma-atomic emission spectrometry. Extremely high total arsenic concentrations were found in all sediments ranging from 4,000 to 24,800 mg kg?1. High easily mobilizable arsenic contents were found in the first mining area, related to the solubilization of Ca-bearing phases, supported by extracts analyses, X-ray diffraction results and the positive correlation found among the As and Ca fractionations. Ni and Zn were the most mobile among heavy metals, being Cr the least mobile, suggesting an anthropogenic origin due to the metallurgical processes, transport or dispersion generated from neighbour spoil heaps. In the second mining area, the bulk of As was concentrated in the residual phase, as well as Cr, Cu, Fe, Pb, Ti, indicating a mineralogical origin and the low availability of these elements. The strong correlations established between As and Fe and Ti distributions support the hypothesis that As is mainly associated to structural mineral phases in these sediments.  相似文献   
93.
The paper describes the training, validation, testing, and application of models of artificial neural networks (ANN) for computing the cross-shore beach profile of the sand beaches of the province of Valencia (Spain). Sixty ANN models were generated by modifying both the input variables as the number of neurons in the hidden layer. The input variables consist of wave data and sedimentological data. To select and evaluate the performance of the optimal model, the following parameters were used: R2, absolute error, mean absolute percentage error, and percentage relative error. Finally, the results are compared with the numerical model proposed by Aragonés et al. (2016b Aragonés, L., Y. Villacampa, F. J. Navarro-González, and I. López. 2016b. Numerical modelling of the equilibrium profile in Valencia (Spain). Ocean Engineering, 123:16473. doi:10.1016/j.oceaneng.2016.07.036[Crossref], [Web of Science ®] [Google Scholar]) for the equilibrium profile in the study area. The results show a mean absolute error of 0.21?m compared to 0.33?m Aragones’ model, significantly improving the results of the numerical model in the bar area around de Valencia Port. In addition, when comparing the results with other methods currently used (Dean’s or Vellinga formulation), the errors of these compared to ANN are of the order of 167 and 1538% higher, respectively.  相似文献   
94.
The effects of using reduced sampling resolutions to study macroalgal vegetation patterns have not been studied sufficiently. Here, we test the influence of taxonomic resolution level, removal of occasional species, aggregation of species abundances into functional groups and data transformation in the detection of a long-term recovery process by phytobenthic intertidal assemblages. Results indicate that the aggregation of species data into the genus level has very little influence. Likewise, almost any significant information is lost when occasional algae are removed. Analyses at the level of families and orders still clearly detect differences between highly degraded and reference vegetation. By contrast, analyses based on class and functional group abundances capture quite different information. The effect of transformation is similar at the different taxonomic levels. Most surrogate measures properly reflect changes in diversity. It is concluded that genus level is the most appropriate surrogate approach for detecting the recovery process.  相似文献   
95.
In inland waters, transparent exopolymer particles (TEP) can affect carbon export and sequestration in sediments with consequences for lake C budgets. We measured TEP concentration in 32 lakes from two contrasting lake districts covering wide ranges in biological and chemical characteristics. North temperate lakes, located in a wet region, have low to moderate ionic strength and low to high dissolved organic carbon with corresponding variation in color (light absorbance). Mediterranean lakes located in a semiarid region were characterized by high ionic strength and high concentrations of dissolved organic carbon but low color. TEP concentrations were large relative to the living portion of the particulate organic carbon pool in both Mediterranean (36%) and north temperate (33%) lakes. TEP concentrations ranged from 36 to 1,462 μg [as Gum Xanthan equivalents (GX eq)] L−1 in north temperate lakes. In the Mediterranean lakes, concentrations were higher that previously reported for other systems and ranged from 66 to 9,038 μg GX eq L−1. TEP concentration was positive and significantly related to chlorophyll a (chl a) in north temperate lakes and in the entire data set. Although a significant and positive relationship between TEP and chl a was also detected in the Mediterranean lakes, bacterial abundance was most strongly related to TEP. In contrast with the positive influence of phytoplankton and bacteria on TEP, there were weaker relationships between TEP and the chemical variables tested. We observed a significant and positive relationship between pH and TEP (for all lakes) but this relationship was indirectly driven by a co-variation of pH with phytoplankton biomass based on multiple regression analysis. For the Mediterranean lakes, the negative (but not significant) trends between TEP and both conductivity and divalent cations suggest thresholds above which TEP will likely be destabilized. Under these conditions, TEP may flocculate or disperse in the water column.  相似文献   
96.
Most streams draining to the Mediterranean basin are temporary. As a result of their hydrological regime, temporary streams are affected by drying and rewetting periods. Drying can alter in-stream nitrogen (N) availability and reduce N processing rates and subsequent retention after re-wetting. We sought to determine if hydrologic drying modifies reach-scale sediment chemical properties and constrains the response of N processing to rewetting. We compared different abiotic characteristics of sediments and nitrification and denitrification rates between a perennial and intermittent reach in the same stream over a wet period, when surface water flowed in both reaches, and a dry period, when the intermittent reach dried up. We analyzed N processing rates by incubating sediments with stream water, thereby simulating a rewetting when sediments from the intermittent reach were dry. We found that drying increased the sediment nitrate (NO3 ?) content. Conversely, drying did not reduce the recovery of N processing rates to pre-dry levels after simulated flooding conditions. Our results suggest that dry reaches may act as a potential NO3 ? source by releasing downstream NO3 ? pulses after stream flow recovery. Given the European Water Framework Directive requirements to assess stream ecological status, these N pulses following rewetting should be considered when designing management plans in temporary streams. Our study highlights the rapid response of in-stream N processing to rewetting period following a drought. This high resilience to process N should be seen as a vital ecosystem service provided by temporary streams despite annual dry periods.  相似文献   
97.
The northwest region of the Iberian Peninsula is home to a unique ecosystem of bogs,which are particularly sensitive to projected climate cha nge.In this context,the rate of carbon(C)accumulation in Chao de Veiga Mol.an intact raised bog,was analysed.Changes in the accumulation rate over the past10 millennia were determined in a peat core of 847 cm in depth,with a high mean rate of peat growth(11 yr cm^-1,0.09 cm yr^-1).An age-depth model was generated from 22 14C dates and fallout radionuclides.Chronological,stratigraphical and physico-chemical data confirmed the existence of a single cycle of peat formation throughout the Holocene and the formation of ombrotrophic peat 9500 years ago.The total mean C content was 50.2%,and over 10 millennia 583 kg C m^-2 accumulated at a mean rate of 35.3 g C m^-2 yr^-1,with a long-term(apparent)rate of carbon accumulation in the catotelm of59.9 g C m^-2 yr^-1.These values are much higher than reported for other Iberian peatlands and are amongst the highest documented for peatlands in the northern hemisphere.The dynamics of C accumulation and other measured parameters reveals important variations throughout the Holocene.They could be associated with the main climatic events described in the northern hemisphere and are highly consistent with models established for northern latitudes.The Chao de Veiga Mol raised bog is unique and of great potential value for carrying out high resolution palaeoenvironmental studies,especially in relation to regional and Iocal modulations in southern Europe.  相似文献   
98.
99.
Two wells, Balazuc (BA1) and Morte-Mérie (MM1), located in a confined area (1200 m apart) and separated by the Uzer fault (a Liassic structure with a dip fault of 1300 m) were analysed using conventional methodologies and techniques (PRV, TAI, XRD, STEM) in order to compare the diagenetic evolution of clays and organic matter. The thermal convective process allows the circulation of hot fluids and the oxidation of organic matter. The conductive process allows the maturation of the organic matter, the expulsion of hydrocarbons and the deposit of pyrobitumes in the migration channels. To cite this article: L. Martinez et al., C. R. Geoscience 334 (2002) 1021–1028.  相似文献   
100.
An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.  相似文献   
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