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991.
Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater. 相似文献
992.
993.
A procedure to analyse triphenyltin and other organotins in fish tissues is described. The method consists of the following steps: homogenization of the fish, extraction by heating under reflux in a water/hexane mixture, centrifugation, separation of the hexane layer followed by reduction of the volume by evaporation, methylation of the organotin with a Grignard reaction, clean-up of the fish extract by column chromatography, and detection by gas chromatography with flame photometric detection. The extraction was carried out without adding acid or base to the aqueous phase, as the extraction efficiency was independent of pH. The methylation was successfully carried out in the fish extract. For clean-up of the fish extract a florisil column was used, from which the triphenylmethyltin was eluted with hexane. Using this method, triphenyltin has a recovery of 77 ± 10%, with a limit of detection of 0·8 ng/g for 0·1 g fish samples. 相似文献
994.
995.
A.C. Fischer J.J. Kroon T.G. Verburg T. Teunissen H.Th. Wolterbeek 《Marine Chemistry》2007,107(4):533-546
Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron 55Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10− 9 mol/m2 or 1.7 × 10− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log KFe'W = 11.0 ± 0.3 m2/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 −4–10− 5 L/s and rate constants for association in the order of 108 L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry. 相似文献
996.
997.
To study the long-term variability of the thermohaline and dynamic characteristics of the Black Sea, we use three versions
of climatic fields, namely, the fields reconstructed in the model according to the old (1903–1982) and new (1903–2003) hydrological
climatic data arrays of temperature and salinity and according to the data of satellite altimetry. The analysis of the altimetry-based
climatic fields confirms the distinctions (established earlier according to the old and new data arrays) in the seasonal variability
of the integral characteristics of temperature and salinity and in the structures of hydrophysical fields in the sea. It is
shown that, in the winter-spring season, the thermohaline fields reconstructed according to the new and altimetry data arrays
are characterized by a small elevation of the halocline (pycnocline) and the upper boundary of the cold intermediate layer.
In all seasons, the altimetry-based surface geostrophic currents contain numerous mesoscale eddies with different signs of
rotation. Moreover, in all seasons, the Rim Current reconstructed according to the altimetry data is characterized by a narrower
jet almost along the entire its length. This jet is especially intense near the coasts of West Anatolia.
__________
Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 3–17, July–August, 2006. 相似文献
998.
A coupling model for calculating wind-driven currents and waves in a shallow basin with allowance for current-wave interactions is introduced. The model is constructed on the basis of the three-dimensional σ-coordinate model of currents [3] and the SWAN (Simulating Waves Nearshore) spectral wave model [4]. The effect of waves on currents is taken into account in the coefficients of surface and bottom friction through roughness parameters. Results of combined modeling of stationary fields of currents and waves generated by spatially homogeneous wind are correlated with the corresponding results of separate modeling for a cylindrical basin of constant depth and the water area of Lake Donuzlav (the northwestern coast of the Crimea). The allowance for the effect of waves during calculation of tangential wind stresses in the model of currents is shown to be among major factors intensifying water circulation and forming spatial inhomogeneities of the vortex type. In addition, some cases of local decreases in tangential wind stresses are revealed; they appear when the lake is penetrated from the side of the open sea by relatively long waves, which significantly decrease the roughness of the water surface. 相似文献
999.
1000.