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Water Resources - With conventional monitoring at low-frequency, biological responses to weather-related events are missed. In this paper, we examine the chlorophyll-a concentrations in a shallow...  相似文献   
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Highly depleted harzburgites and dunites were recovered from ODP Hole 1274A, near the intersection between the Mid-Atlantic Ocean Ridge and the 15°20′N Fracture Zone. In addition to high degrees of partial melting, these peridotites underwent multiple episodes of melt–rock reaction and intense serpentinization and seawater alteration close to the seafloor. Low concentrations of Se, Cu and platinum-group elements (PGE) in harzburgites drilled at around 35–85 m below seafloor are consistent with the consumption of mantle sulfides after high degrees (>15–20 %) of partial melting and redistribution of chalcophile and siderophile elements into PGE-rich residual microphases. Higher concentrations of Cu, Se, Ru, Rh and Pd in harzburgites from the uppermost and lowest cores testify to late reaction with a sulfide melt. Dunites were formed by percolation of silica- and sulfur-undersaturated melts into low-Se harzburgites. Platinum-group and chalcophile elements were not mobilized during dunite formation and mostly preserve the signature of precursor harzburgites, except for higher Ru and lower Pt contents caused by precipitation and removal of platinum-group minerals. During serpentinization at low temperature (<250 °C) and reducing conditions, mantle sulfides experienced desulfurization to S-poor sulfides (mainly heazlewoodite) and awaruite. Contrary to Se and Cu, sulfur does not record the magmatic evolution of peridotites but was mostly added in hydrothermal sulfides and sulfate from seawater. Platinum-group elements were unaffected by post-magmatic low-temperature processes, except Pt and Pd that may have been slightly remobilized during oxidative seawater alteration.  相似文献   
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The January 25, 2016, Mw 6.3 Alborán Sea earthquake shook the autonomous city of Melilla (Spain) with a macro-seismic intensity of VI (EMS-98). In spite of this low intensity, significant non-structural damages were reported, whose cost was estimated in more than 13 million euros. The damages were concentrated in the modernist district, which is considered the most important and valuable part of the city. This scenario is not new in Melilla, since historical and instrumental seismicity studies based on intensities felt in Melilla have revealed that earthquakes with intensities of V–VI have a return period of approximately 25 years. However, seismic microzonation studies have not been carried out so far. In this paper, we present a seismic microzonation study based on seismic noise measurements and the foreshock, mainshock and aftershock records of the January 25, 2016, earthquake. The seismic signals were processed using the horizontal-to-vertical spectral ratio (HVSR) technique. The frequency amplification results were correlated with geological formations, and after that they were correlated with the distribution of damages. The lagoon and the recent alluvial deposits show the maximum number of damaged buildings and maximum frequency amplifications of 2–8 between 2 and 7 Hz. In the coastal deposits, some amplification in the same frequency range has been observed, but other formations show a minimum number of damaged buildings and a flat spectral response ratio. Two important factors in this damage pattern are the high vulnerability of ornamental facades characteristics (non-structural elements) of the modern architecture buildings and their location on the lagoon and the recent alluvial deposits where maximum site amplification is reached.

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Water chlorination continues to be one of the most common water disinfection processes, especially in developing countries. When natural organic matter (NOM) is present, the process produces disinfection by-products (DBPs), some of them being trihalomethanes (THMs). This study determined the presence, speciation, and kinetics of THMs formation in the water supply for the northern area of the city of Toluca, Mexico. The results show that the concentrations of THMs are below the maximum allowable limits of 200 μg/L in accordance with NOM-127-SSA1-1994. Regarding THMs speciation, the presence of chloroform was more frequently observed in domestic water; furthermore, in one sample in which bromoform was present, it dominated over the chlorine species. Regarding the kinetics of THMs formation, a maximum concentration of THMs (THMsMax) of 13.02 μg/L was obtained, and the time required to reach 50% THMsMax ( t 50) was 39.45 min.  相似文献   
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Summary Forty-two monthly rainfall time series from Spain have been analyzed for the presence of cycles and regional patterns. The study was carried out by means of periodicity tests devised by Whittle, Hannan, Bartlett, Siegel, and Priestley. These tests contribute to a mixed spectrum analysis leading to the evaluation of signals versus the background of coloured noise (autocorrelation). Also, a direct maximum entropy method (MEM) for estimating spectra was applied to the series, in particular an autoregressive (AR) power spectral density (psd) estimation, and an autoregressive moving average (ARMA) psd estimation, with parameters obtained by exact maximum likelihood estimator (MLE).With 4 Figures  相似文献   
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The compressibility of antigorite has been determined up to 8.826(8) GPa, for the first time by single crystal X-ray diffraction in a diamond anvil cell, on a specimen from Cerro del Almirez. Fifteen pressure–volume data, up to 5.910(6) GPa, have been fit by a third-order Birch–Murnaghan equation of state, yielding V 0 = 2,914.07(23) Å3, K T0 = 62.9(4) GPa, with K′ = 6.1(2). The compression of antigorite is very anisotropic with axial compressibilities in the ratio 1.11:1.00:3.22 along a, b and c, respectively. The new equation of state leads to an estimation of the upper stability limit of antigorite that is intermediate with respect to existing values, and in better agreement with experiments. At pressures in excess of 6 GPa antigorite displays a significant volume softening that may be relevant for very cold subducting slabs.  相似文献   
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We undertook two time-series photometric multisite campaigns for the rapidly oscillating Ap star HD 122970. The first one, conducted in 1998, resulted in 119 h of data and in the detection of three pulsation frequencies. The presence of possible further modes which held the promise of deriving a mode identification motivated a second worldwide campaign in the year 2001. This second campaign resulted in 203 h of measurement, but did not reveal further modes. Rather, one of the previously detected signals disappeared. The two modes common to both data sets have different spherical degree. They also showed slight frequency modulation, and one of them varied in amplitude as well. Possible causes of the latter behaviour include intrinsic instability of the pulsation spectrum or precession of the pulsational axis and orbital motion in a binary system. Frequency analysis of the Hipparcos observations of the star did not allow us to determine the stellar rotation period. The amplitude and phase behaviour of the two modes of HD 122970 in the Strömgren uvby bands is quite similar to that observed for other roAp stars.  相似文献   
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