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141.
Relations Between Aquifer Electrical and Hydraulic Properties 总被引:2,自引:0,他引:2
142.
143.
Nitrate and herbicide loading in two groundwater basins of Illinois'' sinkhole plain 总被引:1,自引:0,他引:1
This investigation was designed to estimate the mass loading of nitrate (NO3−) and herbicides in spring water discharging from groundwater basins in an agriculturally dominated, mantled karst terrain. The loading was normalized to land use and NO3− and herbicide losses were compared to estimated losses in other agricultural areas of the Midwestern USA. Our study area consisted of two large karst springs that drain two adjoining groundwater basins (total area of 37.7 km2) in southwestern Illinois' sinkhole plain, USA. The springs and stream that they form were monitored for almost 2 years. Nitrate–nitrogen (NO3–N) concentrations at three monitoring sites were almost always above the background concentration (1.9 mg/l). NO3–N concentrations at the two springs ranged from 1.08 to 6.08 with a median concentration of 3.61 mg/l. Atrazine and alachlor concentrations ranged from <0.01 to 34 μg/l and <0.01 to 0.98 μg/l, respectively, with median concentrations of 0.48 and 0.12 μg/l, respectively. Approximately 100,000 kg/yr of NO3–N, 39 kg/yr of atrazine, and 2.8 kg/yr of alachlor were discharged from the two springs. Slightly more than half of the discharged NO3− came from background sources and most of the remainder probably came from fertilizer. This represents a 21–31% loss of fertilizer N from the groundwater basins. The pesticide losses were 3.8–5.8% of the applied atrazine, and 0.05–0.08% of the applied alachlor. The loss of atrazine adsorbed to the suspended solid fraction was about 2 kg/yr, only about 5% of the total mass of atrazine discharged from the springs. 相似文献
144.
John M. Ferry Boswell A. Wing Sarah C. Penniston-Dorland Douglas Rumble 《Contributions to Mineralogy and Petrology》2002,142(6):679-699
Periclase formed in siliceous dolomitic marbles during contact metamorphism in the Monzoni and Predazzo aureoles, the Dolomites, northern Italy, by infiltration of the carbonate rocks by chemically reactive, H2O-rich fluids at 500 bar and 565-710 °C. The spatial distribution of periclase and oxygen isotope compositions is consistent with reactive fluid flow that was primarily vertical and upward in both aureoles with time-integrated flux ~5,000 and ~300 mol fluid/cm2 rock in the Monzoni and Predazzo aureoles, respectively. The new results for Monzoni and Predazzo are considered along with published studies of 13 other aureoles to draw general conclusions about the direction, amount, and controls on the geometry of reactive fluid flow during contact metamorphism of siliceous carbonate rocks. Flow in 12 aureoles was primarily vertically upward with and without a horizontal component directed away from the pluton. Fluid flow in two of the other three was primarily horizontal, directed from the pluton into the aureole. The direction of flow in the remaining aureole is uncertain. Earlier suggestions that fluid flow is often horizontal, directed toward the pluton, are likely explained by an erroneous assumption that widespread coexisting mineral reactants and products represent arrested prograde decarbonation reactions. With the exception of three samples from one aureole, time-integrated fluid flux was in the range 102-104 mol/cm2. Both the amount and direction of fluid flow are consistent with hydrodynamic models of contact metamorphism. The orientation of bedding and lithologic contacts appears to be the principal control over whether fluid flow was either primarily vertical or horizontal. Other pre-metamorphic structures, including dikes, faults, fold hinges, and fracture zones, served to channel fluid flow as well. 相似文献
145.
146.
Associations between place and wine are historically deep. Past and current narratives of wine production are wedded to environment attributes of particular places, and in both the European and Australasian settings this has been codified by way of formal labelling requirements for the place of origin for wines. In this paper we explore the role of place references on the front labels of Australian and New Zealand wines through a small initial survey. The results reveal that the importance of place references is stronger for New Zealand wines. We argue that this reflects strongly the very different structures of the industries in the two countries, with the emphasis for New Zealand producers on high-quality wines for which origin statements are expected as opposed to the Australian focus on the production of bulk, value-driven wines dependent on the blending of wines across regions and places. This in turn has implications for the future development and marketing trajectories of the two industries. 相似文献
147.
148.
Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquifer with pH values as high as 12.8. To understand the geochemistry of the alkaline ground water system, we analyzed samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH- in equilibrium with Ca(OH)2. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides and have not accumulated in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that metals can move through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline water. 相似文献
149.
Geotechnical properties of municipal sewage sludge 总被引:3,自引:0,他引:3
Brendan C. O’Kelly 《Geotechnical and Geological Engineering》2006,24(4):833-850
The geotechnical properties of municipal sewage sludge, in particular those pertinent to the handling and landfilling of the
material, are presented. Index, drying, compaction, shear strength and consolidation tests were conducted on the material
at different states of biodegradation. The organic content and specific gravity of solids were found to be inversely related,
with typical organic contents of 50–70% and specific gravity of solids values of 1.55–1.80. The density of the compacted material
was low in comparison with mineral soils. Standard Proctor compaction yielded a maximum dry density of 0.56 tonne/m3 at 85% water content. Laboratory vane-shear and triaxial compression tests indicated that, below about 180% water content,
the shear strength of the sludge material increased exponentially with reducing water content. Consolidated-undrained triaxial
compression tests on the pasteurised sludge material indicated an effective angle of shearing resistance of 32° for the moderately
degraded material and 37° for the strongly degraded material. Biogas was produced at rates of up to 0.33 L/day/kg slurry due
to ongoing biodegradation and the resulting pore pressure response must be taken into account in any stress analysis. Consolidation
tests using the hydraulic consolidation cell, oedometer and triaxial apparatus indicated that the sludge material was highly
compressible although practically impermeable, for example the coefficient of permeability for the moderately degraded slurry
was of the order of 10−9m/s. However, creep deformation was significant with typical coefficient of secondary compression values of 0.02–0.08 for
the compacted material. A more free-draining material was produced at higher states of biodegradation. 相似文献