Investigation on the Levels of Heavy Metals,Polycyclic Aromatic Hydrocarbons,and Polychlorinated Biphenyls in Sewage Sludge Samples and Ecotoxicological Testing     

Senar Ozcan  Ali Tor  Mehmet Emin Aydin 《洁净——土壤、空气、水》2013,41(4):411-418

This article reports the levels of heavy metals, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) in sewage sludges taken from two wastewater treatment plants (WWTPs) in Konya (Turkey) as well as their toxicity. The concentrations of heavy metals, including Cd, Cr, Cu, Ni, Pb, Zn in sludge samples from plant #2 did not exceed the limits described in both Turkish and European Union (EU) regulations. The similar result was observed in samples obtained from plant #1, except for sludge taken in May 2010. The ΣPAHs concentration ranging from 960 to 7680 µg/kg dry matter shows that sewage sludges from plant #1 could be used for agricultural purpose. However, sewage sludges from plant #2 (ΣPAHs: 1077–17 509 µg/kg dry matter) was not suitable for using in agriculture. The concentrations of ΣPCBs in all investigated sludges from plant #1 (7.46–709.36 µg/kg dry matter) and plant #2 (14.12–788.47 µg/kg dry matter) were lower than the limits reported in Turkish and EU regulations. The probable sources of PAHs and PCBs in sludges were also determined. The ecotoxicological tests examined on Vibrio fischeri and Lepidium sativum organisms showed that sludges from plant #1 had no significant toxic effect, while sludges from plant #2 had acute toxic property. Finally, all the results showed that sewage sludges from plant #1 had potential for being used in agriculture.  相似文献   

Seasonal Growth Dynamics of Posidonia oceanica in a Pristine Mediterranean Gulf     

Mutlu  Erhan  Olguner  Cansu  Gökoğlu  Mehmet  Özvarol  Yaşar 《Ocean Science Journal》2022,57(3):381-397

Ocean Science Journal - Seasonal growth dynamics and ecology of Posidonia oceanica were studied in a space alongshore a pristine Mediterranean gulf in 2011–2012. About one-third of the...  相似文献   

Monitoring the land use/cover changes and habitat quality using Landsat dataset and landscape metrics under the immigration effect in subalpine eastern Turkey     

Onur Satir  Mehmet Akif Erdogan 《Environmental Earth Sciences》2016,75(15):1118

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Holocene coastal change in the ancient harbor of Yenikap?-?stanbul and its impact on cultural history     

Oya Algan  M. Nam?k Yalç?n  Yücel Y?lmaz  Elmas K?rc?-Elmas  Özlem Bulkan  Cem Gazio?lu  Mehmet Ali Polat 《Quaternary Research》2011,76(1):30-45

An extensive rescue excavation has been conducted in the ancient harbor of ?stanbul (Yenikap?) by the Sea of Marmara, revealing a depositional sequence displaying clear evidence of transgression and coastal progradation during the Holocene. The basal layer of this sequence lies at 6 m below the present sea level and contains remains of a Neolithic settlement known to have been present in the area, indicating that the sea level at ~ 8-9 cal ka BP was lower than 6 m below present. Sea level advanced to its maximum at ~ 6.8-7 cal ka BP, drowning Lykos Stream and forming an inlet at its mouth. After ~ 3 cal ka BP, coastal progradation became evident. Subsequent construction of the Byzantine Harbor (Theodosius; 4th century AD) created a restricted small basin and accumulation of fine-grained sediments. The sedimentation rate was increased due to coastal progradation and anthropogenic factors during the deposition of coarse-grained sediments at the upper parts of the sequence (7th-9th centuries AD). The harbor was probably abandoned after the 11th century AD by filling up with Lykos Stream detritus and continued seaward migration of the coastline.  相似文献   

Spectrophotometric Determination of Gold (III) after Liquid–Liquid Extraction and Selective Pre‐concentration with a Novel Dibenzo‐18‐Crown‐6 Derivative     

Volkan N. Bulut  Celal Duran  Zekeriya Biyiklioglu  Mehmet Tufekci  Mustafa Soylak 《Geostandards and Geoanalytical Research》2011,35(4):471-483

A selective and sensitive method for the extraction and spectrophotometric determination of gold with N,N′‐6,7,9,10,17,18,20,21‐octahydrodibenzo[b,k][1,4,7,10,13,16] hexaoxacyclo‐octadecine‐2,13–diylbis(2‐chloroacetamide) (ODBOCA) is described. The ODBOCA–Au(III) complex was extracted from a slightly acidic aqueous solution (pH 5) into a chloroform layer and then the absorbance of the extract was measured using a UV–Vis spectrophotometer with 1.0 cm quartz cells at 540 nm. An enrichment factor of 200 was achieved. In the chloroform medium at 540 nm, the molar absorptivity and Sandell’s sensitivity were 4.12 × 10³ l mol^?1 cm^?1 and 0.048 μg cm^?2, respectively. Beer’s law was obeyed in the range of 0.5–15 μg ml^?1 in the measured solution. The relative standard deviation for ten replicate samples at the 1.0 μg ml^?1 level was 3.0%. The limit of detection, based on 3s, was 0.5 μg l^?1 in the original sample. The effects of pH, ligand concentration and shaking time were studied. The ratio of the metal ion to ligand molecules in the complex was found to be 1:2 according to the Job Method. The effects of interference by a number of metal ions were investigated. The method was verified with certified reference materials and spiked tests, and quantitative recovery values were obtained. The method was fast, accurate, selective and precise, and was applied to the determination of gold in water and ore with good results.  相似文献   

Stochastic Modeling Approach for the Evaluation of Backbreak due to Blasting Operations in Open Pit Mines   总被引：2，自引：0，他引：2  

Mehmet Sari  Ebrahim Ghasemi  Mohammad Ataei 《Rock Mechanics and Rock Engineering》2014,47(2):771-783

Backbreak is an undesirable side effect of bench blasting operations in open pit mines. A large number of parameters affect backbreak, including controllable parameters (such as blast design parameters and explosive characteristics) and uncontrollable parameters (such as rock and discontinuities properties). The complexity of the backbreak phenomenon and the uncertainty in terms of the impact of various parameters makes its prediction very difficult. The aim of this paper is to determine the suitability of the stochastic modeling approach for the prediction of backbreak and to assess the influence of controllable parameters on the phenomenon. To achieve this, a database containing actual measured backbreak occurrences and the major effective controllable parameters on backbreak (i.e., burden, spacing, stemming length, powder factor, and geometric stiffness ratio) was created from 175 blasting events in the Sungun copper mine, Iran. From this database, first, a new site-specific empirical equation for predicting backbreak was developed using multiple regression analysis. Then, the backbreak phenomenon was simulated by the Monte Carlo (MC) method. The results reveal that stochastic modeling is a good means of modeling and evaluating the effects of the variability of blasting parameters on backbreak. Thus, the developed model is suitable for practical use in the Sungun copper mine. Finally, a sensitivity analysis showed that stemming length is the most important parameter in controlling backbreak.  相似文献   

Organic and inorganic correlations for Northwest Africa 852 by synchrotron‐based Fourier transform infrared microspectroscopy          下载免费PDF全文

Mehmet Yesiltas  Robert E. Peale  Miriam Unger  Julia Sedlmair  Carol J. Hirschmugl 《Meteoritics & planetary science》2015,50(10):1684-1696

Relationships between organic molecules and inorganic minerals are investigated in a single 34 μm diameter grain of the CR2 chondrite Northwest Africa 852 (NWA) 852 with submicron spatial resolution using synchrotron‐based imaging micro‐FTIR spectroscopy. Correlations based on absorption strength for the various constituents are determined using statistical correlation analysis. The silicate band is found to be correlated with the hydration band, and the latter is highly correlated with stretching modes of aliphatic hydrocarbons. Spatial distribution maps show that water+organic combination, silicate, OH, and C‐H distributions overlap, suggesting a possible catalytic role of phyllosilicates in the formation of organics. In contrast, the carbonate band is anticorrelated with water+organic combination, however uncorrelated with any other spectral feature. The average ratio of asymmetric CH₂ and CH₃ band strengths (CH₂/CH₃ = 2.53) for NWA 852 is similar to the average ratio of interplanetary dust particles (~2.40) and Wild 2 cometary dust particles (2.50), but it significantly exceeds that of interstellar medium objects (~1.00) and several aqueously altered carbonaceous chondrites (~1.40). This suggests organics of similar length/branching, and perhaps similar formation regions, for NWA 852, Wild 2 dust particles, and interplanetary dust particles. The heterogeneous spatial distribution of ratio values indicates the presence of a mixture of aliphatic organic material with different length/branching, and thus a wide range of parent body processes, which occurred before the considered grain was formed.  相似文献   

The influences of the Southern and North Atlantic Oscillations on climatic surface variables in Turkey     

M. aatay Karabrk  Ercan Kahya  Mehmet Karaca 《水文研究》2005,19(6):1185-1211

In this study, Turkish climatic variables (precipitation, stream flow and maximum and minimum temperatures) were first analysed in association with both the Southern Oscillation (SO) and the North Atlantic Oscillation (NAO). The relationships between Turkish maximum and minimum monthly temperatures and the extreme phases of the SO (El Niño and La Niña events) were examined. The results of this analysis showed that relationships between Turkish monthly maximum temperatures and El Niño and La Niña contain some complexity still to be identified, because both events produce a signal indicating a correspondence with cold anomalies in the aggregate composites. A relationship between turkish minimum temperatures and El Niño was detected in western Anatolia, whereas there was no significant and consistent signal associated with La Niña. Moreover a series of cross‐correlation analyses was carried out to demonstrate the teleconnections between the climatic variables and both the NAO and SO. The NAO during winter was found to influence precipitation and stream‐flow patterns. In contrast temperature patterns appeared to be less sensitive to the NAO. Furthermore, lag‐correlation results indicated a prediction potential for both precipitation and stream‐flow variables in connection with the NAO. Simultaneous and time‐lag correlations between the climatic variables and the SO index, in general, indicated weaker relationships in comparison with those for the NAO. These analyses also showed that the influences of the SO on Turkish temperature data are negligible. The outcomes were presented in conjunction with an explanation regarding physical mechanisms behind the implied teleconnections. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Neural networks and fuzzy inference systems for predicting water consumption time series     

Mehmet Ali Yurdusev  Mahmut Fırat  Mustafa Erkan Turan  B. Gultekin Sinir 《Stochastic Environmental Research and Risk Assessment (SERRA)》2009,23(8):1225-1225

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Synthesis of Calix(aza)crown and its Oligomeric Analogue for the Extraction of Selected Metal Cations and Dichromate Anions     

Gülderen Uysal Akkus  Shahabuddin Memon  Mehmet Sezgin  Mustafa Yilmaz 《洁净——土壤、空气、水》2009,37(2):109-114

The present study reports the synthesis of a novel ionophore, calix[4]azacrown ( 5 ) bearing two amino groups at the lower rim along with its oligomeric analogue ( 6 ). The liquid‐liquid extraction properties of these compounds towards selected metal cations and dichromate anions have been evaluated. It is observed that ( 5 ) and ( 6 ) are good extractants for the selected metal cations. However, in the case of dichromate anion, only species ( 5 ) shows remarkable extraction properties at low pH, whereas species ( 6 ) shows poor extraction behavior. The results have importance especially in wastewater treatment to obtain environmentally safe industrial effluent and they should also assist supramolecular chemists in designing and synthesizing more sophisticated host molecules for the removal of toxic pollutants.  相似文献