The surface chemistry of multi-oxide silicates     

Eric H. Oelkers  Sergey V. Golubev  Claire Chairat  Oleg S. Pokrovsky  Jacques Schott 《Geochimica et cosmochimica acta》2009,73(16):4617-6554

The surface chemistry of natural wollastonite, diopside, enstatite, forsterite, and albite in aqueous solutions was characterized using both electrokinetic techniques and surface titrations performed for 20 min in batch reactors. Titrations performed in such reactors allow determination of both proton consumption and metal release from the mineral surface as a function of pH. The compositions, based on aqueous solution analysis, of all investigated surfaces vary dramatically with solution pH. Ca and Mg are preferentially released from the surfaces of all investigated divalent metal silicates at pH less than ∼8.5-10 but preferentially retained relative to silica at higher pH. As such, the surfaces of these minerals are Si-rich and divalent metal poor except in strongly alkaline solutions. The preferential removal of divalent cations from these surfaces is coupled to proton consumption. The number of protons consumed by the preferential removal of each divalent cation is pH independent but depends on the identity of the mineral; ∼1.5 protons are consumed by the preferential removal of each Ca atom from wollastonite, ∼3 protons are consumed by the preferential removal of each Mg or Ca atom from diopside or enstatite, and ∼4 protons are consumed by the preferential removal of each Mg from forsterite. These observations are interpreted to stem from the creation of additional ‘internal’ adsorption sites by the preferential removal of divalent metal cations which can be coupled to the condensation of partially detached Si. Similarly, Na and Al are preferentially removed from the albite surface at 2 > pH > 11; mass balance calculations suggest that three protons are consumed by the preferential removal of each Al atom from this surface over this entire pH range. Electrokinetic measurements on fresh mineral powders yield an isoelectric point (pH_IEP) 2.6, 4.4, 3.0, 4.5, and <1, for wollastonite, diopside, enstatite, forsterite, and albite, respectively, consistent with the predominance of SiO₂ in the surface layer of all of these multi-oxide silicates at acidic pH. Taken together, these observations suggest fundamental differences between the surface chemistry of simple versus multi-oxide minerals including (1) a dependency of the number and identity of multi-oxide silicate surface sites on the aqueous solution composition, and (2) the dominant role of metal-proton exchange reactions on the reactivity of multi-oxide mineral surfaces including their dissolution rate variation with aqueous solution composition.  相似文献   

Steric Sea-Level Change and its Impact on the Gravity Field caused by Global Climate Change     

Sabine Roedelsperger  Michael Kuhn  Oleg Makarynskyy  Carl Gerstenecker 《Pure and Applied Geophysics》2008,165(6):1131-1151

It is sometimes assumed that steric sea-level variations do not produce a gravity signal as no net mass change, thus no change of ocean bottom pressure is associated with it. Analyzing the output of two CO₂ emission scenarios over a period of 2000 years in terms of steric sea-level changes, we try to quantify the gravitational effect of steric sea-level variations. The first scenario, computed with version 2.6 of the Earth System Climate Model developed at the University of Victoria, Canada (UVic ESCM), is implemented with a linear CO₂ increase of 1% of the initial concentration of 365 ppm and shows a globally averaged steric effect of 5.2 m after 2000 years. In the second scenario, computed with UVic ESCM version 2.7, the CO₂ concentration increases quasi-exponentially to a level of 3011 ppm and is hold fixed afterwards. The corresponding globally averaged steric effect in the first 2000 years is 2.3 m. We show, due to the (vertical) redistribution of ocean water masses (expansion or contraction), the steric effect results also in a small change in the Earth’s gravity field compared to usually larger changes associated with net mass changes. Maximum effects for computation points located on the initial ocean surface can be found in scenario 1, with the effect on gravitational attraction and potential ranging from 0.0 to −0.7·10⁻⁵ m s⁻² and −3·10⁻³ to 6·10⁻³ m² s⁻², respectively. As expected, the effect is not zero but negligible for practical applications.  相似文献   

Methane with Abnormally High δ13C and δD Values from the Coastal Hot Springs in Lake Baikal     

Kalmychkov  G. V.  Hachikubo  A.  Pokrovsky  B. G.  Minami  H.  Yamashita  S.  Khlystov  O. M. 《Lithology and Mineral Resources》2020,55(6):439-444

Lithology and Mineral Resources - We studied the composition and isotopic characteristics (δ13C and δD) of hydrocarbon gases from the Kotelnikovsky, Zmeiny, and Goryachnisky hot springs...  相似文献   

Group-velocity tomography of South America and the surrounding oceans   总被引：2，自引：0，他引：2  

Oleg Vdovin  José A. Rial  Anatoli L. Levshin  & Michael H. Ritzwoller 《Geophysical Journal International》1999,136(2):324-340

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Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin   总被引：1，自引：1，他引：0  

Alexey A. Krylov  Oleg M. Khlystov  Akihiro Hachikubo  Hirotsugu Minami  Yutaka Nunokawa  Hitoshi Shoji  Tamara I. Zemskaya  Lieven Naudts  Tatyana V. Pogodaeva  Masato Kida  Gennady V. Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):427-437

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.  相似文献   

A new mineral species rossovskyite, (Fe3+,Ta)(Nb,Ti)O4: crystal chemistry and physical properties     

Sergey I. Konovalenko  Sergey A. Ananyev  Nikita V. Chukanov  Ramiza K. Rastsvetaeva  Sergey M. Aksenov  Anna A. Baeva  Ramil R. Gainov  Farit G. Vagizov  Oleg N. Lopatin  Tatiana S. Nebera 《Physics and Chemistry of Minerals》2015,42(10):825-833

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Paleogeographic evolution of the Southern Pannonian Basin: 40Ar/39Ar age constraints on the Miocene continental series of Northern Croatia     

Oleg Mandic  Arjan de Leeuw  Jeronim Buli?  Klaudia F. Kuiper  Wout Krijgsman  Zlata Juri?i?-Pol?ak 《International Journal of Earth Sciences》2012,101(4):1033-1046

The Pannonian Basin, originating during the Early Miocene, is a large extensional basin incorporated between Alpine, Carpathian and Dinaride fold-thrust belts. Back-arc extensional tectonics triggered deposition of up to 500-m-thick continental fluvio-lacustrine deposits distributed in numerous sub-basins of the Southern Pannonian Basin. Extensive andesitic and dacitic volcanism accompanied the syn-rift deposition and caused a number of pyroclastic intercalations. Here, we analyze two volcanic ash layers located at the base and top of the continental series. The lowermost ash from Mt. Kalnik yielded an ⁴⁰Ar/³⁹Ar age of 18.07?±?0.07?Ma. This indicates that the marine-continental transition in the Slovenia-Zagorje Basin, coinciding with the onset of rifting tectonics in the Southern Pannonian Basin, occurs roughly at the Eggenburgian/Ottnangian boundary of the regional Paratethys time scale. This age proves the synchronicity of initial rifting in the Southern Pannonian Basin with the beginning of sedimentation in the Dinaride Lake System. Beside geodynamic evolution, the two regions also share a biotic evolutionary history: both belong to the same ecoregion, which we designate here as the Illyrian Bioprovince. The youngest volcanic ash level is sampled at the Glina and Karlovac sub-depressions, and both sites yield the same ⁴⁰Ar/³⁹Ar age of 15.91?±?0.06 and 16.03?±?0.06?Ma, respectively. This indicates that lacustrine sedimentation in the Southern Pannonian Basin continued at least until the earliest Badenian. The present results provide not only important bench marks on duration of initial synrift in the Pannonian Basin System, but also deliver substantial backbone data for paleogeographic reconstructions in Central and Southeastern Europe around the Early–Middle Miocene transition.  相似文献   

Primary Production and the Hydrochemical Parameters of the Salt Lakes in the North-Western Part of the Crimea(Russia)     

Vladimir POPOVICHEV  Oleg EREMIN  Natalya RODIONOVA  Tatyana TSARINA  Nikolai BOBKO 《《地质学报》英文版》2014,88(Z1):96-97

正1 Introduction It is known that more than 300 lakes and lagoons are present in the Crimean Peninsula,which are divided depending on position to 7 groups:Perekop,Tarkhankut,Evpatoriyskaya,Khersonesskaya,lake on the mountainpastures,Kerch and Genicheskaya.Almost the all lakes,with the exception of the small freshwater lakes,which situated on mountain pastures of the Main ridge of  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000449     

Oleg G.Safonov  Leonid Y.Aranovich 《地学前缘(英文版)》2014,5(5):711-727

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.  相似文献   

Relationship between MODIS based Aerosol Optical Depth and PM10 over Croatia     

Sanja Grgurić  Josip Križan  Goran Gašparac  Oleg Antonić  Zdravko Špirić  Rodelise E. Mamouri  A. Christodoulou  Argyro Nisantzi  Athos Agapiou  Kyriakos Themistocleous  Kurt Fedra  Charalambos Panayiotou  Diofantos Hadjimitsis 《Central European Journal of Geosciences》2014,6(1):2-16

This study analyzes the relationship between Aerosol Optical Depth (AOD) obtained from Terra and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) and ground-based PM10 mass concentration distribution over a period of 5 years (2008–2012), and investigates the applicability of satellite AOD data for ground PM10 mapping for the Croatian territory. Many studies have shown that satellite AOD data are correlated to ground-based PM mass concentration. However, the relationship between AOD and PM is not explicit and there are unknowns that cause uncertainties in this relationship. The relationship between MODIS AOD and ground-based PM10 has been studied on the basis of a large data set where daily averaged PM10 data from the 12 air quality stations across Croatia over the 5 year period are correlated with AODs retrieved from MODIS Terra and Aqua. A database was developed to associate coincident MODIS AOD (independent) and PM10 data (dependent variable). Additional tested independent variables (predictors, estimators) included season, cloud fraction, and meteorological parameters — including temperature, air pressure, relative humidity, wind speed, wind direction, as well as planetary boundary layer height — using meteorological data from WRF (Weather Research and Forecast) model. It has been found that 1) a univariate linear regression model fails at explaining the data variability well which suggests nonlinearity of the AOD-PM10 relationship, and 2) explanation of data variability can be improved with multivariate linear modeling and a neural network approach, using additional independent variables.  相似文献