Mineralogical and isotopic properties of inorganic nanocrystalline magnetites     

Damien Faivre  Pierre Agrinier  Pierpaolo Zuddas  Katavut Pachana  Jean-Yves Laval 《Geochimica et cosmochimica acta》2004,68(21):4395-4403

Inorganic magnetite nanocrystals were synthesized in an aqueous medium at 25°C, atmospheric pressure, ionic strength of 0.1 M, oxygen fugacity close to 0, and under controlled chemical affinity, which was maintained constant during an experiment and varied between different experiments. The total concentration of iron in the initial solutions, with Fe(III)/Fe(II) ratios of 2, was varied in order to measure the role of this parameter on the reaction rate, particle morphology, and oxygen isotopic composition. The reaction rates were followed by a pHstat apparatus. The nature and morphology of particles were studied by transmission electron microscopy and electron energy loss spectroscopy. Fractionation factors of oxygen isotopes were determined by mass spectrometry after oxygen extraction from the solid on BrF₅ lines. At low total iron concentrations, goethite and poorly crystalline iron oxides were observed coexisting with magnetite. At higher concentrations, euhedral single crystals of pure magnetite with an average characteristic size of 10 nm were formed, based on a first-order rate law with respect to total iron concentration. These results confirm that, under high supersaturation conditions, low-temperature inorganic processes can lead to the formation of well-crystallized nanometric magnetite crystals with narrow size distribution. The observed oxygen isotope fractionation factor between magnetite crystals and water was of 0-1‰, similar to the fractionation factor associated with bacterially produced magnetite. We suggest that the solution chemistry used in this study for inorganic precipitation is relevant to better understanding of magnetite precipitation in bacterial magnetosomes, which might thus be characterized by high saturation states and pH.  相似文献   

Determination of cirrus radiative parameters from combination between active and passive remote sensing measurements during FRENCH/DIRAC 2001     

Grard Brogniez  Frdric Parol  Laurianne Bcu  Jacques Pelon  Olivier Jourdan  Jean-Franois Gayet  Frdrique Auriol  Christian Verwaerde  Jean-Yves Balois  Bahaiddin Damiri 《Atmospheric Research》2004,72(1-4):425

In the context of the next AQUA Train satellite experiment, airborne measurements were carried out to simulate satellite measurements. They were conducted between September 25 and October 12, 2001, off the coast of southern France over the Atlantic Ocean and over the Mediterranean Sea, respectively. During the intensive Field Radiation Experiment on Natural Cirrus and High-level clouds (FRENCH/DIRAC 2001), natural ice clouds were sampled from in situ and remote sensing measurements. On October 5 and 7, 2001, cirrus cloud decks were described by a complete data set acquired by: (i) in situ microphysical instruments onboard the TBM-700 aircraft: PMS probe, and Polar Nephelometer (ii) and downward-looking radiative instruments onboard the Mystère 20 aircraft: an infrared radiometer, a lidar, a visible imager with polarisation capabilities, and a middle infrared radiometer. Moreover, classical thermodynamical measurements were carried out onboard the Mystère 20. Mean microphysical characteristics of cirrus deck are derived from interpretation of remote sensing measurements. These properties are compared with those derived from in situ microphysical measurements in order to evaluate the radiative impact of natural cirrus clouds.  相似文献   

Comment on “segmentation and disruption of the East Pacific Rise in the mouth of the Gulf of California” by Peter Lonsdale (Marine Geophysical Researches 17, pp. 323–359, 1995)     

François Michaud  Jean-Yves Royer  Jacques Bourgois  Bernard Mercier De Lepinay 《Marine Geophysical Researches》1996,18(5):597-599

  相似文献   

Structure of the Malpelo Ridge (Colombia) from seismic and gravity modelling     

Boris Marcaillou  Philippe Charvis  Jean-Yves Collot 《Marine Geophysical Researches》2006,27(4):289-300

Wide-angle and multichannel seismic data collected on the Malpelo Ridge provide an image of the deep structure of the ridge and new insights on its emplacement and tectonic history. The crustal structure of the Malpelo Ridge shows a 14 km thick asymmetric crustal root with a smooth transition to the oceanic basin southeastward, whereas the transition is abrupt beneath its northwestern flank. Crustal thickening is mainly related to the thickening of the lower crust, which exhibits velocities from 6.5 to 7.4 km/s. The deep structure is consistent with emplacement at an active spreading axis under a hotspot like the present-day Galapagos Hotspot on the Cocos-Nazca Spreading Centre. Our results favour the hypothesis that the Malpelo Ridge was formerly a continuation of the Cocos Ridge, emplaced simultaneously with the Carnegie Ridge at the Cocos-Nazca Spreading Centre, from which it was separated and subsequently drifted southward relative to the Cocos Ridge due to differential motion along the dextral strike-slip Panama Fracture Zone. The steep faulted northern flank of the Malpelo Ridge and the counterpart steep and faulted southern flank of Regina Ridge are possibly related to a rifting phase that resulted in the Coiba Microplate’s separation from the Nazca Plate along the Sandra Rift.  相似文献   

Seismological study of the central Ecuadorian margin: Evidence of upper plate deformation     

Nicole Bethoux  Monica Segovia  Viviana Alvarez  Jean-Yves Collot  Philippe Charvis  Audrey Gailler  Tony Monfret 《Journal of South American Earth Sciences》2011,31(1):139-152

A seismic study of a segment of the convergent margin of Ecuador is presented. During the SISTEUR campaign a network of 24 Ocean Bottom Seismometers (OBS) was deployed on the Carnegie Ridge, one line along the main axes of the ridge and two lines across the strike of the edge of the ridge, during one month. This marine network was complemented with a land network of 20 stations distributed in two lines: one parallel to the margin and the other perpendicular to it.The seismic event recorded by these networks, were located using different crustal models defined from the wide-angle seismic data modeling. Relative location techniques were used to improve earthquake locations. Seismogram waveform modeling allowed us to constrain hypocentral location for events farther than ～50 km from the network. This modeling also provided additional information to constrain the focal mechanisms of these events. The upper limit of the Interplate Seismogenic Zone (ISZ) is estimated to be at a 10 km depth in the region. The background seismic activity of the upper plate provided new insights:1) A seismic cluster that reaches the base of the overriding plate is linked to the Jipijapa-Portoviejo fault. The reactivation of this Quaternary fault is confirmed by focal mechanisms that provide rupture planes parallel to its superficial projection (N10°–N25°).2) The focal mechanisms presented in this study are compatible with a homogeneous regional stress field corresponding to an E–W to ESE–WNW compression and an NNE–SSW extension. The presence of strike-slip deformation, with a reverse component, corresponds to the NNE escape of the North Andean Block. Normal faulting accommodating this movement suggests that this part of the North Andean Block cannot be considered as a rigid block.  相似文献   

Les argiles bleues du Cambrien inférieur de Saint-Pétersbourg et leur fissuration. Implications pour des stockages souterrains     

Marcel Arnould  Jean-Yves Boisson  Ivan P Ivanov 《Comptes Rendus Geoscience》2002,334(16):1135

The Lower Cambrian Saint Petersburg blue clays are composed of predominant illite and chlorite, sometimes accompanied by kaolinite. The <0.1 μm fraction has a high content of illite–smectite mixed layers. Particle-size distribution is more than 50% of clay particles and about 30% of silts. These blue clays correspond to plastic (and soft) clays; they may be compared to the Callovian clays of Bure (France), where storage of natural waste is envisaged. To cite this article: M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.

Résumé

Les « argiles bleues » du Cambrien Inférieur de Saint-Pétersbourg sont constituées d'illite dominante et de chlorite, avec parfois présence de kaolinite. Des interstratifiés illite/montmorillonite sont très abondants dans la phase <0,1 μm. Du point de vue granulométrique, outre plus de 50% de particules argileuses, il existe une phase silteuse de l'ordre de 30%. Du point de vue pétrophysique, ce sont des argiles plastiques, de consistance molle. Elles sont subhorizontales et ont jusqu'à 116 m d'épaisseur. Outre l'absence de métamorphisme, malgré leur âge, leur caractère le plus remarquable est leur réseau de fracturation, bien observable en carrière. Les joints sont nets, sans remplissage ni cimentation. Les plans verticaux sont particulièrement développés. Le volume unitaire des blocs de matrice ne dépasse guère 1 m³. Des traces d'oxydation témoignent de circulations d'eau. Ces argiles silteuses anciennes peuvent aider à mieux connaı̂tre et comprendre les argilites silteuses épigénétiques calloviennes du site de Bure (Haute-Marne, France), où un stockage souterrain de déchets nucléaires est envisagé. Pour citer cet article : M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.  相似文献   

Enhancement of regional variations in salinity and temperature in a coral reef lagoon, New Caledonia     

Sylvain Ouillon  Pascal Douillet  Renaud Fichez  Jean-Yves Panch 《Comptes Rendus Geoscience》2005,337(16):231

The variability in salinity and temperature in the southwest lagoon of New Caledonia (2100 km²) under non-storm conditions is analysed using a 4-year dataset (1997–2001). Seasonal and interannual variations in salinity are amplified nearshore. Temperature is larger in bays than in the open lagoon during summer, the reverse is true in winter. El Niño Southern Oscillation (ENSO) related nearshore temperature variations parallel those at regional scale, but with seasonal variations amplified. Haline stratification, if any, is enhanced in coastal areas. To cite this article: S. Ouillon et al., C. R. Geoscience 337 (2005).  相似文献   

New Early Permian paleomagnetic results from the Brive basin (French Massif Central) and their implications for Late Variscan tectonics     

Yan Chen  Bernard Henry  Michel Faure  Jean-François Becq-Giraudon  Jean-Yves Talbot  Lucien Daly  Maxime Le Goff 《International Journal of Earth Sciences》2006,95(2):306-317

In order to assess the structural evolution of the Brive basin and the Paleozoic activity of surrounding major faults in the French Massif Central, we carried out a paleomagnetic study on Early Permian rocks from this basin. Positive-fold tests and solely reversed polarities indicate that the characteristic remanent magnetization is likely to be primary. Early Permian tilt-corrected site mean declinations vary from 207°–167° indicating that the Brive basin experienced internal vertical-axis rotations. On the contrary, Late Permian paleomagnetic site means exhibit a circular Fisherian distribution showing no relative rotations. Detailed analyses of Permian paleomagnetic data from five contemporaneous basins of the French Massif Central reveal that these basins share the same equatorial paleolatitude with stable Europe throughout the Permian. However, in Early Permian, three of the five basins experienced differential rotations. The Saint-Affrique basin not only suffered internal deformation during the Early Permian, but the basin as a whole underwent a full-scale counterclockwise vertical-axis block rotation with respect to stable Europe. As a consequence, paleomagnetic data from similar late orogenic basins have to be thus carefully considered for establishment of Apparent Polar Wander paths.  相似文献   

Establishing irrigation potential of a hillside aquifer in the African highlands     

Seifu A. Tilahun  Debebe L. Yilak  Petra Schmitter  Fasikaw A. Zimale  Simon Langan  Jennie Barron  Jean-Yves Parlange  Tammo S. Steenhuis 《水文研究》2020,34(8):1741-1753

Feeding 9 billion people in 2050 will require sustainable development of all water resources, both surface and subsurface. Yet, little is known about the irrigation potential of hillside shallow aquifers in many highland settings in sub-Saharan Africa that are being considered for providing irrigation water during the dry monsoon phase for smallholder farmers. Information on the shallow groundwater being available in space and time on sloping lands might aid in increasing food production in the dry monsoon phase. Therefore, the research objective of this work is to estimate potential groundwater storage as a potential source of irrigation water for hillside aquifers where lateral subsurface flow is dominant. The research was carried out in the Robit Bata experimental watershed in the Lake Tana basin which is typical of many undulating watersheds in the Ethiopian highlands. Farmers have excavated more than 300 hand dug wells for irrigation. We used 42 of these wells to monitor water table fluctuation from April 16, 2014 to December 2015. Precipitation and runoff data were recorded for the same period. The temporal groundwater storage was estimated using two methods: one based on the water balance with rainfall as input and baseflow and evaporative losses leaving the watershed as outputs; the second based on the observed rise and fall of water levels in wells. We found that maximum groundwater storage was at the end of the rain phase in September after which it decreased linearly until the middle of December due to short groundwater retention times. In the remaining part of the dry season period, only wells located close to faults contained water. Thus, without additional water sources, sloping lands can only be used for significant irrigation inputs during the first 3 months out of the 8 months long dry season.  相似文献