Weathering of phlogopite in simulated bioleaching solutions     

Tariq M. Bhatti  Jerry M. Bigham  Antti Vuorinen  Olli H. Tuovinen 《International Journal of Mineral Processing》2011,98(1-2):30-34

The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH₄⁺, K⁺, or Na⁺) in the culture solution. NH₄⁺ and K⁺ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na⁺ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.  相似文献   

Book review: Too Hot to Touch: The Problem of High-Level Nuclear Waste, by William M. Alley and Rosemarie Alley (Cambridge University Press, 2013)     

Leonard F. Konikow 《Hydrogeology Journal》2013,21(8):1909-1910

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Response and recovery of the Eel River, California, and its tributaries to floods in 1955, 1964, and 1997     

Jan Sloan  Jerry R. Miller  Nicholas Lancaster 《Geomorphology》2001,36(3-4)

Northwestern California is prone to regional, high magnitude winter rainstorms, which repeatedly produce catastrophic floods in the basins of the northern Coast Ranges. Major floods on the Eel River in 1955 and 1964 resulted in substantial geomorphic changes to the channel, adjacent terraces, and tributaries. This study evaluated the changes and the effects of a moderate flood in 1997 through field observations and examination of aerial photographs that spanned from 1954 to 1996. The purpose was to document the nature and magnitude of geomorphic responses to these three floods and assess the rates and controls on the recovery of the Eel River and its tributaries. Channel widening from extensive bank erosion was the dominant geomorphic change along the lower Eel River during major floods. As a result of the 1964 flood, the largest amount of widening was 195 m and represented an 80% change in channel width. Channel narrowing characterized the periods after the 1955 and 1964 floods. More than 30 years after the 1964 flood, however, the river had not returned to pre-flood width, which suggests that channel recovery required decades to complete. A long recovery time is unusual given that the Eel River is located in an area with a “superhumid” climate and has an exceptionally high sediment yield. This long recovery time may reflect highly seasonal precipitation and runoff, which are concentrated in 3–5 months each winter. In contrast to the main stem of the Eel River, the dominant effects of floods on the tributaries of the Eel River were rapid aggradation of channel bed and valley floor followed by immediate downcutting. Dendrogeomorphic data, aerial photographs, and field observations indicate that thick wedges of gravel, derived largely from hillslope failures in upper reaches of the tributaries, are deposited at and immediately upstream of the mouths of tributaries as the stage of the Eel River exceeded that of the tributaries during major floods. In the waning stages of the flood, the tributaries cut through the gravel at a rate equal to the lowering of the Eel and generated unpaired terraces and nickpoints. The complete process of deposition and incision can occur within a few days of peak discharge. Although reworking of some sediment on the valley floor may continue for years after large floods, channel morphology in the tributaries appears to be a product of infrequent, high magnitude events. The morphology of the tributary channel also appears to be greatly influenced by the frequency and magnitude of mass wasting in headwater areas of small basins.  相似文献   

Application of biomarkers for improving risk assessments of chemicals under the Water Framework Directive: a case study     

Hagger JA  Jones MB  Lowe D  Leonard DR  Owen R  Galloway TS 《Marine pollution bulletin》2008,56(6):1111-1118

To answer the requirement of the European Commission's Water Framework Directive (WFD) for biological-effects endpoints to classify the ecological health of aquatic ecosystems, we propose the biomarker response index (BRI). The BRI, based on a suite of biomarkers at different levels of biological response at the individual level, provides an integrated relative measure of the general health status of coastal invertebrates. Using the BRI, the health of mussels (Mytilus edulis) from 10 estuaries classified by the Environment Agency of England and Wales under the WFD was compared. Eight sites were healthier than predicted and two showed a similar health status to that of the predicted point-source pollution risk classification. Results indicate that the BRI offers a potential measure of organism health that can be used in monitoring under the WFD as an additional aid to reduce uncertainty in defining risk classification and to provide better evidence of existing impact.  相似文献   

Implications of the saltation–abrasion bedrock incision model for steady‐state river longitudinal profile relief and concavity     

Leonard S. Sklar  William E. Dietrich 《地球表面变化过程与地形》2008,33(7):1129-1151

The saltation–abrasion model predicts rates of river incision into bedrock as an explicit function of sediment supply, grain size, boundary shear stress and rock strength. Here we use this experimentally calibrated model to explore the controls on river longitudinal profile concavity and relief for the simple but illustrative case of steady‐state topography. Over a wide range of rock uplift rates we find a characteristic downstream trend, in which upstream reaches are close to the threshold of sediment motion with large extents of bedrock exposure in the channel bed, while downstream reaches have higher excess shear stresses and lesser extents of bedrock exposure. Profile concavity is most sensitive to spatial gradients in runoff and the rate of downstream sediment fining. Concavity is also sensitive to the supply rate of coarse sediment, which varies with rock uplift rate and with the fraction of the total sediment load in the bedload size class. Variations in rock strength have little influence on profile concavity. Profile relief is most sensitive to grain size and amount of runoff. Rock uplift rate and rock strength influence relief most strongly for high rates of rock uplift. Analysis of potential covariation of grain size with rock uplift rate and rock strength suggests that the influence of these variables on profile form could occur in large part through their influence on grain size. Similarly, covariation between grain size and the fraction of sediment load in the bedload size class provides another indirect avenue for rock uplift and strength to influence profile form. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Glacial isostatic adjustment in 3-D earth models: Implications for the analysis of tide gauge records along the U.S. east coast     

Jonathan E. Davis  Konstantin Latychev  Jerry X. Mitrovica  Roblyn Kendall  Mark E. Tamisiea 《Journal of Geodynamics》2008,46(3-5):90

Tide gauge records of recent sea-level change along the U.S. east coast have received significant attention within the literature of glacial isostatic adjustment (GIA). Geographic trends in these tide gauge rates are not reduced by a GIA correction based on a commonly adopted radial viscosity profile (characterized, in particular, by a lower mantle viscosity 1−2×10²¹ Pa s), and this has led to speculation that the residual trends reflect contributions from neotectonics or oceanographic processes. While the trends can be significantly reduced by adopting an Earth model with a stiffer lower mantle, such a model appears to be incompatible with independent constraints from post-glacial decay times in Hudson Bay. We use a finite-element model of the GIA process to investigate whether 3-D viscosity variations superimposed onto the “common” radial viscosity profile may provide a route to reconciling the east coast sea-level trends. We find that the specific 3-D structure we impose has little impact on the geographic trends in the GIA-corrected rates. However, we do find that the imposed lateral variations in lower mantle viscosity introduce a nearly uniform upward shift of 0.5 mm/yr in GIA-induced sea-level rates along the U.S. east coast. Thus, inferences of regional (U.S. east coast) sea-level rise due to modern melting of ice reservoirs, based on tide gauge rates corrected using 1-D GIA models, may be significantly biased by this simplifying assumption.  相似文献   

Utility of the 2-D Multi-Electrode Resistivity Imaging Technique in Groundwater Exploration in the Voltaian Sedimentary Basin, Northern Ghana   总被引：2，自引：0，他引：2  

Anthony Ewusi  Jerry S. Kuma  Hans J. Voigt 《Natural Resources Research》2009,18(4):267-275

Guinea worm and other water borne diseases associated with untreated surface water use have necessitated that communities are supplied with groundwater in the Northern Region of Ghana. The Electrical Resistivity Survey (ERS) method is one of the common geophysical survey techniques used for borehole siting in Ghana. Various groundwater exploration programs have utilized it by employing the four electrode system. However, the ERS has not been able to locate potential borehole sites successfully in the Voltaian Sedimentary Basin (VSB) in the Northern Region of Ghana although it has been successful in other geological formations. Unsatisfactory results obtained from the employment of the ERS system in the VSB therefore necessitated an experiment with the 2-D Multi-Electrode Resistivity Imaging (2-D MERI) technique. Field results show that the 2-D MERI is a robust and efficient technique: an improvement on the four electrode ERS system in terms of amount and quality of data obtained. The 2-D MERI interpretations were confirmed with a much improved borehole drilling success rate of 60% compared to 38% obtained using the ERS within the mudstone and shale formations. The 2-D MERI also indicated that very low resistivity layers in the VSB may not necessarily be good targets for borehole drilling and the generally held notion that groundwater cannot be found at depths more than 25 m is no longer tenable.  相似文献   

Surface loading of a viscoelastic planetIII. Aspherical models     

Jeroen Tromp  & Jerry X. Mitrovica 《Geophysical Journal International》2000,140(2):425-441

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Archaeological geology of the Rustad Quarry site (32RI775): An early archaic site in Southeastern North Dakota     

Garry Leonard Running 《Geoarchaeology》1995,10(3):183-204

At The Rustad Quarry Site (32RI775), in southeastern North Dakota, Early Archaic artifacts, bison bone, and hearth features were found in the lowest of three Boroll-like buried soils formed in alluvial fan sediments. Alluvial fan sediments were deposited from 8000 to 4925 B.P., and were then buried by eolian sand. The alluvial fan sediments (mudflows) bury lacustrine sediments (Sherack Formation deposited from 9900 to 9500 B.P. in Glacial Lake Agassiz II), both of which overlie a Moorhead Phase fluvial terrace deposited from 10,900 to 9,900 B.P. Cultural remains were associated with five radiocarbon ages, three on archaeological charcoal (7180 B.P., 7240 B.P., and 7550 B.P.) and two on organic carbon from two welded A-horizons containing the cultural remains (7370 B.P. and 7675 B.P.). A well-developed Aquoll-like soil formed in the lacustrine sediments from 9500 to 8000 B.P. Soil morphology and chemistry of the Boroll-like fan soils, the Aquoll-like lacustrine soil, and other Boroll-like soils formed in eolian and deltaic sediments nearby suggest a subhumid, cool continental climate with riparian woodland and mixed prairie vegetation at the site and surrounding area from 11,400 B.P. to the present. This partially contradicts paleoenvironmental reconstruction from pollen sites nearby that suggest the area was covered by a closed canopy spruce forest from terminal late-Pleistocene to 10,000 B.P. Alluvial fan formation and eolian activity on the adjacent Sheyenne Delta occurred from 8000 to 5000 B.P., which indicates greater landscape instability and drier conditions during the mid-Holocene (Altithermal).  相似文献   

The Ultimate CCD for Laser Guide Star Wavefront Sensing on Extremely Large Telescopes     

James W. Beletic  Sean Adkins  Barry Burke  Robert Reich  Bernie Kosicki  Vyshnavi Suntharalingham  Charlie Bleau  Ray DuVarney  Richard Stover  Jerry Nelson  Francois Rigaut 《Experimental Astronomy》2005,19(1-3):103-109

All of the extremely large telescopes (ELTs) will utilize sodium laser guide star (LGS) adaptive optics (AO) systems. Most of these telescopes plan to use the Shack-Hartmann approach for wavefront sensing. In these AO systems, the laser spots in subapertures at the edge of the pupil will suffer from spot elongation due to the 10 km extent of the sodium layer and the large separation from the projection laser. This spot elongation will severely degrade the performance of standard geometry wavefront sensing systems. In this paper, we present a CCD with custom pixel morphology that aligns the pixels of each subaperture with the radial extension of the LGS spot. This CCD design will give better performance than a standard geometry CCDs for continuous wave lasers. In addition, this CCD design is optimal for a pulsed sodium laser. The pixel geometry enables each subaperture to follow a laser pulse traversing the sodium layer, providing optimal sampling of a limited number of detected photons. In addition to novel pixel layout, this CCD will also incorporate experimental JFET sense amplifiers and use CMOS design approaches to simplify the routing of biases, clocks and video output. This CCD will attain photon-noise limited performance at high frame rates, and is being incorporated in the plans for the Thirty Meter Telescope (TMT).  相似文献