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Results of nondestructive gamma‐ray analyses of cosmogenic radionuclides (7Be, 22Na, 26Al, 46Sc, 48V, 54Mn, 56Co, 57Co, 58Co, and 60Co) in 19 fragments of the Ko?ice meteorite are presented and discussed. The activities varied mainly with position of fragments in the meteoroid body, and with fluxes of cosmic‐ray particles in the space affecting radionuclides with different half‐lives. Monte Carlo simulations of the production rates of 60Co and 26Al compared with experimental data indicate that the pre‐atmospheric radius of the meteoroid was 50 ± 5 cm. In two Ko?ice fragments, He, Ne, and Ar concentrations and isotopic compositions were also analyzed. The noble‐gas cosmic‐ray exposure age of the Ko?ice meteorite is 5–7 Myr, consistent with the conspicuous peak (or doublet peak) in the exposure age histogram of H chondrites. One sample likely contains traces of implanted solar wind Ne, suggesting that Ko?ice is a regolith breccia. The agreement between the simulated and observed 26Al activities indicate that the meteoroid was mostly irradiated by a long‐term average flux of galactic cosmic rays of 4.8 particles cm?2 s?1, whereas the short‐lived radionuclide activities are more consistent with a flux of 7.0 protons cm?2 s?1 as a result of the low solar modulation of the galactic cosmic rays during the last few years before the meteorite fall.  相似文献   
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Proteomics is a new and promising approach to evaluate potential effects of pollution. In order to investigate if there is a direct link between the protein expression profiles obtained by the SELDI-TOF MS technology and effects observed at the organism level in fish, plasma samples from unexposed and 20 ppb alkylphenol exposed female Atlantic cod (Gadus morhua) with high phenotypic variation in gonadosomatic index (GSI) were analyzed by SELDI-TOF MS. Principle component analysis (PCA) showed that the major proteomic variation present in the dataset (i.e. 23.6%) could be significantly correlated to the individual variation in GSI, which indicates that SELDI-TOF MS data can reflect effects observed at higher levels of organization in fish. Further exploration of the other principal components revealed an additional proteomic pattern specific for the alkylphenol exposed females. Hence, this study supports the usefulness of SELDI-TOF MS as a proteomic tool in ecotoxicological research.  相似文献   
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The aim of the work was to establish methodology for realistic laboratory-based test exposures of organisms to oil dispersions, specifically designed to generate parameterized toxicity data. Such data are needed to improve the value of numerical models used to predict fate and effects of oil spills and different oil spill responses. A method for continuous and predictable in-line production of oil dispersions with defined size distribution of different oil qualities was successfully established. The system enables simultaneous comparison between the effects of different concentrations of dispersion and their corresponding equilibrium water soluble fractions. Thus, net effects of the oil droplet fraction may be estimated. The method provides data for comparing the toxicity of oil dispersions generated both mechanically and with the use of chemical dispersions, incorporating the toxicity of both dissolved oil and droplets of oil.  相似文献   
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Thermal ionization mass spectrometry (TI-MS) has long been the method of choice for Pb-isotope determinations. More recently, however, inductively coupled plasma mass spectrometry (ICP-MS) has been used to determine Pb-isotope ratios for mineral exploration. The ICP-MS technique, although not as precise as TI-MS, may promote a wider application of Ph-isotope ratio methods because it allows individual isotopes to be determined more rapidly, generally without need for chemical separation (e.g., Smith et al., 1984; Hinners et al., 1987). To demonstrate the utility of the ICP-MS method, we have conducted a series of Pb-isotope measurements on several suites of samples using both TI-MS and ICP-MS.  相似文献   
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We derive the relativistic Carnot-Clausius relation and the set of fundamental equations of the thermodynamic system with the aid of Neugebauer's variational principle for several media. Some equations are already well-known in the literature but here we obtain the full set from a uniform point of view.  相似文献   
119.
In this review paper, state-of-the-art observational and numerical modeling methods for small scale turbulence and mixing with applications to coastal oceans are presented in one context. Unresolved dynamics and remaining problems of field observations and numerical simulations are reviewed on the basis of the approach that modern process-oriented studies should be based on both observations and models. First of all, the basic dynamics of surface and bottom boundary layers as well as intermediate stratified regimes including the interaction of turbulence and internal waves are briefly discussed. Then, an overview is given on just established or recently emerging mechanical, acoustic and optical observational techniques. Microstructure shear probes although developed already in the 1970s have only recently become reliable commercial products. Specifically under surface waves turbulence measurements are difficult due to the necessary decomposition of waves and turbulence. The methods to apply Acoustic Doppler Current Profilers (ADCPs) for estimations of Reynolds stresses, turbulence kinetic energy and dissipation rates are under further development. Finally, applications of well-established turbulence resolving particle image velocimetry (PIV) to the dynamics of the bottom boundary layer are presented. As counterpart to the field methods the state-of-the-art in numerical modeling in coastal seas is presented. This includes the application of the Large Eddy Simulation (LES) method to shallow water Langmuir Circulation (LC) and to stratified flow over a topographic obstacle. Furthermore, statistical turbulence closure methods as well as empirical turbulence parameterizations and their applicability to coastal ocean turbulence and mixing are discussed. Specific problems related to the combined wave-current bottom boundary layer are discussed. Finally, two coastal modeling sensitivity studies are presented as applications, a two-dimensional study of upwelling and downwelling and a three-dimensional study for a marginal sea scenario (Baltic Sea). It is concluded that the discussed methods need further refinements specifically to account for the complex dynamics associated with the presence of surface and internal waves.  相似文献   
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The trajectory and orbit of the LL7 ordinary chondrite Dishchii'bikoh are derived from low‐light video observations of a fireball first detected at 10:56:26 UTC on June 2, 2016. Results show a relatively steep ~21° inclined orbit and a short 1.13 AU semimajor axis. Following entry in Earth's atmosphere, the meteor luminosity oscillated corresponding to a meteoroid spin rate of 2.28 ± 0.02 rotations per second. A large fragment broke off at 44 km altitude. Further down, mass was lost to dust during flares at altitudes of 34, 29, and 25 km. Surviving meteorites were detected by Doppler weather radar and several small 0.9–29 g meteorites were recovered under the radar reflection footprint. Based on cosmogenic radionuclides and ground‐based radiometric observations, the Dishchii'bikoh meteoroid was 80 ± 20 cm in diameter assuming the density was 3.5 g/cm3. The meteoroid's collisional history confirms that the unusual petrologic class of LL7 does not require a different parent body than three previously observed LL chondrite falls. Dishchii'bikoh was ejected 11 Ma ago from parent body material that has a 4471 ± 6 Ma U‐Pb age, the same as that of Chelyabinsk (4452 ± 21 Ma). The distribution of the four known pre‐impact LL chondrite orbits is best matched by dynamical modeling if the source of LL chondrites is in the inner asteroid belt in a low inclined orbit, with the highly inclined Dishchii'bikoh being the result of interactions with Earth before impacting.  相似文献   
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