Chemical Characterisation of Geological Raw Materials Used in Traditional Ceramics     

Maria Fernanda Gazulla  Maria Pilar Gomez  Antonio Barba  Monica Orduña 《Geostandards and Geoanalytical Research》2004,28(2):203-212

A wide range of natural raw materials is used in the manufacture of traditional ceramic products such as ceramic tiles, frits, glazes and pigments. The chemical composition of these raw materials needs to be strictly controlled to assure end-product quality and enable the identification of the origin of defects caused by impurities or contamination. Six types of ceramic raw materials (silica sand, clays and kaolin, feldspars and related minerals, calcium and magnesium carbonates, sodium and calcium borates, and zirconium silicates) have been analysed in this study. X-ray fluorescence (XRF), potentiometry, coulometry and atomic absorption spectrometry (AAS) were used in this chemical characterisation. A methodology has been established for characterising each studied raw material, by identifying the chemical elements to be determined, selecting the most appropriate technique and validating each measurement. The reference materials used for validation were BCS CRM 267, 313/1, 393 and 388 (BAS), GBW 03103, GBW 07404, NIST SRM 181, 201a and 1835, Euronorm CRM 782-1 and Syenite SY-2. The results showed that most of the elements present in the geological samples used as traditional ceramic raw materials could be determined by XRF. The determination of light elements, such as lithium, fluorine and boron, is more suitably conducted by ICP-AES/AAS, potentiometry or potentiometry/ICP-AES respectively. Organic and inorganic carbon could be determined by coulometry. Inorganic carbon (CO₂) could also be determined by coulometry or by thermogravimetry, if samples did not contain clay minerals. Loss on ignition was always determined by gravimetry.  相似文献   

Determination of Platinum-Group Elements in Geological Reference Materials by High Resolution-ICP-MS after Nickel Sulfide Fire-Assay Collection and Te Co-Precipitation     

Claudia P.R. Morcelli  Ana Maria G. Figueiredo  Jacinta Enzweiler  Jorge E.S. Sarkis  Alexandre P.S. Jorge  Maurício Kakazu 《Geostandards and Geoanalytical Research》2004,28(2):305-310

Inductively coupled plasma-mass spectrometry (ICP-MS) after NiS fire assay-Te co-precipitation was employed in the determination of Ru, Rh, Pd, Os, Ir and Pt at ng g^-1 levels in six platinum-group element (PGE) geological reference materials. In general, the average of several results was in good agreement with the certified values taking into account respective uncertainties. High relative standard deviations were observed for the reference materials GPt-3 and GPt-4. Problems associated with the NiS fire assay procedure and PGE determination at the sub-10 ng g^-1 level are reviewed and discussed.  相似文献   

Rapid tectonic exhumation, detachment faulting and orogenic collapse in the Caledonides of western Ireland     

Peter D. Clift  John F. Dewey  Amy E. Draut  David M. Chew  Maria Mange  Paul D. Ryan 《Tectonophysics》2004,384(1-4):91-113

Collision of the oceanic Lough Nafooey Island Arc with the passive margin of Laurentia after 480 Ma in western Ireland resulted in the deformation, magmatism and metamorphism of the Grampian Orogeny, analogous to the modern Taiwan and Miocene New Guinea Orogens. After 470 Ma, the metamorphosed Laurentian margin sediments (Dalradian Supergroup) now exposed in Connemara and North Mayo were cooled rapidly (>35 °C/m.y.) and exhumed to the surface. We propose that this exhumation occurred mainly as a result of an oceanward collapse of the colliding arc southwards, probably aided by subduction rollback, into the new trench formed after subduction polarity reversal following collision. The Achill Beg Fault, in particular, along the southern edge of the North Mayo Dalradian Terrane, separates very low-grade sedimentary rocks of the South Mayo Trough (Lough Nafooey forearc) and accreted sedimentary rocks of the Clew Bay Complex from high-grade Dalradian meta-sedimentary rocks, suggesting that this was a major detachment structure. In northern Connemara, the unconformity between the Dalradian and the Silurian cover probably represents an eroded major detachment surface, with the Renvyle–Bofin Slide as a related but subordinate structure. Blocks of sheared mafic and ultramafic rocks in the Dalradian immediately below this unconformity surface probably represent arc lower crustal and mantle rocks or fragments of a high level ophiolite sheet entrained along the detachment during exhumation.Orogenic collapse was accompanied in the South Mayo Trough by coarse clastic sedimentation derived mostly from the exhuming Dalradian to the north and, to a lesser extent, from the Lough Nafooey Arc to the south. Sediment flow in the South Mayo Trough was dominantly axial, deepening toward the west. Volcanism associated with orogenic collapse (Rosroe and Mweelrea Formations) is variably enriched in high field strength elements, suggesting a heterogeneous enriched mantle wedge under the new post-collisional continental arc.  相似文献   

An expression of Philippine Sea plate rotation: the Parece Vela and Shikoku Basins   总被引：4，自引：0，他引：4  

Maria Sdrolias  Walter R. Roest  R. Dietmar Müller   《Tectonophysics》2004,394(1-2):69-86

The Philippine Sea plate, located between the Pacific, Eurasian and Australian plates, is the world's largest marginal basin plate. The motion of the Philippine Sea plate through time is poorly understood as it is almost entirely surrounded by subduction zones and hence, previous studies have relied on palaeomagnetic analysis to constrain its rotation. We present a comprehensive analysis of geophysical data within the Parece Vela and Shikoku Basins—two Oligocene to Miocene back-arc basins—which provide independent constraints on the rotational history of the Philippine Sea plate by means of their seafloor spreading record. We have created a detailed plate model for the opening of the Parece Vela and Shikoku Basins based on an analysis of all available magnetic, gravity and bathymetric data in the region. Subduction along the Izu–Bonin–Mariana trench led to trench roll-back, arc rupture and back-arc rifting in the Parece Vela and Shikoku Basins at 30 Ma. Seafloor spreading in both basins developed by chron 9o (28 Ma), and possibly by chron 10o (29 Ma), as a northward and southward propagating rift, respectively. The spreading orientation in the Parece Vela Basin was E–W as opposed to ENE–WSW in the Shikoku Basin. The spreading ridges joined by chron 6By (23 Ma) and formed a R–R–R triple junction to accommodate the difference in spreading orientations in both basins. At chron 6No (20 Ma), the spreading direction in the Parece Vela Basin changed from E–W to NE–SW. At chron 5Ey (19 Ma), the spreading direction in the Shikoku Basin changed from ENE–WSW to NE–SW. This change was accompanied by a marked decrease in spreading rate. Cessation of back-arc opening occurred at 15 Ma, a time of regional plate reorganisation in SE Asia. We interpret the dramatic change in spreading rate and direction from E–W to NE–SW at 20±1.3 Ma as an expression of Philippine Sea plate rotation and is constrained by the spacing between our magnetic anomaly identifications and the curvature of the fracture zones. This rotation was previously thought to have begun at 25 Ma as a result of a global change in plate motions. Our results suggest that the Philippine Sea plate rotated clockwise by about 4° between 20 and 15 Ma about a pole located 35°N, 84°E. This implies that the majority of the 34° clockwise rotation inferred to have occurred between 25 and 5 Ma from paleomagnetic data may have in fact been confined to the period between 15 and 5 Ma.  相似文献   

Characterization of Cu-complexes in smectite with different layer charge location: chemical, thermal and EXAFS studies     

Maria Franca Brigatti  S Colonna  Luca Medici 《Geochimica et cosmochimica acta》2004,68(4):781-788

The retention of Cu and Cu-amino acid complexes by montmorillonite and beidellite, before and after repeated acidified aqueous solution treatments, was studied using X-ray diffraction, chemical and thermal analyses, mass spectrometry and synchrotron-based X-ray absorption spectroscopy (XAS).The results indicate that the extraction of metal complexes from smectites depends on the nature of the layer charge and on the kind of organic species. Cu-cysteine complexes are strongly retained in the interlayer position, whereas Cu-glycine complexes are mostly adsorbed in cationic form which can be easily removed from the silicate layer. The layer periodicity for Cu-smectites treated with glycine shows little or no layer expansion, whereas significant swelling of the layer periodicity is observed in smectites treated with cysteine.Thermal decomposition of both smectites with sorbed Cu-amino acid species shows the evolution of H₂O, NO, CH₃CH₃, and CO₂. In Cu-cysteine treated smectites, the release of H₂S, NO₂, SO₂, and N₂O₃ also occurs.X-ray absorption spectroscopy (XAS) was used to assess the relationships between the structure of the Cu complexes and their desorption from smectites. In Cu-exchanged smectites, the first coordination shell agrees with the hypothesis that the Cu coordinates to oxygen atoms to form monomer and/or dimer complexes. The first coordination shell of Cu in smectites treated with glycine shows four atoms at distances of ∼2 Å. Two of these bonds are with nitrogen and two with oxygen atoms. For copper-cysteine complexes XAS data are compatible with the existence of Cu-N clusters, thus suggesting that Cu links to the amino acid by the aminic group.  相似文献   

July 2006     

Maria Helena Henriques  Rui Pena dos Reis  José Brilha  Teresa Mota 《Environmental Geology》2005,48(2):276-277

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Late Eocene brachiopods from the Euganean Hills (NE Italy)     

Maria Aleksandra Bitner  Iginio Dieni 《Eclogae Geologicae Helvetiae》2005,98(1):103-111

Five species belonging to five genera and an unidentified rhynchonellid have been recognised in a Late Eocene (Priabonian) brachiopod assemblage from Castelnuovo in the Euganean Hills, north-eastern Italy. One genus and two species are new, i. e. Venetocrania euganea gen. et sp. nov. and “Terebratula” italica sp. nov. Orthothyris pectinoides (von Koenen 1894) is recorded for the first time from Italy. The other species are Terebratulina sp. cf. T. tenuistriata (Leymerie 1846) and Lacazella mediterranea (Risso 1826), both already known from the Italian Eocene.  相似文献   

Crystal morphology and surface structures of orthorhombic MgSiO3 in the presence of divalent impurity ions     

Maria Alfredsson  Furio Corà  John P. Brodholt  Steve C. Parker  G. David Price 《Physics and Chemistry of Minerals》2005,32(5-6):379-387

Many rheological and transport properties of rocks are determined by the grain boundary structures of their constituent minerals. These grain boundaries often also hold a high concentration of dopant ions. Here, as a first step towards modelling the transport and rheological behaviour of the lower mantle, we report the results of lattice static simulations on the surface structures of Fe²⁺ and Ca²⁺-doped orthorhombic MgSiO₃-perovskite. For all the surfaces we studied, the energies of the doped structures are lowered, sometimes by more than 1 J/m², with respect to the pure surfaces. From our calculated crystal morphologies, we predict that the grains become more tabular as the concentration of Fe²⁺ ions increases, while under equilibrium conditions the grains are cubic. By calculating the replacement energies of Mg²⁺ by Fe²⁺ and Ca²⁺ ions in the six outermost surface layers, we conclude that these divalent ions would tend to segregate onto the crystal surfaces. We suggest, therefore, that the grain boundary structure and rheology of MgSiO₃-perovskite dominated rocks will be strongly affected by the presence of minor elements in the lower mantle.  相似文献   

57Fe-Mössbauer spectroscopy on natural eosphorite-childrenite-ernstite samples     

Geraldo Magela da Costa  Ricardo Scholz  Joachim Karfunkel  Vladimir Bermanec  Mário Luiz de Sá Carneiro Chaves 《Physics and Chemistry of Minerals》2005,31(10):714-720

Samples of the eosphorite-childrenite [(Mn²⁺, Fe²⁺)AlPO₄(OH)₂H₂O] series from Divino das Laranjeiras and Araçuaí (Minas Gerais State) and Parelhas (Rio Grande do Norte State) pegmatites have been investigated by X-ray diffraction, microprobe analysis and Mössbauer spectroscopy at 295 and 77 K. The Mössbauer spectra of ernstite [(Mn²⁺, Fe³⁺)AlPO₄(OH)_2-xO_x] showed the existence of ferric ions in both A and B sites, whereas ferrous ions seem to be located exclusively in the A site. Nonoxidised samples show ferrous ions located in both sites, and no Fe³⁺ could be detected. The interpretation of the Mössbauer spectra of both, oxidised and nonoxidised samples, is difficult because the hyperfine parameters of these minerals are rather similar, rendering it difficult to make proper site assignments.  相似文献   

Le régime alimentaire du Cervidae (Mammalia) Eucladoceros ctenoides (Nesti 1841) reconstitué par la morphologie du crâne et par l’usure dentaire     

Andrea M. F. Valli  Maria R. Palombo 《Swiss Journal of Geoscience》2005,98(1):133-143

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