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In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004). 相似文献
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Ricardo Sánchez‐Murillo Ana M. Durán‐Quesada Christian Birkel Germain Esquivel‐Hernández Jan Boll 《水文研究》2017,31(4):956-967
The last 2014‐16 El Niño event was among the three strongest episodes on record. El Niño considerably changes annual and seasonal precipitation across the tropics. Here, we present a unique stable isotope data set of daily precipitation collected in Costa Rica prior to, during, and after El Niño 2014‐16, in combination with Lagrangian moisture source and precipitation anomaly diagnostics. δ2H composition ranged from ‐129.4 to +18.1 (‰) while δ18O ranged from ‐17.3 to +1.0 (‰). No significant difference was observed among δ18O (P=0.186) and δ2H (P=0.664) mean annual compositions. However, mean annual d‐excess showed a significant decreasing trend (from +13.3 to +8.7 ‰) (P<0.001) with values ranging from +26.6 to ‐13.9 ‰ prior to and during the El Niño evolution. The latter decrease in d‐excess can be partly explained by an enhanced moisture flux convergence across the southeastern Caribbean Sea coupled with moisture transport from northern South America by means of an increased Caribbean Low Level Jet regime. During 2014‐15, precipitation deficit across the Pacific domain averaged 46% resulting in a very severe drought; while a 94% precipitation surplus was observed in the Caribbean domain. Understanding these regional moisture transport mechanisms during a strong El Niño event may contribute to a) better understanding of precipitation anomalies in the tropics and b) re‐evaluate past stable isotope interpretations of ENSO events in paleoclimatic archives within the Central America region. 相似文献
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Catherine Pierre Germain Bayon Marie-Madeleine Blanc-Valleron Jean Mascle Stéphanie Dupré 《Geo-Marine Letters》2014,34(2-3):253-267
On the passive margin of the Nile deep-sea fan, the active Cheops mud volcano (MV; ca. 1,500 m diameter, ~20–30 m above seafloor, 3,010–3,020 m water depth) comprises a crater lake with hot (up to ca. 42 °C) methane-rich muddy brines in places overflowing down the MV flanks. During the Medeco2 cruise in fall 2007, ROV dives enabled detailed sampling of the brine fluid, bottom lake sediments at ca. 450 m lake depth, sub-surface sediments from the MV flanks, and carbonate crusts at the MV foot. Based on mineralogical, elemental and stable isotope analyses, this study aims at exploring the origin of the brine fluid and the key biogeochemical processes controlling the formation of these deep-sea authigenic carbonates. In addition to their patchy occurrence in crusts outcropping at the seafloor, authigenic carbonates occur as small concretions disseminated within sub-seafloor sediments, as well as in the bottom sediments and muddy brine of the crater lake. Aragonite and Mg-calcite dominate in the carbonate crusts and in sub-seafloor concretions at the MV foot, whereas Mg-calcite, dolomite and ankerite dominate in the muddy brine lake and in sub-seafloor concretions near the crater rim. The carbonate crusts and sub-seafloor concretions at the MV foot precipitated in isotopic equilibrium with bottom seawater temperature; their low δ13C values (–42.6 to –24.5‰) indicate that anaerobic oxidation of methane was the main driver of carbonate precipitation. By contrast, carbonates from the muddy lake brine, bottom lake concretions and crater rim concretions display much higher δ13C (up to –5.2‰) and low δ18O values (down to –2.8‰); this is consistent with their formation in warm fluids of deep origin characterized by 13C-rich CO2 and, as confirmed by independent evidence, slightly higher heavy rare earth element signatures, the main driver of carbonate precipitation being methanogenesis. Moreover, the benthic activity within the seafloor sediment enhances aerobic oxidation of methane and of sulphide that promotes carbonate dissolution and gypsum precipitation. These findings imply that the coupling of carbon and sulphur microbial reactions represents the major link for the transfer of elements and for carbon isotope fractionation between fluids and authigenic minerals. A new challenge awaiting future studies in cold seep environments is to expand this work to oxidized and reduced sulphur authigenic minerals. 相似文献
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Karen T. Johnson Margie Wickham‐St. Germain Saebom Ko Scott G. Huling 《Ground Water Monitoring & Remediation》2012,32(3):84-92
Groundwater samples collected at sites where in situ chemical oxidation (ISCO) has been deployed may contain binary mixtures of groundwater contaminants and permanganate (MnO4–), an oxidant injected into the subsurface to destroy the contaminant. Commingling of the oxidant and contaminant in aqueous samples may negatively impact the quality of the sample as well as the analytical instruments used to quantify contaminant concentrations. In this study, binary mixtures comprised of (1) a multicomponent standard with permanganate and (2) groundwater samples collected at two ISCO field sites were preserved with ascorbic acid. Ascorbic acid reacts rapidly with the MnO4– and limits the reaction between MnO4– and the organic compounds in the mixture. Consequently, most of the compounds in the multicomponent standard were within the control limit for quality assurance. However, despite timely efforts to preserve the samples, the rapid reaction between permanganate and contaminant caused the concentration of several sensitive compounds to fall significantly below the lower control limit. Concentrations of volatile organic compounds in the field‐preserved binary mixture groundwater samples were greater than in samples refrigerated in the field and preserved upon arrival at the laboratory, indicating the time‐dependency and benefit of field preservation. The molar ratio of ascorbic acid required to neutralize KMnO4 was 1.64 (mol ascorbic acid/mol KMnO4); this provided a baseline to estimate the volume of ascorbic acid stock solution and/or the weight of crystalline ascorbic acid required to neutralize MnO4–. Excess ascorbic acid did not negatively impact the quality of the aqueous samples, or analytical instruments, used in the analyses. 相似文献
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Determination of Rare Earth Elements, Sc, Y, Zr, Ba, Hf and Th in Geological Samples by ICP-MS after Tm Addition and Alkaline Fusion 总被引：2，自引：0，他引：2
Germain Bayon Jean Alix Barrat Joël Etoubleau Mathieu Benoit Claire Bollinger Sidonie Révillon 《Geostandards and Geoanalytical Research》2009,33(1):51-62
We present a revised method for the determination of concentrations of rare earth (REE) and other trace elements (Y, Sc, Zr, Ba, Hf, Th) in geological samples. Our analytical procedure involves sample digestion using alkaline fusion (NaOH-Na2 O2 ) after addition of a Tm spike, co-precipitation on iron hydroxides, and measurement by sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS). The procedure was tested successfully for various rock types (i.e., basalt, ultramafic rock, sediment, soil, granite), including rocks with low trace element abundances (sub ng g−1 ). Results obtained for a series of nine geological reference materials (BIR-1, BCR-2, UB-N, JP-1, AC-E, MA-N, MAG-1, GSMS-2, GSS-4) are in reasonable agreement with published working values. 相似文献
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Ronan Le Bayon 《Swiss Journal of Geoscience》2012,105(2):171-181
A laboratory study was conducted to assess the effect of heat-up to high diagenetic to low metamorphic temperatures on vitrinite reflectance (VR) at high pressures using the same heat-up processes, apparatus and starting material as those employed in prior experimental studies on huminite/vitrinite maturation. ??Heat-up?? is the isobaric increase in temperature of an organic matter maturation experiment from room temperature to the desired run temperature T ehu (T ehu ?=?temperature at the end of heat-up). The experiments were performed on xylite of swamp cypress and used a heating rate of 50?°C/min. These confined system maturation experiments were carried out at 10?kbar and involved temperatures T ehu ranging from 175 to 450?°C. Additional experiments were conducted at pressures of 5, 20 and 25?kbar to evaluate the influence of pressure on the effect of heat-up on VR. At 10?kbar, results of this study show that heat-up does not influence VR for T ehu ?< ~270?°C. This absence of maturation is viewed as the result of an activation time delaying vitrinite maturation at these diagenetic to very low metamorphic temperatures. For T ehu ?> ~270?°C, heat-up has a significant effect on VR at 10?kbar: VR greatly increases with T ehu during the short heat-up event. This effect of heat-up on VR points out the rapid kinetics of the initial VR increase. Increasing pressure reduces VR increase gained during heat-up. Obviously, pressure retards the initial VR increase and thus controls organic matter maturation. In addition to temperature, the formulation of VR evolution rate equation must consider pressure, activation time and VR gained during heat-up. 相似文献
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M. Legrand C. Feniet-Saigne E. S. Saltzman C. Germain 《Journal of Atmospheric Chemistry》1992,14(1-4):245-260
A simultaneous glaciochemical study of methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO4
-) has been conducted on the Antarctic plateau (South Pole, Vostok) and in more coastal regions. The objective was to investigate marine sulfur emissions in very remote areas. Firstly, our data suggest that MSA and nss-SO4 present in antarctic ice are mainly marine in origin and that DMS emissions have been significantly modulated by short term (eg. El Nino Southern Oscillation events) as well as long term climatic changes in the past. Secondly, our study of spatial variations of these two sulfur species seems to indicate that the atmosphere of coastal antarctic regions are mainly supplied by local DMS emissions whereas the atmosphere of the high plateau is also influenced by DMS emissions from more temperate marine latitudes. Thirdly, our study of the partitioning between MSA and nss-SO4 suggest that the temperature could have been an important parameter controlling the final composition of the high southern latitude atmosphere over the last climatic cycle; colder temperature favoring the formation of MSA. However, our data also support a possible role played by changes in the transport pattern of marine air to the high antarctic plateau. 相似文献