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41.
A Closure Study of Aerosol Hygroscopic Growth Factor during the 2006 Pearl River Delta Campaign 总被引:3,自引:0,他引:3
LIU Xingang ZHANG Yuanhang WEN Mengting WANG Jingli Jinsang JUNG CHANG Shih-yu HU Min ZENG Limin Young Joon KIM 《大气科学进展》2010,27(4):947-956
Measurements of aerosol physical, chemical and optical parameters
were carried out in Guangzhou, China from 1 July to 31 July 2006 during the
Pearl River Delta Campaign. The dry aerosol scattering coefficient was measured
using an integrating nephelometer and the aerosol scattering coefficient for
wet conditions was determined by subtracting the sum of the aerosol absorption
coefficient, gas scattering coefficient and gas absorption coefficient from the
atmospheric extinction coefficient. Following this, the aerosol hygroscopic
growth factor, f(RH), was calculated as the ratio of wet and dry aerosol
scattering coefficients. Measurements of size-resolved chemical composition,
relative humidity (RH), and published functional relationships between particle
chemical composition and water uptake were likewise used to find the aerosol
scattering coefficients in wet and dry conditions using Mie theory for
internally- or externally-mixed particle species [(NH4)2SO4, NH4NO3, NaCl, POM, EC and residue]. Closure was obtained by comparing
the measured f(RH) values from the nephelometer and other in situ optical
instruments with those computed from chemical composition and thermodynamics.
Results show that the model can represent the observed f(RH) and is
appropriate for use as a component in other higher-order models. 相似文献
42.
The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM2.5 mass (21.5 μg m− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM2.5 sources.Additionally, the impact of air mass pathways on the PM2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM2.5 mass during the biomass burning (BB) event equaled 63.8%. 相似文献
43.
Deformation microstructures of olivine in peridotite from Spitsbergen, Svalbard and implications for seismic anisotropy 总被引:1,自引:0,他引:1
To understand the deformation mechanism and seismic anisotropy in the uppermost mantle beneath Spitsbergen, Svalbard, in the Arctic, the deformation microstructures of olivine in the peridotite of Spitsbergen were studied. Seismic anisotropy in the upper mantle can be explained mainly by the lattice-preferred orientation (LPO) of olivine. The LPOs of the olivine in the peridotites were determined using electron backscattered diffraction patterns. Eight specimens out of 10 showed that the [100] axis of the olivine was aligned subparallel to the lineation and that the (010) plane was subparallel to the foliation, showing a type A LPO. In the other two specimens the [100] axis of olivine was aligned subparallel to the lineation and both the [010] and [001] axes were distributed in a girdle nearly perpendicular to the lineation, showing a type D LPO. The dislocation density of the olivine in the samples showing a type D LPO was higher than that in the samples showing a type A LPO. The result of an Fourier transformation infrared study showed that both the types A and D samples were dry. These observations were in good agreement with a previous experimental study ( Tectonophysics , 421 , 2006, 1 ): samples showing a type D LPO for olivine were observed at a high stress condition and samples showing both types A and D LPO were deformed under dry condition. Observations of both strong LPOs and dislocations of olivine indicate that the peridotites studied were deformed by dislocation creep. The seismic anisotropy calculated from the LPOs of the olivine could be used to explain the seismic anisotropy of P - and S -waves in the lithospheric mantle beneath Spitsbergen, Svalbard. 相似文献
44.
45.
The presence of the minimum salinity and oxygen-rich East Sea Intermediate Water (ESIW) off Korean coast has raised many questions
about its origin and movement. This study attempts to answer these questions in the context of numerical model. For this,
the Miami Isopycnic Coordinate Ocean Model is used with surface and inflow boundary conditions based on available data. Model
results show that the ESIW forms most distinctly off Vladivostok, where the center of doming structure is observed, and moves
southward along Korean coast forming a large cyclonic gyre around the doming. The renewed ESIW has the character of minimum
potential vorticity common to usual mode waters. These results are compatible with various indications made in previous observational
and theoretical studies. However, it is not known whether the doming structure is a result of convection or the latter is
favored by the former.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
46.
Eun-Hee Koh Seung Hyun Lee Dugin Kaown Hee Sun Moon Eunhee Lee Kang-Kun Lee Bong-Rae Kang 《Environmental Earth Sciences》2017,76(4):176
Impacts of land use changes and groundwater management actions on groundwater quality were evaluated at the island scale with spatiotemporal trends of NO3-N and Cl concentrations in groundwater of Jeju Island, Korea. The temporal trends from 1993 to 2012 in the concentrations of NO3-N and Cl from more than 3900 wells were estimated using the Mann–Kendall trend test and Sen’s slope analysis and compared with the land use change trend for the period 1995–2009. The results indicate that the upward trends in NO3-N were associated with the expansion of agricultural lands, whereas Cl trends were considered to be affected by other factors in addition to the land use changes. In the mid-mountainous region, the deterioration in the groundwater quality by the both NO3-N and Cl was expected due to the continuous expansion of agricultural lands. In the lowland area, the NO3-N and Cl components showed different trends depending on the regions. In the eastern area, increasing trends in NO3-N were observed due to the development of new agricultural areas, while the Cl concentration was observed to decrease as a result of the regulation on groundwater extraction to reduce seawater intrusion. Our study highlights that a comprehensive interpretation of trends in NO3-N and Cl and land use changes for long-term periods can provide useful insights to prepare for suitable groundwater management plans in the whole island perspective. 相似文献
47.
Abstract: A total of 16 specimens of fossil-winged fruits were found from the Middle Miocene marine deposits, Duho Formation, Pohang Basin, Korea. They were identified into two structurally different groups: 15 specimens into a winged fruit of Fraxinus, and one specimen of Liriodendron. The most samaras (13 specimens) were identified as Fraxinus oishii, which is characterized by narrowly ovate or ovate–elliptic shapes that are 2.7–3.6 cm in length and 0.7–1 cm in width (l/w ratio=3.4–4). The apexes of the Fraxinus oishii samara are round or slightly emarginated, and a seed of the samara is always located at the base, of which the general shape is narrow rhombic-ellipsoidal. The seed is 1.2–2 cm long and 0.5–0.7 cm wide. Two specimens are different from the samara of Fraxinus oishii. They have a 6.6 length/width ratio (3.3 cm long and 0.5 cm wide), and thus, are temporarily classified into the Fraxinus sp. One specimen was recognized as a winged seed of Liriodendron meisenense. The wing is broadly lanceolate to elliptic in shape, has a smooth, acute apex, and is approximately 3 cm long and 0.7 cm wide. Samaras of Fraxinus oishii and Liriodendron meisenense were early reported from the Middle Miocene deposits from North Korea, but these specimens are the first discovery in South Korea. Further study of the Duho Formation may connect flora relationships between North and South Korea. 相似文献
48.
AbstractPipes buried in soft ground can be damaged due to the vertical and lateral movement of the ground during the construction of the embankment. To investigate such a movement of the soft ground, full-scale tests using embankment piles and stabilizing piles were conducted for 70?days. A pile-supported embankment has been used to reduce the deformation of soft ground by transferring the embankment load through piles to the firm layer below the soft ground, whereas stabilizing piles have been employed to resist the lateral earth pressure that is induced in soft ground by embankment loads. The Coupling Area (CA), which was defined as the quantitative index to determine the resistance effect of both settlement and lateral flow of the soft ground when the embankment was reinforced, is adapted. The analysis results of the CA indicate that the piled embankment was more effective for preventing the damage to buried pipe installed near the embankment, while the stabilizing piles had almost the same effect as the piled embankment when the pipe was buried far away from the embankment. 相似文献
49.
Above- and below-ground productivities and tissue N content were measured monthly to quantify N incorporation to sustain eelgrass growth in Koje Bay on the south coast of Korea from January to December 2002. N acquisition was also estimated through measurements of N uptake kinetics, tissue biomass, and in situ inorganic N concentrations in water column and sediments. Above- and below-ground productivities were highest in summer and lowest in late fall and winter. Leaf tissue N content was highest in December and lowest in July, while rhizome tissue N content was highest in October and lowest in April. Estimated monthly N incorporation by leaf tissues based on the leaf productivity and N content ranged from 0.4 g N m?2 month?1 in November to 2.0 g N m?2 month?1 in May. N incorporation by below-ground tissues ranged from 0.1 g N m?2 month?1 in February to 0.2 g N m?2 month?1 in October. Annual whole plant N incorporation was 14.5 g N m?2 y?1, and N incorporation by leaf tissues accounted for about 87 % of total N incorporation. Maximum uptake rate (V max ) and half saturation constant (K m ) of leaf NH4 + uptake were significantly lower than those of root NH4 + uptake. Above- and below-ground biomass ranged from 20.8 g DW m?2 and 8.6 g DW m?2 in winter to 350.0 g DW m?2 and 81.3 g DW m?2 in spring, respectively. NH4 + concentrations varied from 0.2 to 4.3 mM in water column and from 93.0 to 551.7 mM in sediment pore water. Based on these measurements, annual N acquisition by root tissues contributed slightly higher than that by leaf tissues to total plant N acquisition. During winter, monthly leaf N acquisition was lower than monthly leaf N incorporation. This implies that Z. marina has internal nitrogen retention system to offset the shortage and excess of nitrogen. 相似文献
50.
Calibration chamber tests were conducted on open‐ended model piles driven into dried siliceous sands with different soil conditions in order to clarify the effect of soil conditions on load transfer mechanism in the soil plug. The model pile used in the test series was devised so that the bearing capacity of an open‐ended pile could be measured as three components: outside shaft resistance, plug resistance, and tip resistance. Under the assumption that the unit shaft resistance due to pile‐soil plug interaction varies linearly near the pile tip, the plug resistance was estimated. The plug capacity, which was defined as the plug resistance at ultimate condition, is mainly dependent on the ambient lateral pressure and relative density. The length of wedged plug that transfers the load decreases with the decrease of relative density, but it is independent of the ambient pressure and penetration depth. Under several assumptions, the value of earth pressure coefficient in the soil plug can be calculated. It gradually reduces with increase in the longitudinal distance from the pile tip. At the bottom of the soil plug, it tends to decrease with increase in the penetration depth and relative density, and to increase with the increase of ambient pressure. This may be attributed to (1) the decrease of friction angle as a result of increase in the effective vertical stress, (2) the difference in the dilation degree of the soil plug during driving with ambient pressures, and (3) the difference in compaction degree of soil plug during driving with relative densities. Based on the test results, an empirical equation was suggested to compute the earth pressure coefficient to be used in the calculation of plug capacity using one‐dimensional analysis, and it produces proper plug capacities for all soil conditions. 相似文献