排序方式： 共有25条查询结果，搜索用时 31 毫秒
1.
This work describes the potential usability of neutralized red mud for the removal of organochlorine pesticides (OCPs) from aqueous solutions. After examination on the adsorption capability of neutralized red mud for all studied OCPs, the experiments were performed by employing aldrin as a model compound. The effect of several parameters, such as contact time, pH of the solution, initial aldrin concentration, and dosage of the adsorbent was evaluated by batch experiments. The determination of OCPs was carried out using traditional liquid–liquid extraction followed by a GC coupled with µ‐electron capture detector (GC‐µECD). The results showed that adsorption equilibrium time depended upon the initial aldrin concentration and adsorption followed the second‐order kinetic model. Kinetic study also indicated that the film diffusion mechanism was a main rate control mechanism. The removal was explained by considering the electrostatic interactions between metal oxides surface of the neutralized red mud and inductively charged centers (negative charge (d?) of chlorine atoms and positive charge (d+) of π‐cloud aromatic ring) of the aldrin molecules. In comparison to the Langmuir isotherm model, the Freundlich model better represented the adsorption data. The neutralized red mud was also succesfully employed for the removal of OCPs from real water samples, including tap water and surface (lake) water, fortified with studied OCPs. 相似文献
2.
3.
Abdullah Ates Funda Bilim Aydin Buyuksarac Attila Aydemir Ozcan Bektas Yasemin Aslan 《Surveys in Geophysics》2012,33(5):869-885
In this paper, aeromagnetic and gravity anomalies obtained from the General Directorate of Mineral Research and Exploration were subjected to upward continuation to 3?km from the ground surface to suppress shallow effects and to expose only regional, deep sources. Then, a reduction to pole (RTP) map of aeromagnetic anomalies was produced from the 3?km upward continued data. A sinuous boundary to the south of Turkey is observed in the RTP map that may indicate the suture zone between the Anatolides and African/Arabian Plates in the closure time of the Tethys Ocean. The sinuous boundary can be correlated with the recent palaeo-tectonic maps. The southern part of the sinuous boundary is quite different and less magnetic in comparison with the northern block. In addition, maxspots maps of the aeromagnetic and gravity anomalies were produced to find out and enhance the boundaries of tectonic units. Crustal thickness, recently calculated and mapped for the western Turkey, is also extended to the whole of Turkey, and the crustal thicknesses are correlated with the previous seismological findings and deep seismic sections. The average crustal thickness calculations using the gravity data are about 28?km along the coastal regions and increase up to 42?km through the Iranian border in the east of Turkey. Density and susceptibility values used as parameters for construction of two-dimensional (2D) gravity and magnetic models were compiled in a table from different localities of Turkey. 2D models indicate that all of the anomalous masses are located in the upper crust, and this could be well correlated with the earthquakes which occurred at shallow depths. 相似文献
4.
Attila Aydemir Abdullah Ates Funda Bilim Aydin Buyuksarac Ozcan Bektas 《Surveys in Geophysics》2014,35(2):431-448
The North Anatolian Fault (NAF) is not observed on the surface beyond 40 km southeast of Karliova town toward the western shoreline of Lake Van. Various amplitudes of gravity and aeromagnetic anomalies are observed around the lake and surrounding region. In the gravity anomaly map, contour intensity is observed from the north of Mus city center toward Lake Van. There is a possibility that the NAF extends from here to the lake. Because there is no gravity data within the lake, the extension of the NAF is unknown and uncertain in the lake and to the east. Meanwhile, it is observed from the aeromagnetic anomalies that there are several positive and negative amplitude anomalies aligned around a slightly curved line in the east–west direction. The same curvature becomes much clearer in the analytic signal transformation map. The volcanic mountains of Nemrut and Suphan, and magnetic anomalies to the east of the Lake Van are all lined up and extended with this slightly curved line, provoking thoughts that a fault zone that was not previously mapped may exist. The epicenter of the major earthquake event that occurred on October 23, 2011 is located on this fault zone. The fault plane solution of this earthquake indicates a thrust fault in the east–west direction, consistent with the results of this study. Volcanic mountains in this zone are accepted as still being active because of gas seepages from their calderas, and magnetic anomalies are caused by buried causative bodies, probably magmatic intrusions. Because of its magmatic nature, this zone could be a good prospect for geothermal energy exploration. In this study, the basement of the Van Basin was also modelled three-dimensionally (3D) in order to investigate its hydrocarbon potential, because the first oil production in Anatolia was recorded around the Kurzot village in this basin. According to the 3D modelling results, the basin is composed of three different depressions aligned in the N–S direction and many prospective structures were observed between and around these depressions where the depocenter depths may reach down to 10 km. 相似文献
5.
Mustafa Basaran Gunay Erpul A. Ugur Ozcan Pieter Bogman Wim M. Cornelis Donald Gabriels 《Environmental Earth Sciences》2010,61(7):1375-1384
There are various types of the windblown sediment traps developed for wind tunnel and field studies. One of the main supports
expected from these traps is in measuring surface dust concentrations to appropriately derive flux equations. The measurement
performance and accuracy of a trap is very important and depends strictly upon the physical characteristics and the behaviors
of dust grains with air flows. This paper presents the measurement results of static pressure distribution (SPD) of wind flow
around Vaseline-coated slide (VCS) catchers with an aim of finding out whether or not particle trapping efficiency (η) of
the VCS is related to the SPD. The SPD was evaluated by a wind reduction coefficient (R
c) in a series of wind tunnel experiments with different VCS settings which have different attachment configurations on a pole.
Three VCS configurations were considered: a configuration on a circular plastic pole (CPP) and two configurations on wooden
square poles (WSP1 and WSP2, respectively). Thus, the primary contribution of this work was to experimentally analyze the effect of the different attachment
configurations on the SPD, and the secondary objective was to determine the effect of the SPD on the η. It was shown that
spatial correlation and spatial pattern of the R
c were different in the surrounding area of each configuration, and ANOVA and DUNCAN tests indicated that η(s) of WSP1, WSP2, and CPP were different at the significant level of P ≤ 0.05 with the mean of 0.94 ± 0.09, 0.63 ± 0.14, and 1.13 ± 0.07, respectively. Additionally, the amount of PM20, PM40, PM60, PM80, and PM100 trapped by the configurations of WSP1, WSP2, and CPP considerably varied depending upon the particular aerodynamic circumstances associated with every configuration. 相似文献
6.
Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were determined in urban air samples of Konya, Turkey between August 2006 and May 2007. The concentrations of pollutants in both the gas and particulate phase were separately analysed. The average total (gas + particulate) concentrations of PAHs, PCBs and OCPs were determined as 206 ng m− 3, 0.106 ng m− 3, 4.78 ng m− 3 respectively. All of the investigated target compounds were dominantly found in the gas phase except OCPs. Higher air concentrations of PAHs were found at winter season while the highest concentrations of PCBs were determined in September. The highest OCPs were detected in October and in March. In urban air of Konya, PCB 28 and PCB 52 congeners represent 46% and 35% of total PCBs while Phenanthrene, Fluoranthene, Pyrene accounted for 29%, 13%, 10% of total PAHs. HCH compounds (α + β + γ + δ-HCH), total DDTs (p,p′-DDE, p,p′-DDD, p,p′-DDT), Endosulfan compounds (Endosulfan I, Endosulfan II, Endosulfan sulfate) were dominantly determined as 30%, 21%, 20% of total OCPs respectively. Considering the relation between these compounds with temperature, there was no significant correlation observed. Despite banned/restricted use in Turkey, some OCPs were determined in urban air. These results demonstrated that they are either illegally being used in the course of agricultural activity and gardens in Konya or they are residues of past use in environment. According to these results, it can be suggested that Konya is an actively contributing region to persistent organic pollutants in Turkey. 相似文献
7.
Discovered and undiscovered gold endowment of Turkey: a quantitative mineral resource assessment using GIS and rank statistical analysis 总被引：1，自引：0，他引：1
An assessment of the discovered and undiscovered gold endowment of Turkey, a prolific sector in the Tethyan Metallogenic Belt, is developed from a comprehensive Geographic Information System database containing 402 gold deposits and prospects. The majority of the gold deposits and prospects are epithermal, porphyry, volcanic-associated massive sulfides, orogenic gold, and skarn systems. These five major deposit types form more than 90% of the known gold deposits and prospects. Just 87, corresponding to 21.6%, of the deposits and prospects in the data set have current calculated gold reserve and/or resources, containing a total of 54.885 Moz Au. Current gold reserves of the country are 21.447 Moz constituting 39.1% of the total gold resources, of which 17.1 Moz gold are contained in four deposits. Out of these 87 deposits and prospects, only 27 contain significant gold reserve and/or resources (defined as equal to or more than 0.32 Moz or 10 tons Au), and contain 91.8% of the total gold endowment of the country. The cumulative frequency distribution model of the gold endowment of Turkey abides by log-normal distribution. Observed and estimated 10th, 50th (median), and 90th percentiles of the data are 0.0046 Moz [0.0045 Moz estimated], 0.1030 Moz [0.0875 Moz], and 1.4969 Moz [1.6938 Moz], respectively. The 99th percentile of the data is 7.6444 Moz [18.9636 Moz]. The arithmetic mean of the known gold endowment is 0.657 Moz and the Swanson mean size is 0.492 Moz. The arithmetic mean of the 27 significant gold deposit or prospects is 1.94 Moz. Zipf’s law estimates of the undiscovered (residual) gold resources of Turkey are based on the current size of the largest, rank 1, gold deposit of Turkey, which is the Kisladag porphyry deposit that has 17.481 Moz gold endowment (including past production). Zipf’s law estimates a total of 88.261 Moz natural or total gold endowment, 57.133 Moz or 65% of which has already been found. This predicts at least 31.128 Moz residual or undiscovered gold resources to be found in Turkey, though the lack of full delineation of the rank 1 deposit, Kisladag, means that this figure is very conservative. 相似文献
8.
A. Ugur Ozcan Gunay Erpul Mustafa Basaran H. Emrah Erdogan 《Environmental Geology》2008,53(8):1731-1741
The universal soil loss equation (USLE) is an erosion model to estimate average soil loss that would generally result from
splash, sheet, and rill erosion from agricultural plots. Recently, use of USLE has been extended as a useful tool predicting
soil losses and planning control practices by the effective integration of the GIS-based procedures to estimate the factor
values on a grid cell basis. This study was performed for five different lands uses of Indağı Mountain Pass, Cankırı to predict
the soil erosion risk by the USLE/GIS methodology for planning conservation measures in the site. Of the USLE factors, rainfall-runoff
erosivity factor (USLE-R) and topographic factor (USLE-LS) were greatly involved in GIS. These were surfaced by correcting
USLE-R site-specifically using DEM and climatic data and by evaluating USLE-LS by the flow accumulation tool using DEM and
watershed delineation tool to consider the topographical and hydrological effects on the soil loss. The study assessed the
soil erodibility factor (USLE-K) by randomly sampled field properties by geostatistical analysis. Crop management factor for
different land-use/land cover type and land use (USLE-C) was assigned to the numerical values from crop and flora type, canopy
and density of five different land uses, which are plantation, recreational land, cropland, forest and grassland, by means
of reclassifying digital land use map available for the site. Support practice factor (USLE-P) was taken as a unit assuming
no erosion control practices. USLE/GIS technology together with the geostatistics combined these major erosion factors to
predict average soil loss per unit area per unit time. Resulting soil loss map revealed that spatial average soil loss in
terms of the land uses were 1.99, 1.29, 1.21, 1.20, 0.89 t ha−1 year−1 for the cropland, grassland, recreation, plantation and forest, respectively. Since the rate of soil formation was expected
to be so slow in Central Anatolia of Turkey and any soil loss of more than 1 ton ha−1 year−1 over 50–100 years was considered as irreversible for this region, soil erosion in the Indağı Mountain Pass, to the great
extent, attained the irreversible state, and these findings should be very useful to take mitigation measures in the site. 相似文献
9.
Serkan Sayin Fatih Ozcan Mustafa Yilmaz Ali Tor Shahabuddin Memon Yunus Cengeloglu 《洁净——土壤、空气、水》2010,38(7):639-648
In this study, 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene ( 3 ) has been prepared by the treatment of calix[4]arene with a secondary amine (4‐benzylpiperidine) and formaldehyde by means of Mannich reaction. The prepared Mannich base ( 3 ) has been grafted onto [3‐(2,3‐epoxypropoxy)‐propyl]‐trimethoxysilane‐modified Fe3O4 magnetite nanoparticles (EPPTMS‐MN) in order to obtain 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy calix[4]arene‐grafted EPPTMS‐MN (BP‐calix[4]arene‐grafted Fe3O4). All new compounds were characterized by a combination of FTIR and 1H‐NMR analyses. The morphology of the magnetic nanoparticles was examined by transmission electron microscopy. Moreover, the studies regarding the removal of arsenate and dichromate ions from the aqueous solutions were also carried out by using 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene in liquid–liquid extraction and BP‐calix[4]arene‐grafted Fe3O4 ( 4 ) in solid–liquid extraction experiments. The extraction results indicated that 3 is protonated at proton‐switchable binding sites in acidic conditions. Hence, facilitating binding of arsenate and dichromate is resulted from both electrostatic interactions and hydrogen bonding. To understand the selectivity of 3 , the retention of dichromate anions in the presence of Cl−, NO, and SO anions at pH 1.5 was also examined. 相似文献
10.
The oxidation of organophosphorus pesticides (OPPs), such as malathion and parathion, in aqueous solution was studied using conventional ozonation (O3), photolytic ozonation (O3/UV, O3/UV/H2O2), and heterogeneous catalytic ozonation (O3/TiO2/UV) processes. Experiments were performed in batch mode at laboratory scale and processes were compared in terms of disappearance kinetics. The best results of pesticide mineralization were obtained when TiO2 particles in combination with ozone (O3) and UV photolysis (λ = 254 nm) were applied. Decomposition of 99% of parent compounds were achieved in 10 min and oxon derivatives were completely removed in 30 min. The initial reaction rate increases linearly with increasing catalyst amount. Toxicity measurements of the treated solutions were carried out in order to evaluate the efficiency of the treatment methods. No detoxification was achieved for O3 and O3/UV applications. Heterogeneous photocatalytic ozonation was shown to be feasible for achieving complete decomposition of OPPs and their oxon intermediates. 相似文献