Geochemical and mineralogical characteristics of ion-adsorption type REE mineralization in Phuket, Thailand   总被引：1，自引：0，他引：1  

Kenzo Sanematsu  Yoshiaki Kon  Akira Imai  Koichiro Watanabe  Yasushi Watanabe 《Mineralium Deposita》2013,48(4):437-451

Geochemical and mineralogical studies were conducted on the 12-m-thick weathering profile of the Kata Beach granite in Phuket, Thailand, in order to reveal the transport and adsorption of rare earth elements (REE) related to the ion-adsorption type mineralization. The parent rock is ilmenite-series biotite granite with transitional characteristics from I type to S type, abundant in REE (592 ppm). REE are contained dominantly in fluorocarbonate as well as in allanite, titanite, apatite, and zircon. The chondrite-normalized REE pattern of the parent granite indicates enrichment of LREE relative to HREE and no significant Ce anomaly. The upper part of the weathering profile from the surface to 4.5 m depth is mostly characterized by positive Ce anomaly, showing lower REE contents ranging from 174 to 548 ppm and lower percentages of adsorbed REE from 34% to 68% compared with the parent granite. In contrast, the lower part of the profile from 4.5 to 12 m depth is characterized by negative Ce anomaly, showing higher REE contents ranging from 578 to 1,084 ppm and higher percentages from 53% to 85%. The negative Ce anomaly and enrichment of REE in the lower part of the profile suggest that acidic soil water in an oxidizing condition in the upper part mostly immobilized Ce⁴⁺ as CeO₂ and transported REE³⁺ downward to the lower part of the profile. The transported REE³⁺ were adsorbed onto weathering products or distributed to secondary minerals such as rhabdophane. The immobilization of REE results from the increase of pH due to the contact with higher pH groundwater. Since the majority of REE in the weathered granite are present in the ion-adsorption fraction with negative Ce anomaly, the percentages of adsorbed REE are positively correlated with the whole-rock negative Ce anomaly. The result of this study suggests that the ion-adsorption type REE mineralization is identified by the occurrence of easily soluble REE fluorocarbonate and whole-rock negative Ce anomaly of weathered granite. Although fractionation of REE in weathered granite is controlled by the occurrence of REE-bearing minerals and adsorption by weathering products, the ion-adsorption fraction tends to be enriched in LREE relative to weathered granite.  相似文献   

Potential of submarine-cave sediments and oxygen isotope composition of cavernicolous micro-bivalve as a late Holocene paleoenvironmental record   总被引：2，自引：1，他引：1  

Akihisa Kitamura  Nagisa Yamamoto  Tomoki Kase  Shu-ichi Ohashi  Mayumi Hiramoto  Hitoshi Fukusawa  Tsuyoshi Watanabe  Tomohisa Irino  Hiroshi Kojitani  Michiyo Shimamura  Ikuo Kawakami 《Global and Planetary Change》2007,55(4):301-316

A sediment layer (43 cm thick) and surface sediments (5 cm thick) in a submarine limestone cave (31 m water depth) on the fore-reef slope of Ie Island, off Okinawa mainland, Japan, were examined by visual, mineralogical and geochemical means. Oxygen isotope analysis was performed on the cavernicolous micro-bivalve Carditella iejimensis from both cored sediments and surface sediments, and the water temperature within the cave was recorded for nearly one year. These data show that: (1) water temperature within the cave is equal to that at 30 m deep in the open sea; (2) the biotic and non-biotic environments within the cave have persisted for the past 2000 years; (3) mud-size carbonate detritus is a major constituent of the submarine-cave deposit, and may have come mainly from the suspended carbonate mud produced on the emergent Holocene reef flat over the past two millennia; (4) the δ¹⁸O-derived temperature (T_δ18_O) of C. iejimensis suggests that the species grows between April and July; (5) the T_δ18_O of C. iejimensis from cored sediments implies that there were two warmer intervals, at AD 340 ± 40 and AD 1000 ± 40, which correspond to the Roman Warm Period and Medieval Warm Period, respectively. These suggest that submarine-cave sediments provide unique information for Holocene reef development. In addition, oxygen isotope records of cavernicolous C. iejimensis are a useful tool to reconstruct century-scale climatic variability for the Okinawa Islands during the Holocene.  相似文献   

Benefits of an impact mission to 3200 Phaethon: nature of the extinct comet and artificial meteor shower     

Toshihiro Kasuga  Jun-Ichi Watanabe  Mikiya Sato 《Monthly notices of the Royal Astronomical Society》2006,373(3):1107-1111

The asteroid 3200 Phaethon is suggested as a candidate for direct impact research. The object is considered to be an extinct comet and the parent of the Geminid meteor shower. One could say that this provides a possible argument for a space mission. Based on such a mission, this paper proposes to investigate the nature of the extinct comet and the additional interesting possibility of artificially generated meteor showers.
Dust trail theory can calculate the distribution of a bundle of trails and be used to show in which years artificial meteors would be expected. Results indicate that meteor showers will be seen on Earth about 200 yr after the event, on 2022 April 12.  相似文献   

Spatial variability of chemical tracers in surface snow along the traverse route from the coast to 1000 km inland at east Dronning Maud Land, Antarctica   总被引：1，自引：0，他引：1  

Toshitaka Suzuki  Yoshinori Iizuka  Teruo Furukawa  Kenichi Matsuoka  Kokichi Kamiyama  Okitsugu Watanabe 《极地研究(英文版)》2003,14(1)

1　IntroductionAntarcticicesheetisaburialgroundforatmosphericdeposition .Sincethereiscon tinuousinteractionbetweentheicesheetandtheatmosphere,variousatmosphericsub stancesareinjectedtotheicesheetsequentiallyintimeandspace.Therefore,verticalanalysesoftheicesheetprovideuswithinformationaboutpastclimaticchange (Delmas1 992 ;LegrandandMayewski 1 997)andhorizontalanalysesoftheicesheetprovideuswithknowledgeregardinglong rangetransportofairbornematerials (Kamiyamaetal.1 989;KreutzandMayewski 1 999)…  相似文献   

Co-accretion of the Earth-Moon system after the giant impact: reduction of the total angular momentum by lunar impact ejecta     

Ryuji Morishima  Sei-ichiro Watanabe 《Icarus》2004,168(1):60-79

Though the Moon is considered to have been formed by the so-called giant impact, the mass of the Earth immediately after the impact is still controversial. If the Moon was formed during the Earth's accretion, a subsequent accretion of residual heliocentric planetesimals onto the protoearth and the protomoon must have occurred. In this co-accretion stage, a significant amount of lunar-impact-ejecta would be ejected to circumterrestrial orbits, since the mean impact velocity of the planetesimals with the protomoon is much larger than the escape velocity of the protomoon. Orbital calculations of test particles ejected from the protomoon, whose semimajor axis is smaller than that of the present Moon, reveal that most of the particles escaping from the protomoon also escape from the Hill sphere of the protoearth and reduce the planetocentric angular momentum of the primordial Earth-Moon system. Using the results of the ejecta simulations, we investigate the evolution of the mass ratio and the total angular momentum (Earth's spin angular momentum + Moon's orbital angular momentum) of the Earth-Moon system during the co-accretion. We find that the mass of the protomoon is almost constant or rather decreases and the total angular momentum decreases significantly, if the random velocity of planetesimals is as large as the escape velocity of the protoearth. On the other hand, if the random velocity is the half of the escape velocity of the protoearth, the mass ratio is kept to be almost as large as the present value and the decrease of the total angular momentum is not so significant. Comparing with the results of giant impact simulations, we find that the mass of the protoearth immediately after the Moon-forming impact was 0.7-0.8 times the present value if the impactor-to-target mass ratio was 3:7, whereas the giant impact occurred almost in the end of the Earth's accretion if the impactor-to-target mass ratio was 1:9.  相似文献   

Hydrothermal synthesis of pumpellyite–okhotskite series minerals     

M. Akasaka  Y. Suzuki  H. Watanabe 《Mineralogy and Petrology》2003,77(1-2):25-37

Summary ?Hydrothermal experiments to synthesize pumpellyite group minerals of the pumpellyite–okhotskite series and to investigate their stability have been carried out at 200, 300 and 400 MPa P _fluid and 250–500 °C by using cold-seal pressure vessels and solid buffers of MnO₂–Mn₂O₃, Cu₂O–CuO and Cu₂O–Cu buffer assemblages. Okhotskite and pumpellyite rich in the okhotskite component crystallized from an oxide mixture starting material of Ca₄MgMn³⁺ ₃Al₂Si₆O_24.5-oxide+excess H₂O at P _fluid of 200, 300 and 400 MPa and temperatures of 300 and 400 °C. However, a single phase of okhotskite was not produced, and associated piemontite, hausmannite, wollastonite, clinopyroxene, corundum, braunite–neltnerite solid solution and alleghanyite also formed. Mn-pumpellyite of the okhotskite–pumpellyite join occurs as aggregates of needle crystals, rounded grains or flaky crystals. Chemical compositions are variable and range from pumpellyite-(Mn²⁺) to okhotskite: 31–36 SiO₂, 13–21 Al₂O₃, 12–25 total Mn₂O₃, 0.6–4 MgO and 20–24 wt.% CaO. Reconnaissance experiments using a starting material of synthetic Ca₂Mn³⁺Al₂Si₃O₁₂(OH)-piemontite at 300 MPa and temperatures of 250, 300, 400 and 500 °C indicate that Mn-rich pumpellyite can crystallize from piemontite at lower temperatures than the stability field of piemontite. The Mn-rich pumpellyite was accompanied by garnet, wollastonite and alleghanyite. The chemical compositions of the Mn-pumpellyites are 32–36 SiO₂, 18–27 Al₂O₃, 8–18 total Mn₂O₃ and 20–23 wt.% CaO. This study shows that the stability fields of piemontite, piemontite+Mn-pumpellyite, and Mn-pumpellyite range in this order with decreasing temperature under high fO₂ conditions. The maximum stability temperature of Mn-rich pumpellyite lies between 400 and 500 °C at 200–400 MPa in high fO₂ conditions. Received March 3, 2000; revised version accepted December 28, 2001  相似文献   

The EUV Imaging Spectrometer for Hinode   总被引：1，自引：0，他引：1  

J. L. Culhane  L. K. Harra  A. M. James  K. Al-Janabi  L. J. Bradley  R. A. Chaudry  K. Rees  J. A. Tandy  P. Thomas  M. C. R. Whillock  B. Winter  G. A. Doschek  C. M. Korendyke  C. M. Brown  S. Myers  J. Mariska  J. Seely  J. Lang  B. J. Kent  B. M. Shaughnessy  P. R. Young  G. M. Simnett  C. M. Castelli  S. Mahmoud  H. Mapson-Menard  B. J. Probyn  R. J. Thomas  J. Davila  K. Dere  D. Windt  J. Shea  R. Hagood  R. Moye  H. Hara  T. Watanabe  K. Matsuzaki  T. Kosugi  V. Hansteen  Ø. Wikstol 《Solar physics》2007,243(1):19-61

The EUV Imaging Spectrometer (EIS) on Hinode will observe solar corona and upper transition region emission lines in the wavelength ranges 170?–?210 Å and 250?–?290 Å. The line centroid positions and profile widths will allow plasma velocities and turbulent or non-thermal line broadenings to be measured. We will derive local plasma temperatures and densities from the line intensities. The spectra will allow accurate determination of differential emission measure and element abundances within a variety of corona and transition region structures. These powerful spectroscopic diagnostics will allow identification and characterization of magnetic reconnection and wave propagation processes in the upper solar atmosphere. We will also directly study the detailed evolution and heating of coronal loops. The EIS instrument incorporates a unique two element, normal incidence design. The optics are coated with optimized multilayer coatings. We have selected highly efficient, backside-illuminated, thinned CCDs. These design features result in an instrument that has significantly greater effective area than previous orbiting EUV spectrographs with typical active region 2?–?5 s exposure times in the brightest lines. EIS can scan a field of 6×8.5 arc?min with spatial and velocity scales of 1 arc?sec and 25 km?s^?1 per pixel. The instrument design, its absolute calibration, and performance are described in detail in this paper. EIS will be used along with the Solar Optical Telescope (SOT) and the X-ray Telescope (XRT) for a wide range of studies of the solar atmosphere.  相似文献   

Gold Mineralization at the Agawa Prospect in Yamaguchi Prefecture,Southwestern Japan          下载免费PDF全文

Ryuya Sato  Osao Sawai  Yasushi Watanabe 《Resource Geology》2016,66(2):199-212

Agawa gold prospect, located in Yamaguchi Prefecture, southwestern Japan, is a small prospect, where placer gold has been explored and mined since the 17th century. We investigated the prospect to clarify the genesis of the deposit based on the geology, hydrothermal alteration, geochronology, and ore mineralogy. The main mineralized zone of the prospect has a horizontal and vertical extensions of 500 m and 100 m, respectively, and a width of less than 100 m. Gold mineralization in the prospect occurs as dissemination and stockwork veinlets in the intensely sericitized rocks at the apical part of the Agawa dioritic porphyry intrusion at 86.5–88.5 Ma. Mineralization is typified by at least three stages – an early stage characterized by the occurrence of pyrrhotite and native gold; a middle stage by chalcopyrite; and a late stage by pyrite–bornite. Mineral assemblage and fluid inclusion microthermometry estimation suggest a trend of decreasing temperatures from 400°C to 160°C at a constant sulfur fugacity. The mineralizing fluids formed by the mixing of a hypogene fluid of possibly magmatic origin with an external lower‐temperature and lower‐salinity fluid. The mixing process decreased the temperature and salinity of the fluid, resulting in the precipitation of sulfides, native gold and Bi–Te alloys and sulfosalts. The magnetite‐series signature of the Agawa porphyry and related molybdenite‐bearing mineralization indicate that the plutonism of the San‐in granitoids belt extends to the westernmost end of the Honshu Island. The compiled geochronology and distribution of the metallic deposits in the southwestern Japan arc show that transition from ilmenite‐series to magnetite‐series plutonism started earlier in the west, and shifted eastwards with time during the period from Late Cretaceous to Paleogene.  相似文献   

Plasmaspheric hiss observed in the topside ionosphere at mid- and low-latitudes     

T. Ondoh  Y. Nakamura  S. Watanabe  K. Aikyo  T. Murakami 《Planetary and Space Science》1983,31(4):411-422

Latitudinal characteristics of ELF hiss in mid- and low-latitudes have been statistically studied by using ELF/VLF electric field spectra (50 Hz-30 kHz) from ISIS-1 and -2 received at Kashima station, Japan from 1973 to 1977. Most ISIS ELF/VLF data observed in mid- and low-latitude include ELF hiss at frequencies below a few kHz. The ELF hiss has the strongest intensity among VLF phenomena observed by the ISIS electric dipole antenna in mid- and low-latitudes, but the ELF hiss has no rising structure like the chorus in the detailed frequency-time spectrum. The ELF hiss is classified into the steady ELF hiss whose upper frequency limit is approximately constant with latitude and the ELF hiss whose upper frequency limit increases with latitude. These two types of ELF hiss occur often in medium or quiet geomagnetic activities. Sometimes there occurs a partial or complete lack of ELF hiss along an ISIS pass.Spectral shape and bandwidth of ELF hiss in the topside ionosphere are very similar to those of plasmaspheric hiss and of inner zone hiss. The occurrence rate of steady ELF hiss is about 0.3 near the geomagnetic equator and decreases rapidly with latitude around L = 3. Hence it seems likely that ELF hiss is generated by cyclotron resonant instability with electrons of several tens of keV in the equatorial outer plasmasphere beyond L = 3.Thirty-seven per cent of ELF hiss events received at Kashima station occurred during storm times and 63% of them occurred in non-storm or quiet periods. Sixty-seven per cent of 82 ELF hiss events during storm times were observed in the recovery phase of geomagnetic storms. This agrees with the previous satellite observations of ELF hiss by search coil magnetometers. The electric field of ELF hiss becomes very weak every 10 s, which is the satellite spin period, in mid- and low-latitudes, but not near the geomagnetic equator. Ray tracing results suggest that waves of ELF hiss generated in the equatorial outer plasmasphere propagate down in the electrostatic whistler mode towards the equatorial ionosphere, bouncing between the LHR reflection points in both the plasmaspheric hemispheres.  相似文献   

Seismic experiments on Showa-Shinzan lava dome using firework shots     

Hiroki Miyamachi  Hidefumi Watanabe  Takeo Moriya  Hiromu Okada 《Pure and Applied Geophysics》1987,125(6):1025-1037

Seismic experiments were conducted on Showa-Shinzan, a parasitic lava dome of volcano Usu, Hokkaido, which was formed during 1943–1945 activity. Since we found that firework shots fired on the ground can effectively produce seismic waves, we placed many seismometers on and around the dome during the summer festivals in 1984 and 1985. The internal structure had been previously studied using a prospecting technique employing dynamite blasts in 1954. The measured interval velocity across the dome in 1984 ranges 1.8–2.2 km/s drastically low compared to the results (3.0–4.0 km/s) in 1954; in addition, the velocity is 0.3–0.5 km/s higher than that in the surrounding area. The variation of the observed first arrival amplitudes can be explained by geometrical spreading in the high velocity lava dome. These observations show a marked change in the internal physical state of the dome corresponding to a drop in the measured highest temperature at fumaroles on the dome from 800°C in 1947 to 310°C in 1986.  相似文献