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141.
Geoengineering prognoses are often based on data from a limited number of investigations of soil and rock mass. There is generally a desire to reduce the uncertainty in the prognoses while minimising the investigation costs. Value of Information Analysis (VOIA) is a support for decisions regarding investigation strategies and the aim of this paper is to present methodology for VOIA that takes into account four decision alternatives where the input data could be provided by experts. The methodology will be applied in a case study where the value of information related to an investigation borehole will be calculated. The results indicate that the value of information of the borehole is low compared with the realisation costs of the investigation. It was found that models for VOIA in underground construction projects are complex but that the analysis can be simplified with extensive use of expert knowledge and calculations of the value of perfect information as a benchmark for investigation strategies.  相似文献   
142.
This paper investigates the writing of situated knowledge and explores the possibilities of enacting difference by writing differently. We present a selection of research stories in which carrier bags, sounds, baskets, gardens and potatoes are interpreted less as objects of research or metaphors to aid in analysing phenomena, than as mediators of the stories. Our stories emphasise the ontological politics of engaging with and representing the relational, the messy, the spontaneous, the unpredictable, the non‐human and bodily experiences. These stories demonstrate how writing is performative and how it is integral to the production of knowledge.  相似文献   
143.
For long time the western-central Mexico has been affected by oblique subduction caused by Farallon plate beneath North America. As result, smaller plates (e.g. Cocos Plate), several fault systems outlining crustal blocks (e.g. Michoacán block) and magmatic arcs (e.g. Paleocene-Early Oligocene magmatism and the Trans-Mexican Volcanic Belt) were developed. Still, no paleomagnetic data are available for Oligocene and Miocene. The principal aim of this study is to evaluate whether the tectonic rotations and relative motions of these blocks occurred before the Miocene. Here, we report a detailed rock-magnetic and paleomagnetic results from Tecalitlan area, located in the Michoacán block. Sixteen sites (about 150 oriented samples) were collected including one radiometrically dated diabase dike (35.0 ± 1.8 Ma). Rock-magnetic experiments permitted identification of magnetic carriers and assessment of the paleomagnetic stability. Continuous susceptibility measurements vs temperature in most cases yield reasonably reversible curves with Curie points close to that of magnetite. Reliable paleomagnetic directions were obtained for 12 sites. Inclination I and declination D of the mean paleomagnetic direction obtained in this study are I = 33.1°, D = 345.0°, and Fisherian statistical parameters are k = 25, α95 = 8.9°. The corresponding mean paleomagnetic pole position is Plat = 75.7°, Plong = 166.6°, K = 31, A95 = 8.0°. The mean inclination is in reasonably good agreement with the expected value, as derived from reference poles for the stable North America. Magnetic declination is not significantly different from that expected which is in disagreement with a counterclockwise tectonic rotation of about 20° previously reported for the studied area. Based on paleomagnetic results obtained in this study compiled with those currently available from the Michoacán Block, we propose a simple model suggesting that sometime in Eocene epoch the convergence vector of the Farallon plate relative to North America plate was normal to the trench before reaching an actual oblique convergence.  相似文献   
144.
The research studies the applicability of two elastoplastic models for the collapse prediction of the lateritic soil profile from Southeastern Brazil. These tropical soils have peculiar geotechnical behavior, due to their mineralogical composition and porous structure coming from intense process of formation. Two elastoplastic models were analyzed: the Barcelona Basic Model (BBM) and another one based on BBM, however developed for tropical soils. Oedometric tests with suction control were performed at three distinct depths of the soil profile. The BBM was not suitable for the upper layer of the soil profile, because BBM considers the compressible behavior of the soil in function of the reduction of the elastoplastic compressibility index with the increase of the matric suction. The model developed for tropical soils showed better suited to the compressible behavior of the soil profile, resulting in good prediction of the collapse potential, mainly by accepting increasing values of the elastoplastic compressibility index of the soil profile with the matric suction rise.  相似文献   
145.
Dissolved (<1 kDa), colloidal (1 kDa–0.45 μm) and particulate (>0.45 μm) size fractions of 30 elements were determined for four rivers (Sirppujoki, Laajoki, Mynäjoki and Paimionjoki), including 12 low-order inflow streams, largely affected by soil erosion and acidity in SW Finland. In addition, geochemical modelling was used to predict the formation of free ions and complexes in these rivers. Total metal concentrations were relatively high but most of the elements occurred mainly in a colloidal or particulate form and even elements expected to be very soluble occurred to a large extent in colloidal form. According to geochemical modelling these patterns could be explained by in-stream metal complexation/adsorption only to a limited extent. Instead there were strong indications that the high metal concentrations and dominant solid fractions were largely caused by erosion of metal bearing phyllosilicates. A strong influence of acid sulphate (AS) soils, known to exist in the catchment, could be clearly distinguished in Sirppujoki river as it had very high concentrations of dissolved metals, while in the two nearby rivers (Laajoki and Mynäjoki) the influence of AS soils was largely masked by eroded phyllosilicates. In Paimionjoki river the colloidal and particulate fractions dominated very strongly, indicating that total metal concentrations are almost solely controlled by erosion of phyllosilicates. Consequently, rivers draining clay plains sensitive to erosion, like those in SW Finland, have generally high “background” metal concentrations due to erosion of relatively non-toxic colloidal/particulate phyllosilicates. Thus, relying on only semi-dissolved (<0.45 μm) concentrations obtained in routine monitoring and/or speciation modelling can lead to a great overestimation of the water toxicity in this environment.  相似文献   
146.
Arsenic and antimony contamination is found at the Pezinok mining site in the southwest of the Slovak Republic. Investigation of this site included sampling and analysis of water, mineralogical analyses, sequential extraction, in addition to flow and geochemical modeling. The highest dissolved arsenic concentrations correspond to mine tailings (up to 90,000 μg/L) and the arsenic is present predominately as As(V). The primary source of the arsenic is the dissolution of arsenopyrite. Concentration of antimony reaches 7,500 μg/L and its primary source is the dissolution of stibnite. Pore water in mine tailings is well-buffered by the dissolution of carbonates (pH values between 6.6 and 7.0) and arsenopyrite grains are surrounded by reaction rims composed of ferric iron minerals. Based on sequential extraction results, most solid phase arsenic is in the reducible fraction (i.e. ferric oxyhydroxides), sulfidic fraction, and residual fraction. Distribution of antimony in the solid phase is similar, but contents are lower. The principal attenuation mechanism for As(V) is adsorption to ferric oxide and hydroxides, but the adsorption seems to be limited by the competition with Sb(V) produced by the oxidation of stibnite for adsorption sites. Water in mine tailings is at equilibrium with gypsum and calcite, but far from equilibrium with any arsenic and antimony minerals. The concentrations of arsenic and antimony in the surrounding aquifer are much lower, with maximum values of 215 and 426 μg/L, respectively. Arsenic and antimony are transported by ground water flow towards the Blatina Creek, but their loading from ground water to the creek is much lower compared with the input from the mine adits. In the Blatina Creek, arsenic and antimony are attenuated by dilution and by adsorption on ferric iron minerals in stream sediments with resulting respective concentrations of 93 and 45 μg/L at the site boundary south of mine tailing ponds.  相似文献   
147.
Phase assemblages and temperatures of phase changes provide important information about the bulk properties of fluid inclusions, and are typically obtained by microthermometry. Inclusions are synthesized in natural quartz containing an aqueous fluid with a composition in the ternary systems of H2O-NaCl2-CaCl2, H2O-NaCl-MgCl2, and H2O-CaCl2-MgCl2. This study reveals that these fluid inclusions may behave highly unpredictably at low temperatures due to the formation of metastable phase assemblages. Eutectic temperatures cannot be detected in most of the fluid inclusions containing these ternary systems. Nucleation of a variety of solid ice and salt-hydrate phases in single fluid inclusions is often partly inhibited. Raman spectroscopy at low temperatures provides an important tool for interpreting and understanding microthermometric experiments, and visualizing stable and metastable phase assemblages. Final dissolution temperatures of ice, salt-hydrates, and salt must be treated with care, as they can only be interpreted by purely empirical or thermodynamic models at stable conditions.  相似文献   
148.
149.
By using UV spectra for the O star HD 93521 taken with the ORFEUS II echelle spectrograph, we determine an 'astrophysical' f value for the S  ii   λ 94.7-nm line: f =0.00498−0.00138+0.00172 , error at 1 σ level. This is almost a factor of 30 smaller than the guessed value found in the Kurucz data base (  f =0.1472) , which was until now the only one available for this transition. We use our 'astrophysical' f to investigate the S abundance in two damped Ly α absorption systems (DLAs) observed with the UV–Visual Echelle Spectrograph (UVES) at the European Southern Observatory's 8.2-m Kueyen telescope. In the case of the absorber at z abs=3.02486 towards QSO 0347-3819, we find a sulphur column density which is consistent, within errors, with that determined by Centurión et al. by means of the λ 125.9-nm line, thus providing an external check on the accuracy of our f value. For the damped absorber at z abs=4.4680 towards BR J0307-4945, we determine a high value of the S abundance, which, however, is probably the result of blending with Ly α forest lines.  相似文献   
150.
The field properties, magnetic susceptibility, particle size, calcium carbonate content, soil micromorphology and optical luminescence ages of the upper 6.1 m and lowermost 4.7 m of the 45 m loess–palaeosol sequence at El Lambedero in the Tafí del Valle region of Tucumán Province (Sierras Pampeanas, northwest Argentina) have been used to set up a partial stratigraphy and chronology, as well as a basic pedosedimentary model of loess accumulation, palaeosol development, reworking and erosion for the site. The minimum ages derived from the basal part of the section suggest that loess began to accumulate some time before 165 ka. A thick and well‐developed pedocomplex in the upper profile is correlated with at least the latter part of marine isotope stage (MIS) 5, whereas the overlying palaeosol may be attributable to pedogenic activity during MIS 3. The absence of material younger than 33 ka close to the surface of this rounded spur landform is probably the result of either non‐deposition or erosional stripping in response to climatic change, or episodic uplift in this seismically active region. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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