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91.
92.
Uptake of environmentally relevant platinum group elements (PGE) by the marine macroalga, Ulva lactuca, has been studied. Removal of nM concentrations of Rh(III), Pd(II) and Pt(IV) added to filtered sea water appeared to proceed via pseudo-first-order kinetics, with respective forward rate constants of either 0.0039 or 0.0042 h− 1, 0.0058 or 0.0096 h− 1 and 0.0017 or 0.0032 h− 1, depending on whether an irreversible or reversible reaction was invoked. The (quasi-) equilibrium distribution coefficients, derived from linear fits to uptake (sorption) isotherms, were about 1400, 900 and 350 mL g− 1 on a dry mass basis for Rh, Pd and Pt, respectively. With increasing sea water pH, over the range 7.9 to 8.4, uptake of Rh by Ulva increased considerably, whereas a small increase in Pt removal was observed; in contrast, uptake of Pd exhibited no clear dependence on pH. The percentage of metal taken up that was internalised within cells, evaluated by washing selected algal samples in 3 mM EDTA, was about 40% for Rh, 80% for Pd and 95% for Pt. Results of this study were interpreted in terms of what is known about the aqueous speciation of PGE in sea water. Thus, Rh exists as cationic hydrated chloride complexes which are readily adsorbed at the algal surface. Palladium has an exceptional affinity for organic ligands, and uptake (and internalisation) appears to be governed by competition for Pd2+ from aqueous and algal binding sites. Platinum (IV) exists predominantly as a series of (mainly) negatively charged chloride and mixed hydroxychloride complexes that have little propensity to interact with the algal surface; however, its high degree of internalisation requires at least some interaction with specific and perhaps physiologically active sites.  相似文献   
93.
Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L− 1 dFe, 3 nmol L− 1 dMn and 40 nmol L− 1 dAl and returned to 0.6 nmol L− 1 dFe, 0.5 nmol L− 1 dMn and 10 nmol L− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m− 2 yr− 1 (range 1.0–2.9 g m− 2 yr− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise.  相似文献   
94.
95.
Hedgerow is one of the most important rural landscapes in the world, especially in Europe. Knowledge about the hydrological role of hedgerows is useful in many fields of study, such as hydrological modelling and rural landscape management. The aim of this study was to investigate the impact of a hedgerow on rainfall distribution, soil-water potential gradient, lateral water transfer and water balance. A hillslope with a hedgerow perpendicular to the slope was monitored. To evaluate hedgerow rainfall interception, rainfall was measured (hourly, daily, and by rainfall event) both next to and up to 16 m upslope and 12 m downslope perpendicularly away from the hedgerow. The strongest correlation between rainfall next to the hedgerow and rainfall at more distant points was obtained using data measured per rainfall event. The average percentage of rainfall intercepted equalled 28% for the leafed period and 12% for the leafless period. The impact of the hedgerow on spatial rainfall distribution was related to distance from the hedgerow and rainfall amount. Annual distribution of soil-water potential showed that the hedgerow influenced it up to 9 m upslope and 6 m downslope, the area in which most of the hedgerow's roots were observed. The soil was driest at the end of summer, which delayed soil rewetting during autumn in areas surrounding the hedgerow. Annual groundwater dynamics exhibited three distinct periods due to temporal rainfall distribution and, especially at the end of summer, root-water uptake. In addition, the total potential gradient showed that unsaturated flow was directed towards the hedgerow in summer and autumn. These results indicate that at the local scale hedgerows influences (1) spatial rainfall distribution, (2) soil rewetting, and (3) groundwater recharge, often at distances well beyond the hedgerow's drip line. Consequently, the processes involved in soil-water dynamics around hedgerows should be integrated into relevant hydrological models, especially for catchments with a dense hedgerow network. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
96.
97.
In New Caledonia wildfires and invasive mammals (deer and wild pigs) constitute the major agents of land surface degradation. Our study reveals the linkage between land cover and water balance on the northeast coast of New Caledonia (2400 mm annual rainfall) located on a micaschist basement. The hydrological regime of characteristic and representative land surfaces is assessed using a 1-year record from three 100 m2 plots each, located in a forest area degraded by an invasive fauna, in a woody savannah which is regularly burned, and in a healthy forest area. The three plots present highly contrasting hydrological regimes, with annual and maximum runoff/rain ratios during a rain event of, respectively, 0.82, 0.16, 0.03, and 2.7, 0.7, 0.2, for the degraded forest, the savannah and the healthy forest. Such results suggest that subsurface flow originating from the contributing area above the degraded forest plot should exfiltrate inside the plot. A conceptual model for the degraded forest plot shows that water exfiltrating inside the plot represents 61% of the observed runoff. In savannahs, water should mainly be transferred downstream by subsurface flow within a thick organic soil layer limited by an impervious clay layer at a 20–30 cm depth. Savannahs are generally located above forests and generate the transfer of rainwater to downslope forests. Exfiltration into the forests can be the result of this transfer and depends on the thickness and permeability of the forest topsoils and on topographic gradients. Water exfiltration in forest areas highly degraded by pigs and deer enhances erosion and increases further degradation. It probably also limits percolation in the areas located downstream by increasing the amount of superficial runoff concentrated in gullies.  相似文献   
98.
99.
The Kongur Shan Extensional System (KES) is a ~250 km long normal fault system that bounds the Muji–Tashkorgan basin of the Chinese Pamir. It accommodates E–W extension due to the northward indentation of the Pamir salient, and its late Miocene activity has been the focus of tectonic studies. While the KES has a main normal component, ~WNW–ESE‐striking segments have an additional right‐lateral strike‐slip component. Here, we quantify late Quaternary horizontal and vertical slip rates at three locations along the KES, where active faults cut and offset abandoned geomorphic features. We find rates of >3–4 mm a?1 (horizontal) along the western Muji fault in the north and of ~1.7 mm a?1 (vertical) and ~1 mm a?1 (horizontal) along the Kongur Shan fault in the south during the late Pleistocene. These rates are consistent with GPS and late Miocene rates, and imply that E–W extension in the Muji–Tashkorgan basin is faster in the north than in the south.  相似文献   
100.
We provide the first documentation of tectonic deformation resulting from a volcanic eruption on the island of Jan Mayen. Vertical displacement of about 14 m southwest of the stratovolcano Beerenberg is associated with an eruption in ad 1732 on its southeastern flank. The age of the uplift event is bracketed by radiocarbon-dated driftwood buried by material deposited due to uplift, and by tephra from this eruption. Constraints, inferred from radiocarbon ages alone, allow for the possibility that uplift was completed prior to the ad 1732 eruption. However, the occurrence of tephra in the sediment column indicates that some displacement was ongoing during the eruption but ceased before the eruption terminated. We attribute the tectonic deformation to intrusion of shallow magma associated with the volcanic eruption. Our results complement previous studies of volcanic activity on Jan Mayan by providing precise age constraints for past volcanic activity. Also, it raises new hypotheses regarding the nature, timing and prevalence of precursor tectonic events to Jan Mayan eruptions. The uplift caused the complete isolation of a coastal lake by closing its outlet to the sea, thus landlocking the facultative migratory fish species Arctic charr (Salvelinus alpinus).  相似文献   
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