Coupled U-Pb Dating and Hf Isotopic Analysis of Detrital Zircon of Modern River Sand From the Yalu River (YarlungTsangpo) Drainage System in Southern Tibet:Constraints on the Transport Processes and Evolution of Himalayan Rivers     

ZHANG Jinyu  YIN An  LIU Wencan  WU Fuyuan  DING Lin  GROVE Marty 《《地质学报》英文版》2013,87(Z1):102-102

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Adsorption of xenon ions onto defects in organic surfaces: Implications for the origin and the nature of organics in primitive meteorites     

Yves Marrocchi  Bernard Marty  François Robert 《Geochimica et cosmochimica acta》2011,75(20):6255-6266

Noble gases trapped in primitive meteorites are quantitatively hosted by a poorly defined organic phase, labeled phase Q. Xenon is enriched in heavy isotopes by +1.30 ± 0.06% per atomic mass unit (amu, 1σ) in phase Q relative to solar. To understand the origin of this fractionation, we have performed adsorption experiments of xenon atoms and ions, ionized in a radiofrequency plasma. Within the reaction vessel, anthracite was heated and the resulting smoke deposited onto the walls of the vessel, resulting in carbon-rich films. Xenon was trapped in the carbon films either as ions in the ionization zone of the vessel, or as neutral atoms outside this zone. Xenon trapped as ionic Xe is tightly bound and is enriched by +1.36 ± 0.05%/amu (1σ) in heavy isotopes, reproducing the isotopic fractionation of xenon trapped in phase Q relative to solar. Neutral xenon is more loosely trapped, is in much lower concentration, and is not isotopically fractionated. Ionized conditions allow the constant xenon isotopic composition observed in meteorite during stepwise heating release to be reproduced. Furthermore, the trapping efficiency of Xe⁺ estimated from these experiments is consistent with the high xenon concentration measured in phase Q of primitives meteorites.Xenon was not trapped in the film by implantation because the energies of the incident Xe atoms and ions were far too low (<1 eV). From the difference of behavior between ionic and neutral forms, we propose that xenon ions were trapped via chemical bonding at the surface of the newly created C-rich film. The observed mass-dependent fractionation of xenon is unlikely to have occurred in the gas phase. It is more probably related to variations in chemical bonding strengths of Xe isotopes as chemical bonds involving heavy Xe isotopes are more stable than those involving light ones. For young stars, including the young Sun, photons emitted in the far UV energy range able to ionize noble gases (<100 nm) were orders of magnitude more abundant than for the Present-day Sun, allowing efficient ionization of gaseous species. A way to achieve Q-noble gas fractionation and trapping was UV irradiation by nearby young stars from O/B association of the surface of growing organic grains in the outer part of the solar system or by the young Sun at the edge of the disk.  相似文献   

Investigating the nexus of climate,energy, water,and land at decision-relevant scales: the Platform for Regional Integrated Modeling and Analysis (PRIMA)     

Ian Kraucunas  Leon Clarke  James Dirks  John Hathaway  Mohamad Hejazi  Kathy Hibbard  Maoyi Huang  Chunlian Jin  Michael Kintner-Meyer  Kerstin Kleese van Dam  Ruby Leung  Hong-Yi Li  Richard Moss  Marty Peterson  Jennie Rice  Michael Scott  Allison Thomson  Nathalie Voisin  Tristram West 《Climatic change》2015,129(3-4):573-588

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Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 2: field evaluation     

Marty D. Frisbee  Fred M. Phillips  Andrew R. Campbell  Jan M. H. Hendrickx  Emily M. Engle 《水文研究》2010,24(7):834-849

Twelve modified passive capillary samplers (M‐PCAPS) were installed in remote locations within a large, alpine watershed located in the southern Rocky Mountains of Colorado to collect samples of infiltration during the snowmelt and summer rainfall seasons. These samples were collected in order to provide better constraints on the isotopic composition of soil‐water endmembers in the watershed. The seasonally integrated stable isotope composition (δ¹⁸O and δ²H) of soil‐meltwater collected with M‐PCAPS installed at shallow soil depths < 10 cm was similar to the seasonally integrated isotopic composition of bulk snow taken at the soil surface. However, meltwater which infiltrated to depths > 20 cm evolved along an isotopic enrichment line similar to the trendline described by the evolution of fresh snow to surface runoff from snowmelt in the watershed. Coincident changes in geochemistry were also observed at depth suggesting that the isotopic and geochemical composition of deep infiltration may be very different from that obtained by surface and/or shallow‐subsurface measurements. The M‐PCAPS design was also used to estimate downward fluxes of meltwater during the snowmelt season. Shallow and deep infiltration averaged 8·4 and 4·7 cm of event water or 54 and 33% of the measured snow water equivalent (SWE), respectively. Finally, dominant shallow‐subsurface runoff processes occurring during snowmelt could be identified using geochemical data obtained with the M‐PCAPS design. One soil regime was dominated by a combination of slow matrix flow in the shallow soil profile and fast preferential flow at depth through a layer of platy, volcanic rocks. The other soil regime lacked the rock layer and was dominated by slow matrix flow. Based on these results, the M‐PCAPS design appears to be a useful, robust methodology to quantify soil‐water fluxes during the snowmelt season and to sample the stable isotopic and geochemical composition of soil‐meltwater endmembers in remote watersheds. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Water-saturated oceanic lavas from the Manus Basin: volatile behaviour during assimilation–fractional crystallisation–degassing (AFCD)     

B. Marty  Y. Sano  C. France-Lanord   《Journal of Volcanology and Geothermal Research》2001,108(1-4)

We have analysed volatiles (H₂O, He, Ar, CO₂) in differentiated (basaltic andesite, dacite) volcanic glasses dredged at a depth of ca. 2000 m in the eastern part of the Manus Basin between 151°20′ and 152°10′ E. These samples have Sr–O–B isotopic ratios that show that they most likely represent lavas evolved from a common magma source. Since these glasses are very fresh, they provide a unique opportunity to study the behaviour of magmatic volatiles during assimilation–fractional crystallisation–degassing (AFCD). The samples are highly vesicular (up to 18%) and the volatiles trapped in vesicles consist predominantly of H₂O with minor amounts of CO₂, and the concentration of water in the glasses indicates that H₂O saturation was attained. Rare gases except helium are atmospheric in origin, and the ³He/⁴He ratios and the CO₂/³He ratios are respectively lower and higher than those typical of Mid-Ocean Ridge Basalt (MORB), and appear to correlate with the degree of differentiation. AFCD allows efficient degassing of mantle-derived volatiles and contribution of crust-derived and atmosphere-derived volatiles. Given the widespread occurrence of differentiated magmatism at arcs, we suggest that AFCD is responsible for large-scale occurrence of ³He-rich crustal fluids and of atmospheric-like rare gases in arc emanations, and that most of the volatiles are lost continuously during fractional crystallisation, rather than catastrophically during eruptions.  相似文献   

Analyses of nitrogen and argon in single lunar grains: towards a quantification of the asteroidal contribution to planetary surfaces     

Ko Hashizume  Bernard Marty  Rainer Wieler 《Earth and Planetary Science Letters》2002,202(2):201-216

We performed nitrogen and argon isotopic analyses in single 200-μm-sized ilmenite grains of lunar regolith samples 71501, 79035 and 79135. Cosmogenic and trapped components were discriminated using stepwise heating with a power-controlled CO₂ laser. Cosmogenic ¹⁵N and ³⁸Ar correlate among different ilmenite grains, yielding a mean ¹⁵N_c/³⁸Ar_c production ratio of 14.4±1.0 atoms/atom. This yields a ¹⁵N production rate in bulk lunar samples of 3.8-5.6 pg (g rock)⁻¹ Ma⁻¹, which agrees well with previous estimates. The trapped δ¹⁵N values show large variations (up to 300‰) among different grains of a given soil, reflecting complex histories of mixing between different end-members. The ³⁶Ar/¹⁴N ratio, which is expected to increase with increasing contribution of solar ions, varies from 0.007 to 0.44 times the solar abundance ratio. The trapped δ¹⁵N values correlate roughly with the ³⁶Ar/¹⁴N ratios from a non-solar end-member characterized by a ³⁶Ar/¹⁴N ratio close to 0 and variable but generally positive δ¹⁵N values, to lower δ¹⁵N values accompanied by increasing ³⁶Ar/¹⁴N ratios, supporting the claim of Hashizume et al. (2000) that solar nitrogen is largely depleted in ¹⁵N relative to meteoritic or terrestrial nitrogen. Nevertheless, the ³⁶Ar/¹⁴N ratio of the ¹⁵N-depleted (solar) end-member is lower than the solar abundance ratio by a factor of 2.5-5. We explain this by a reprocessing of implanted solar wind atoms, during which part of the chemically inert rare gases were lost. We estimate that the flux of non-solar N necessary to account for the observed δ¹⁵N values is comparable to the flux of micrometeorites and interplanetary dust particles estimated for the Earth. Hence we propose that the variations in δ¹⁵N values observed in lunar regolith can be simply explained by mixing between solar wind contributions and micrometeoritic ones infalling on the Moon. Temporal variations of δ¹⁵N values among samples of different antiquities could be due to changes in the micrometeoritic flux through time, in which case such flux has increased by up to an order of magnitude during the last 0.5 Ga.  相似文献   

Altitude dependence of surface radiation fluxes and cloud forcing in the alps: results from the alpine surface radiation budget network   总被引：1，自引：1，他引：1  

Ch. Marty  R. Philipona  C. Fröhlich  A. Ohmura 《Theoretical and Applied Climatology》2002,72(3-4):137-155

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CHe in volatile fluxes from the solid Earth: implications for carbon geodynamics     

B. Marty  A. Jambon 《Earth and Planetary Science Letters》1987,83(1-4)

In order to picture C geodynamics past and present, theC³He ratios of the relevant reservoirs are considered. Evaluation of publishedC³He ratio in conjunction with new results for MORB glasses worldwide, suggests that this ratio is unfractionated during magma outgassing, a best estimate being 2 × 10⁹.C³He ratios from other volcanic emissions (hot spots and arcs) do not appear significantly different when the subducted component is omitted.This result permits scaling of the CO₂ degassing flux to that of³He and yields a value of 2 × 10¹² mol/yr which corresponds to a model degassing duration of 3.9 Gyr when recycling to the mantle is disregarded.A bulk Earth chondritic ratio of about 2 × 10⁹ is calculated, very close to the MORB value. On the other hand the reconstructed exospheric (“Rubey inventory”) value of4 ± 1 × 10⁷ is very different from both basaltic and chondritic values.Among the possible interpretations of these results the following two are retained: (1) CO₂ was not released in the early age of the Earth because of the reducing conditions prevailing at that time in the mantle. Formation of the core changed this picture and permitted subsequent degassing of CO₂. (2) Carbonates need a continental crust of significant size to become stabilized in the exosphere. Therefore accumulation in the exosphere was delayed until crustal formation.Alternatively, a similar degassing behaviour for both He and CO₂ requires a massive recycling of carbonates throughout time. This possibility is in contradiction with the present-day maximum recycling rate and the severe imbalance with the observed outgassing flux on one hand and with the small fraction of carbon now present in the exosphere on the other.We conclude that carbon has never been severely degassed. The mantle acts as a buffer for C and most carbon is still retained there, possibly as graphite (or diamond?) or dissolved in minerals.  相似文献   

Données cytologiques sur deux Cyanophycées:Spirulina platensis (Gom.) Geitler etSpirulina geitleri J. de Toni     

F. Marty  F. Busson 《Aquatic Sciences - Research Across Boundaries》1970,32(2):559-565

The interest of many research specialists is, at present, focused on twoSpirulina, which can be cultivated for alimentary purposes. Optimum conditions for industrial cultivation are known, but far more must be found out about the systematic position of the two microorganisms as well as their structural and metabolic biochemistry, since these facts are essential for more rational industrial use. This paper marks the beginning of a cytological and cytochemical research program.  相似文献   

Comparison of Satellite-Only Gravity Field Models Constructed with All and Parts of the GOCE Gravity Gradient Dataset     

Sean L. Bruinsma  Christoph Förste  Sandrine Mulet  Marie-Hélène Rio  Oleg Abrikosov  Jean-Charles Marty 《Marine Geodesy》2016,39(3-4):238-255

The impact of GOCE Satellite Gravity Gradiometer data on gravity field models was tested. All models were constructed with the same Laser Geodynamics Satellite (LAGEOS) and Gravity Recovery and Climate Experiment (GRACE) data, which were combined with one or two of the diagonal gravity gradient components for the entire GOCE mission (November 2009 to October 2013). The Stokes coefficients were estimated by solving large normal equation (NE) systems (i.e., the direct numerical approach). The models were evaluated through comparisons with the European Space Agency's (ESA) gravity field model DIR-R5, by GPS/Leveling, GOCE orbit determination, and geostrophic current evaluations. Among the single gradient models, only the model constructed with the vertical ZZ gradients gave good results that were in agreement with the formal errors. The model based only on XX gradients is the least accurate. The orbit results for all models are very close and confirm this finding. All models constructed with two diagonal gradient components are more accurate than the ZZ-only model due to doubling the amount of data and having two complementary observation directions. This translates also to a slower increase of model errors with spatial resolution. The different evaluation methods cannot unambiguously identify the most accurate two-component model. They do not always agree, emphasizing the importance of evaluating models using many different methods. The XZ gravity gradient gives a small positive contribution to model accuracy.  相似文献