A new Fe/Mn geothermometer for hydrothermal systems: Implications for high-salinity fluids at 13°N on the East Pacific Rise     

Nicholas J. Pester  Mikaella Rough  Kang Ding  William E. Seyfried Jr. 《Geochimica et cosmochimica acta》2011,75(24):7881-7892

Field and experimental investigations demonstrate the chemistry of mid-ocean ridge hydrothermal vent fluids reflects fluid-mineral reaction at higher temperatures than those typically measured at the seafloor. To account for this and, in turn, be able to better constrain sub-seafloor hydrothermal processes, we have developed an empirical geothermometer based on the dissolved Fe/Mn ratio in high-temperature fluids. Using data from basalt alteration experiments, the relationship; T (°C) = 331.24 + 112.41*log[Fe/Mn] has been calibrated between 350 and 450 °C. The apparent Fe-Mn equilibrium demonstrated by the experimental data is in good agreement with natural vent fluids, suggesting broad applicability. When used in conjunction with constraints imposed by quartz solubility, associated sub-seafloor pressures can be estimated for basalt-hosted systems. As an example, this methodology is used to interpret new data from 13°N on the East Pacific Rise, where high-temperature fluids both enriched and depleted in chloride (339-646 mmol/kg), relative to seawater, are actively venting within a close proximity. Accounting for these variable salinities, active phase separation is clearly taking place at 13°N, yet the fluid Fe/Mn ratios and the silica concentrations suggest equilibration at temperatures less than those coinciding with the two-phase region. These data show the chloride-enriched fluid reflects the highest temperature and pressure (∼432 °C, 400 bars) of equilibration, consistent with circulation near the top of the inferred magma chamber. This is in agreement with the elevated CO₂ concentration relative to the chloride-depleted fluids. The noted temperature derived from the Fe/Mn geothermometer is higher than the critical temperature for a fluid of equivalent salinity. This carries the important implication that, despite being chloride-enriched relative to seawater, these fluids evolved as the vapor component of even higher salinity brine.  相似文献   

200?years of European temperature variability: insights from and tests of the proxy surrogate reconstruction analog method   总被引：1，自引：0，他引：1  

J?rg Franke  J. Fidel Gonz��lez-Rouco  David Frank  Nicholas E. Graham 《Climate Dynamics》2011,37(1-2):133-150

Spatially resolved climate reconstructions are commonly derived from long instrumental series and proxy data via linear regression based approaches that use the main modes of the climate system. Such reconstructions have been shown to underestimate climate variability and are based upon the assumption that the main modes of climate variability are stationary back in time. Climate models simulate physically consistent climate fields but cannot be taken to represent the real past climate trajectory because of their necessarily simplified scope and chaotic internal variability. Here, we present sensitivity tests of, and a 200-year temperature reconstruction from, the PSR (Proxy Surrogate Reconstruction) method. This method simultaneously capitalizes on the individual strengths of instrumental/proxy data based reconstructions and model simulations by selecting the model states (analogs) that are most similar with proxy/instrumental data available at specific places and specific moments of time. Sensitivity experiments reveal an optimal PSR configuration and indicate that 6,500 simulation years of existing climate models provide a sufficient pool of possible analogs to skillfully reconstruct monthly European temperature fields during the past 200?years. Reconstruction verification based upon only seven instrumental stations indicates potential for extensions back in time using sparse proxy data. Additionally the PSR method allows evaluation of single time series, in this case the homogeneity of instrumental series, by identifying inconsistencies with the reconstructed climate field. We present an updated European temperature reconstruction including newly homogenized instrumental records performed with the computationally efficient PSR method that proves to capture the total variance of the target.  相似文献   

A Simplified Approach to Bridge Substructure Design     

Thomas Nicholas  Karl E. Barth  David M. Boyajian 《Geotechnical and Geological Engineering》2011,29(1):27-35

Strut-and-tie modeling is an analysis and design tool for reinforced concrete elements in which it may be assumed that internal stresses are transferred through a truss mechanism. The tensile ties and compressive struts serve as truss members connected by nodal zones. The internal truss idealized by the strut-and-tie model implicitly account for the distribution of both flexure and shear. In 1998, the AASHTO LRFD Bridge Specifications (1998) incorporated the strut-and-tie modeling procedure for the analysis and design of deep reinforced concrete members where sectional design approaches are not valid. In most instances, hammerhead piers can be defined as deep reinforced concrete members and therefore, should be designed using the strut-and-tie modeling approach. However, most bridge designers have not embraced the strut-and-tie model due to the unfamiliarity with the design procedure, the inability to check the truss model??s validity (without laboratory tests or a finite element model), and the time it takes to complete the strut-and-tie model analysis and design. Therefore, with the formulation of a well-defined strut-and-tie modeling procedure, practicing engineers will become more comfortable with the design method and employ the method more often and more consistently. This paper presents a uniform design procedure for employing strut-and-tie modeling for hammerhead piers that can be readily utilized by practicing engineers. Additionally, a comparison between the strut-and-tie method and standard sectional design practices will be performed for a typical hammerhead pier.  相似文献   

Observed and simulated Lagrangian and eddy characteristics of the East Australian Current and the Tasman Sea     

Gary B. Brassington  Nicholas SummonsRick Lumpkin 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(5):559-573

New insights into the Lagrangian and eddy dynamical processes within the East Australian Current (EAC) and the Tasman Sea are presented. We briefly discuss the past campaigns undertaken to observe the EAC and the Tasman Sea eddies as well as the motivation to renew the deployment of drifting buoys into the EAC and the Tasman Sea. The specific features discussed are motivated by the recent observing campaigns using drifting buoys and the availability of high spatial- and temporal-resolution estimates of the ocean state and circulation from eddy resolving models. The interpretation of these features is also aided by other components of the ocean observing system. The dynamics presented includes: (a) transient EAC separation through a vortex dipole, (b) stratified vortex mergers and secondary circulation of EAC eddies, (c) eddy networks in the Tasman Sea and (d) formation and propagation of the EAC separation point. The importance of these dynamical features to the EAC and the Tasman Sea and their implications for the observing system and modelling are discussed.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2010     

Nicholas Deichmann  John Clinton  Stephan Husen  Benjamin Edwards  Florian Haslinger  Donat Fäh  Domenico Giardini  Philipp Kästli  Urs Kradolfer  Stefan Wiemer 《Swiss Journal of Geoscience》2011,104(3):537-547

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2010. During this period, 407 earthquakes and 85 quarry blasts were detected and located in the region under consideration. With a total of only 19 events with M_L ≥ 2.5, the seismic activity in the year 2010 was below the average over the previous 35 years. The two most noteworthy earthquakes were the M_L 3.4 Barrhorn event near Sankt Niklaus (VS) and the M_L 3.0 event of Feldkirch, both of which produced shaking of intensity IV.  相似文献   

Numerical modelling of intra-wave sediment transport on sandy beaches using a non-hydrostatic,wave-resolving model     

Mancini  Giulia  Briganti  Riccardo  McCall  Robert  Dodd  Nicholas  Zhu  Fangfang 《Ocean Dynamics》2021,71(1):1-20

Ocean Dynamics - The mutual feedback between the swash zone and the surf zone is known to affect large-scale morphodynamic processes such as breaker bar migration on sandy beaches. To fully resolve...  相似文献   

The 2dF Galaxy Redshift Survey: power-spectrum analysis of the final data set and cosmological implications     

Shaun Cole  Will J. Percival  John A. Peacock  Peder Norberg  Carlton M. Baugh  Carlos S. Frenk  Ivan Baldry  Joss Bland-Hawthorn  Terry Bridges  Russell Cannon  Matthew Colless  Chris Collins  Warrick Couch  Nicholas J. G. Cross  Gavin Dalton  Vincent R. Eke  Roberto De Propris  Simon P. Driver  George Efstathiou  Richard S. Ellis  Karl Glazebrook  Carole Jackson  Adrian Jenkins  Ofer Lahav  Ian Lewis  Stuart Lumsden  Steve Maddox  Darren Madgwick  Bruce A. Peterson  Will Sutherland  Keith Taylor 《Monthly notices of the Royal Astronomical Society》2005,362(2):505-534

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Colors of dynamically associated asteroid pairs     

Nicholas A. Moskovitz 《Icarus》2012,221(1):63-71

Recent dynamical studies have identified pairs of asteroids that reside in nearly identical heliocentric orbits. Possible formation scenarios for these systems include dissociation of binary asteroids, collisional disruption of a single parent body, or spin-up and rotational fission of a rubble-pile. Aside from detailed dynamical analyses and measurement of rotational light curves, little work has been done to investigate the colors or spectra of these unusual objects. A photometric and spectroscopic survey was conducted to determine the reflectance properties of asteroid pairs. New observations were obtained for a total of 34 individual asteroids. Additional photometric measurements were retrieved from the Sloan Digital Sky Survey Moving Object Catalog. Colors or spectra for a total of 42 pair components are presented here. The main findings of this work are: (1) the components in the observed pair systems have the same colors within the uncertainties of this survey, and (2) the color distribution of asteroid pairs appears indistinguishable from that of all Main Belt asteroids. These findings support a scenario of pair formation from a common progenitor and suggest that pair formation is likely a compositionally independent process. In agreement with previous studies, this is most consistent with an origin via binary disruption and/or rotational fission.  相似文献   

Surface geochemical and biogeochemical expression of base‐metal mineralization at Woodlawn,New South Wales,Australia     

W. R. Ryall  T. Nicholas 《Australian Journal of Earth Sciences》2013,60(3-4):187-195

The presence of base‐metal mineralization at Woodlawn was first recognised early in 1968 when a roadside reconnaissance geochemical sampling survey, conducted over felsic volcanic rocks in the Goulburn‐Tarago area, encountered anomalous B horizon soils containing up to 200 ppm Cu, 800 ppm Pb and 300 ppm Zn. Regional soil thresholds have been determined at 50 ppm Cu, 90 ppm Pb and 50 ppm Zn. Chip samples from the subsequently located gossan revealed up to 2000 ppm Cu, 8000 ppm Pb and 2000 ppm Zn, 500 ppm Sn, 25 ppm Ag and 3000 ppm As.

The first grid B horizon soil geochemical survey was conducted in 1968 over the gossan and surrounding area, and repeated with closer spaced sampling in the first half of 1970. The first survey delineated strong Cu (to 1000 ppm) and Pb (to 2500 ppm) anomalies coincident with the gossan zone, and intense hydromorphic zinc anomalies (to 3000 ppm) located down slope from the gossan in residual clay‐soils derived from dolerite bedrock. Threshold values have been determined at 140 ppm Cu, 700 ppm Pb and 580 ppm Zn. Ag and Sn in B horizon soils show pronounced anomalies coincident with the gossan and are suitable metals for geochemical target definition. Of fourteen trace elements determined in 1974 from B and C horizon soils on two lines across the ore zone Cu, Pb, Zn, Se, Ba, Sn and Ag show direct correlation with the mineralization, whereas Cd and Mn show moderate hydromorphic dispersion, having accumulated principally in clay soils derived from dolerite weathering. As, Sb and Bi, whilst responding over the ore zone, show elevated values in soils over hanging‐wall units; Ni and Co show maximum levels in soils over dolerite bedrock.

Bark and leaves of Acacia mearnsii, collected from a line across the gossan, contain anomalous levels of Cu, Pb, Zn, Sn and Ti near the ore zone, and weaker, but clearly anomalous Mn and Ni levels over dolerite bedrock. Both bark and leaves of Acacia mearnsii reflect the presence of concealed mineralization. The shrub Solanum linearifolium grows preferentially over and close to the Woodlawn ore zone, where it contains up to 840 ppm Cu, 250 ppm Pb, 7300 ppm Zn, 6 ppm Sn and 250 ppm Ti in leaf ash compared with levels of 200 ppm Cu, 2 ppm Pb, 400 ppm Zn, 0.8 ppm Sn and 60 ppm Ti in plants growing 1.5 km from the ore zone. This shrub has potential as an indicator of base‐metal mineralization.  相似文献   

Noble gas and isotope geochemistry in western Canadian Arctic watersheds: tracing groundwater recharge in permafrost terrain     

Nicholas Utting  Bernard Lauriol  Neil Mochnacz  Werner Aeschbach-Hertig  Ian Clark 《Hydrogeology Journal》2013,21(1):79-91

In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems with features including the occurrence of year-round open water and the formation of icings, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Stable isotopes (δ¹⁸O, δD, δ¹³C_DIC), and noble gases have proved useful to study groundwater recharge and flow of groundwater which discharges along rivers in Canada’s western Arctic. In these studies of six catchments, groundwater recharge was determined to be a mix of snowmelt and precipitation. All systems investigated show that groundwater has recharged through organic soils with elevated P_CO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 5 °C, which when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater circulation times were found to be up to 31 years for non-thermal waters using the ³?H-³He method.  相似文献