Les minéralisations Cu(NiBiUAuAg) d'Ifri (district du Haut Seksaoua,Maroc) : apport de l'étude texturale au débat syngenèse versus épigenèse     

Luc Barbanson  Alain Chauvet  Aziz Gaouzi  Lakhifi Badra  Mohamed Mechiche  Jean Claude Touray  Saı̈d Oukarou 《Comptes Rendus Geoscience》2003,335(14):1021-1029

The Cu ore of Ifri is a chalcopyrite stockwork hosted by Cambrian formations and was until now interpreted as a syngenetic massive sulphide deposit. Textural studies highlight two generations of pyrite early (Py I) and late (Py II) with respect to the regional deformation. The chalcopyrite stockwork overprinted Py II, outlining the epigenetic nature of the Cu mineralization. Regarding the origin of Cu-depositing fluids, the presence in the stockwork paragenesis of an U, W, Sn association and preliminary Pb/Pb dating of a brannerite belonging to this association suggest a contribution of the Tichka granite. To cite this article: L. Barbanson et al., C. R. Geoscience 335 (2003).  相似文献   

Is a management framework based on spawning-stock biomass indicators sustainable? A viability approach     

De Lara  Michel; Doyen  Luc; Guilbaud  Therese; Rochet  Marie-Joelle 《ICES Journal of Marine Science》2007,64(4):761-767

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Lithium Isotope Composition of Marine Biogenic Carbonates and Related Reference Materials          下载免费PDF全文

Luc Bastian  Nathalie Vigier  Stéphanie Reynaud  Marie‐Emmanuelle Kerros  Marie Revel  Germain Bayon 《Geostandards and Geoanalytical Research》2018,42(3):403-415

In this study, the accuracy and the precision corresponding to Li isotopic measurements of low level samples such as marine and coastal carbonates are estimated. To this end, a total of fifty‐four analyses of a Li‐pure reference material (Li7‐N) at concentrations ranging from 1 to 6 ng ml^?1 were first performed. The average δ⁷Li values obtained for solutions with and without chemical purification were 30.3 ± 0.4‰ (2s, n = 19) and 30.2 ± 0.4‰ (2s, n = 36), respectively. These results show that the chosen Li chemical extraction and purification procedure did not induce any significant isotope bias. Two available carbonate reference materials (JCt‐1 and JCp‐1) were analysed, yielding mean δ⁷Li values of 18.0 ± 0.27‰ (2s, n = 6) and 18.8 ± 1.8‰ (2s, n = 9), respectively. Small powder aliquots (< 15 mg) of JCp‐1 displayed significant isotope heterogeneity and we therefore advise favouring JCt‐1 for interlaboratory comparisons. The second part of this study concerns the determination of δ⁷Li value for biogenic carbonate samples. We performed a total of twenty‐nine analyses of seven different tropical coral species grown under controlled and similar conditions (24.0 ± 0.1 °C). Our sample treatment prior to Li extraction involved removal of organic matter before complete dissolution in diluted HCl. Our results show (a) a constant δ⁷Li within each skeleton and between the different species (δ⁷Li = 17.3 ± 0.7‰), and (b) a Li isotope fractionation of ?2‰ compared with inorganic aragonite grown under similar conditions. Comparison with literature data suggests a significant difference between samples living in aquaria and those grown in natural conditions. Finally, we investigate ancient (fossil) carbonate material and foraminifera extracted from marine sedimentary records. Different leaching procedures were tested using various HCl molarities. Results indicate that carbonate preferential dissolution must be carried out at an acid molarity < 0.18 mol l^?1. Possible contamination from silicate minerals can be verified using the Al/Ca ratio, but the threshold value strongly depends on the carbonate δ⁷Li value. When the silicate/carbonate ratio is high in the sediment sample (typically > 2), contamination from silicates cannot be avoided, even at low HCl molarity (? 0.1 mol l^?1). Finally, bulk carbonate and foraminifera extracted from the same core sample exhibited significant discrepancies: δ⁷Li values of foraminifera were more reproducible but were significantly lower. They were also associated with lower Sr/Ca and higher Mn/Ca ratios, suggesting a higher sensitivity to diagenesis, although specific vital effects cannot be fully ruled out.  相似文献   

Terrigenous input response to glacial/interglacial climatic variations over southern Baja California: a rock magnetic approach     

Ccile L. Blanchet  Nicolas Thouveny  Laurence Vidal  Guillaume Leduc  Kazuyo Tachikawa  Edouard Bard  Luc Beaufort 《Quaternary Science Reviews》2007,26(25-28):3118-3133

The sediments deposited off south-western Baja California have recorded millennial-scale fluctuations in biogenic compounds and trace metals accumulation during the last glacial period [Ortiz, J.D., O’Connell, S.B., DelViscio, J., Dean, W.E., Carriquiry, J.D., Marchitto, T., Zheng, Y., van Geen, A., 2004. Enhanced marine productivity off western North America during warm climate intervals of the past 52 ky. Geology 32, 521–524; Dean, W.E., Zheng, Y., Ortiz, J.D., van Geen, A., 2006. Sediment Cd and Mo accumulation in the oxygen-minimum zone off western Baja California linked to global climate over the past 52 ka. Paleoceanography 21, PA4209]. Since the variations in trace metals concentration appear to result from dilution with nonbiogenic matter, the variability of the terrigenous sedimentation needs to be addressed. Therefore, we performed rock magnetic and geochemical analysis on a 38 m-long sediment core collected from the slope off Baja California. The temporal framework provided by ¹⁴C dating and identification of palaeoclimatic transitions allows assigning the sequence to the last glacial–interglacial cycle (last 120 ka). The comparison of magnetic and geochemical properties led to retain the hypothesis of a primary modulation of iron oxides quantity and quality by terrigenous input variations, with a secondary diagenetic amplification. Two magnetic mineral input regimes are distinguished: (i) magnetic susceptibility variations reveal changes in titano-magnetite concentration related to fluvial transport of the terrigenous fraction; (ii) coercivity changes allow detecting variations of hematite or goethite concentrations, minerals generally issued from aeolian deflation of weathered rock surfaces. These two regimes are paced by two distinct climatic forcing: the millennial-scale changes in titano-magnetite input are related to the northern hemisphere climatic variability whilst the record of wind-blown magnetic mineral input contains its major power in the precessional frequency band, with higher input during low insolation periods (and conversely). This record highlights the great sensibility of this region to high and low latitudes climatic regimes.  相似文献   

Geochemical Sourcing of Flint Artifacts from Western Belgium and the German Rhineland: Testing Hypotheses on Gravettian Period Mobility and Raw Material Economy     

Luc Moreau  Michael Brandl  Peter Filzmoser  Christoph Hauzenberger  ric Goemaere  Ivan Jadin  Hlne Collet  Anne Hauzeur  Ralf W. Schmitz 《Geoarchaeology》2016,31(3):229-243

Identifying the geological and geographical origin of lithic raw materials is critical to effectively address prehistoric forager raw material economies and mobility strategies. Currently, Paleolithic archaeology in Belgium lacks a systematic sourcing strategy to effectively substantiate detailed interpretations of prehistoric hunter‐gatherer behavioral change across time and space. This pilot study evaluates the potential to “fingerprint” flint from the Mons Basin, western Belgium, using the laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) technique and a multivariate statistical analysis of 87 geological samples and 39 Gravettian period chipped stone artifacts. We reappraise two hypotheses raised by previous scholars based on visual raw material identification: (1) the Gravettian occupants of Maisières‐Canal supplied themselves with “black flint” from one single source; (2) the sites Rhens and Koblenz‐Metternich yielded artifacts indicative of long‐distance transfer of western Belgian flint into the German Rhineland, ca. 260 km from the primary source area. Our results demonstrate the validity of LA‐ICP‐MS data with flint and compositional data analysis for fingerprinting discrete geological formations from the Mons Basin. We suggest multiple source provisioning for Maisières‐Canal. Geochemical characterization of other potential flint sources is required to validate the long‐distance transfer hypothesis of western Belgian “black flint” into the German Rhineland.  相似文献   

Determination of Mercury in One Hundred and Sixteen Geological and Environmental Reference Materials Using a Direct Mercury Analyser          下载免费PDF全文

Barbara Marie  Luc Marin  Pierre‐Yves Martin  Tioga Gulon  Christophe Cloquet 《Geostandards and Geoanalytical Research》2015,39(1):71-86

The mercury content of 116 reference materials (RMs) from ten international organisations was determined in this study, which focused on variability within and between batches of RMs. Direct mercury analysis (DMA) was applied to RMs having Hg contents between 1 and 6300 ng g^?1 and provided good precision and accuracy. Accuracy was demonstrated by the agreement of our results with certified values, while replicates were made to establish the precision. Low within‐batch variability was noted, with precision from 0.1 to 23% (n = 3–5) apparently depending on Hg content and homogeneity, whereas systematic offsets were detected among several batches. Thanks to the analysis of different batches; the homogeneity or heterogeneity of several RMs was shown, and thus, suitable RMs for quality control for Hg determinations could be recommended.  相似文献   

A diatom-based Holocene record of human impact from a coastal environment: Tuckean Swamp, eastern Australia   总被引：1，自引：0，他引：1  

Kathryn H. Taffs  Luc J. Farago  Hendrik Heijnis  Geraldine Jacobsen 《Journal of Paleolimnology》2008,39(1):71-82

Diatom-based paleolimnological studies are being increasingly used to track anthropogenic change in estuaries. Little is known, however, about the direction and nature of long-term environmental changes in Australian estuaries. In this study, shifts in diatom assemblages preserved in a ²¹⁰Pb and C¹⁴ AMS dated sediment core from Tuckean Swamp were analysed to determine environmental changes that had taken place as a result of changing land-use practices. Prior to European impact, the diatom assemblage remained relatively stable and was dominated by Actinocyclus normanii and Diploneis smithii. An increasing dominance of Cyclotella meneghiniana correlates well with changed land use activities in the catchment area and indicates an increase of freshwater influence in the swamp’s environment. A major shift in species composition began ∼1970, Eunotia flexuosa becoming dominant. The assemblage shifts recorded at this site appear to be consistent with environmental changes triggered by human activities such as vegetation clearance, drainage and the construction of a barrage. This study demonstrates the use of paleolimnoology in an estuarine environment to provide pre-impact data necessary for management of the aquatic environment.  相似文献   

Land use change increases flood hazard: a multi-modelling approach to assess change in flood characteristics driven by socio-economic land use change scenarios     

Hounkpè  Jean  Diekkrüger  Bernd  Afouda  Abel A.  Sintondji  Luc Olivier Crepin 《Natural Hazards》2019,98(3):1021-1050

Natural Hazards - We analysed in the work how change in land use/land cover influences on flood characteristics (frequency and magnitude) using a model inter-comparison approach, statistical...  相似文献   

The sediment budget and dynamics of a delta‐canyon‐lobe system over the Anthropocene timescale: The Rhone River delta,Lake Geneva (Switzerland/France)     

Tiago A. Silva  Stphanie Girardclos  Laura Stutenbecker  Maarten Bakker  Anna Costa  Fritz Schlunegger  Stuart N. Lane  Peter Molnar  Jean‐Luc Loizeau 《Sedimentology》2019,66(3):838-858

Deltas are important coastal sediment accumulation zones in both marine and lacustrine settings. However, currents derived from tides, waves or rivers can transfer that sediment into distal, deep environments, connecting terrestrial and deep marine depozones. The sediment transfer system of the Rhone River in Lake Geneva is composed of a sublacustrine delta, a deeply incised canyon and a distal lobe, which resembles, at a smaller scale, deep‐sea fan systems fed by high discharge rivers. From the comparison of two bathymetric datasets, collected in 1891 and 2014, a sediment budget was calculated for eastern Lake Geneva, based on which sediment distribution patterns were defined. During the past 125 years, sediment deposition occurred mostly in three high sedimentation rate areas: the proximal delta front, the canyon‐levée system and the distal lobe. Mean sedimentation rates in these areas vary from 0·0246 m year^?1 (distal lobe) to 0·0737 m year^?1 (delta front). Although the delta front–levées–distal lobe complex only comprises 17·0% of the analysed area, it stored 74·9% of the total deposited sediment. Results show that 52·5% of the total sediment stored in this complex was transported toward distal locations through the sublacustrine canyon. Namely, the canyon–levée complex stored 15·9% of the total sediment, while 36·6% was deposited in the distal lobe. The results thus show that in deltaic systems where density currents can occur regularly, a significant proportion of riverine sediment input may be transferred to the canyon‐lobe systems leading to important distal sediment accumulation zones.  相似文献   

Restoring earth surface processes through landform design. A 13‐year monitoring of a geomorphic reclamation model for quarries on slopes     

J.F. Martín‐Duque  M.A. Sanz  J.M. Bodoque  A. Lucía  C. Martín‐Moreno 《地球表面变化过程与地形》2010,35(5):531-548

The application of geomorphic principles to land reclamation after surface mining has been reported in the literature since the mid‐1990s, mostly from Australia, Canada and the USA. This paper discusses the reclamation problems of contour mining and quarries on slopes, where steep gradients are prone to both mass movement and water erosion. To address these problems simultaneously, a geomorphic model for reclaiming surface mined slopes is described. Called the ‘highwall–trench–concave slope’ model, it was first applied in the 1995 reclamation of a quarry on a slope (La Revilla) in Central Spain. The geomorphic model does not reproduce the original topography, but has two very different sectors and objectives: (i) the highwall–trench sector allows the former quarry face to evolve naturally by erosion, accommodating fallen debris by means of a trench constructed at the toe of the highwall; (ii) the concave‐slope base sector, mimicking the landforms of the surrounding undisturbed landscape, promotes soil formation and the establishment of self‐sustaining, functional ecosystems in the area protected from sedimentation by the trench. The model improves upon simple topographic reconstruction, because it rebuilds the surficial geology architecture and facilitates re‐establishment of equilibrium slopes through the management and control of geomorphic processes. Thirteen years of monitoring of the geomorphic and edaphic evolution of La Revilla reclaimed quarry confirms that the area is functioning as intended: the highwall is backwasting and material is accumulating at the trench, permitting the recovery of soils and vegetation on the concave slope. However, the trench is filling faster than planned, which may lead to run‐off and sedimentation on the concave slope once the trench is full. The lesson learned for other scenarios is that the model works well in a two‐dimensional scheme, but requires a three‐dimensional drainage management, breaking the reclaimed area into several watersheds with stream channels. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献