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241.
242.
Temporal and spatial changes in marine benthic habitats in relation to the EU Water Framework Directive: The use of sediment profile imagery 总被引:1,自引:0,他引:1
In 2002 to 2006, sediment profile imagery (SPI) was used to study the environmental impact of eutrophication-induced irregular and seasonal hypoxia on marine benthic habitats in six regions in the Skagerrak and Kattegat (West Sweden). The benthic habitat quality (BHQ) was assessed by parameterisation of biogenic structures observed by the SPI technique, and benthic quality status was related to the EU Water Framework Directive (EU-WFD). The temporal changes were analysed by a 5-factor nested ANOVA and significant temporal differences were recorded within three of the regions. Two of these were affected by hypoxia in the deeper parts and one was probably affected by hypoxia below the halocline. The environmental quality status according to the EU-WFD was bad to high in two regions, moderate to good in three regions, and good to high, i.e., acceptable according to the EU-WFD, in only one region. As BHQ is highly correlated to benthic faunal data, measures have to be taken to improve the coastal water quality in five of the six studied areas. 相似文献
243.
244.
Marina G. Persova Yuri G. Soloveichik Georgy M. Trigubovich Denis V. Vagin Petr A. Domnikov 《Geophysical Prospecting》2014,62(5):1193-1201
A large closed wire loop is generally used in field experiments for testing airborne electrical exploration equipment. Thus, methods are required for the precise calculation of an electromagnetic response in the presence of a closed wire loop. We develop a fast and precise scheme for calculating the transient response for such a closed loop laid out at the surface of a horizontally layered conductive ground. Our scheme is based on the relationship between the magnetic flux flowing through a closed loop and the current induced in it. The developed scheme is compared with 2D and 3D finite‐element modelling for several positions of an airborne electromagnetic system flying over a closed loop. We also study the coupling effect between the current flowing in the closed loop and the current flowing in the horizontally layered conductive medium. The result shows that for the central position of the transmitter, the difference between axisymmetrical finite‐element modelling and our scheme is less than 1%. Moreover, for the non‐coaxial transmitter–receiver–loop system, the solution obtained by our scheme is in good agreement with full 3D finite‐element modelling, and our total simulation time is substantially lower: 1 minute versus 120 hours. 相似文献
245.
Pablo A. Lara-Martín Eduardo González-Mazo Mira Petrovic Damià Barceló Bruce J. Brownawell 《Marine pollution bulletin》2014
This work deals with the environmental distribution of nonionic surfactants (nonylphenol and alcohol ethoxylates), their metabolites (NP, nonylphenol; NPEC, nonylphenol ethoxycarboxylates; and PEG, polyethylene glycols) and a selection of 64 pharmaceuticals in the Long Island Sound (LIS) Estuary which receives important sewage discharges from New York City (NYC). Most target compounds were efficiently removed (>95%) in one wastewater treatment plant monitored, with the exception of NPEC and some specific drugs (e.g., hydrochlorothiazide). Concentrations of surfactants (1.4–4.5 μg L−1) and pharmaceuticals (0.1–0.3 μg L−1) in seawater were influenced by tides and sampling depth, consistent with salinity differences. Surfactants levels in suspended solids samples were higher than 1 μg g−1, whereas only most hydrophobic or positively charged pharmaceuticals could be found (e.g., tamoxifen, clarithromycin). Maximum levels of target compounds in LIS sediments (PEG at highest concentrations, 2.8 μg g−1) were measured nearest NYC, sharply decreasing with distance from major sewage inputs. 相似文献
246.
The Pitzer’s interaction parameters, λN–M, involving the Mth cationic Al species Al3+ or AlOH2+ or AlO+ and the Nth neutral species SiO2(aq) (at temperatures of 25–300 °C) or CO2(aq) (at temperatures of 25–150 °C), have been evaluated through empirical linear relationships between λN–M and the surface electrostatic field of the ionic species of interest. These relationships have been obtained starting from the known λN–M for both SiO2(aq) and CO2(aq) with the main dissolved cations. The Pitzer’s interaction parameter thus estimated for the pair CO2(aq)–Al3+ at 25 °C, 0.327, is 20–40% higher than the corresponding values obtained from CO2 solubilities in concentrated solutions of AlCl3, 0.272 ± 0.010 (2σ), and Al2(SO4)3, 0.232 ± 0.002 (2σ), partly corroborating the empirical approach adopted in this study. To test the Pitzer’s interaction coefficients for cationic Al species with aqueous SiO2, the log K values of the kaolinite dissolution reaction have been computed starting from available experimental data at 23–25 °C and ionic strengths of 0.0001–0.12 mol/kg adopting, alternatively, the Pitzer’s equations and the Debye–Hückel equation. A satisfactory agreement has been found between the log K values obtained through these two approaches, with maximum deviations of 0.11–0.12 log units. This good convergence of results is encouraging as it represents a necessary condition to prove the reliability of the Pitzer’s interaction coefficients estimated in this work. These results are a first step to take into account specific interactions among solutes in concentrated electrolyte solutions, such as those hosted in sedimentary basins or geothermal waters, for instance through the Pitzer’s equations. However, experimental or field data at higher ionic strengths are absolutely necessary to validate the reliability of the Pitzer’s interaction coefficients determined in this study. 相似文献
247.
Carmine Apollaro Marina Accornero Luigi Marini Donatella Barca Rosanna De Rosa 《Applied Geochemistry》2009
This work is aimed at investigating the weathering processes of the granodiorites cropping out in a small catchment of the Sila Massif. The mineral constituents in this granodiorite are plagioclase, often zoned with a Ca-rich core and a Na-rich rim, quartz, chlorite, K-feldspar, white mica and epidote. During this study, dolomite was discovered in local stream sediments, as separate monomineralic grains, probably resulting from erosion of veins cutting the crystalline rocks. Prevailing dissolution of foreign dolomite and a Ca-rich plagioclase is suggested by the Ca–Mg–HCO3 chemical composition of local groundwaters and stream waters, which is rather unexpected for waters interacting with granitoid rocks. These qualitative observations are quantitatively confirmed by reaction path modelling of the weathering processes occurring in the study area, which was carried out using the EQ3/6 software package, version 8.0, and the Double Solid Reactant Method. Indeed, it was possible to ascertain that the release of both major dissolved constituents and several trace elements (Ba, Co, Cr, Fe, Mn, Ni, Pb, Sr, V and Zn), from rocks to waters, is chiefly controlled by the dissolution of foreign dolomite and the Ca-rich core of zoned plagioclases. 相似文献
248.
Lateglacial and Holocene palaeohydrology in the western Mediterranean region: The Lake Estanya record (NE Spain) 总被引:3,自引:0,他引:3
Mario Morelln Blas Valero-Garcs Teresa Vegas-Vilarrúbia Penlope Gonzlez-Sampriz
scar Romero Antonio Delgado-Huertas Pilar Mata Ana Moreno Mayte Rico Juan Pablo Corella 《Quaternary Science Reviews》2009,28(25-26):2582-2599
The multi-proxy analysis of sediment cores recovered in karstic Lake Estanya (42°02′ N, 0°32′ E; 670 m a. s. l., NE Spain), located in the transitional area between the humid Pyrenees and the semi-arid Central Ebro Basin, provides the first high-resolution, continuous sedimentary record in the region, extending back the last 21 000 years. The integration of sedimentary facies, elemental and isotopical geochemistry and biogenic silica, together with a robust age model based on 17 AMS radiocarbon dates, enables precise reconstruction of the main hydrological and environmental changes in the region during the last deglaciation.Arid conditions, represented by shallow lake levels, predominantly saline waters and reduced organic productivity occurred throughout the last glacial maximum (21–18 cal kyrs BP) and the lateglacial, reaching their maximum intensity during the period 18–14.5 cal kyrs BP (including Heinrich event 1) and the Younger Dryas (12.9–11.6 cal kyrs BP). Less saline conditions characterized the 14.5–12.6 cal kyrs BP period, suggesting higher effective moisture during the Bölling/Allerød. The onset of more humid conditions started at 9.4 cal kyrs, indicating a delayed hydrological response to the onset of the Holocene which is also documented in several sites of the Mediterranean Basin. Higher, although fluctuating, Holocene lake levels were punctuated by a mid Holocene arid period between 4.8 and 4.0 cal kyrs BP. A major lake-level rise occurred at 1.2 cal kyrs BP, conducive to the establishment of conditions similar to the present and interrupted by a last major water level drop, occurring around 800 cal yrs BP, which coincides with the Medieval Climate Anomaly.The main hydrological stages in Lake Estanya are in phase with most Western Mediterranean and North Atlantic continental and marine records, but our results also show similarities with other Iberian and northern African reconstructions, emphasizing peculiarities of palaeohydrological evolution of the Iberian Peninsula during the last deglaciation. 相似文献
249.
Marina?ValerEmail authorView authors OrcID profile Pierre?Schiano Patrick?Bachèlery 《Contributions to Mineralogy and Petrology》2017,172(9):74
Major and trace element compositions were obtained for bulk rocks and melt inclusions hosted in olivine crystals (Fo > 85) from the adventive cones of the Piton de La Fournaise volcano (La Réunion Island). Ratios of highly incompatible trace elements for these magmas are used to identify the nature of the La Réunion mantle plume source. Although adventive cone lavas display unusual major element compositions compared to the historical lavas of the volcano (e.g., lower CaO/Al2O3), trace element data suggest that the magmas emitted by the adventive cones originate from a common chemical source. This source may correspond to either a homogeneous mixed source of different mantle components or a near-primitive less-differentiated mantle source. The melt inclusions display ratios of highly incompatible elements (e.g., Th/La, Nb/La) which are similar to primitive mantle values, and lower Nb/U ratios compared to most oceanic basalts. These results and previous isotopic and trace element data suggest that La Réunion plume samples a source which is intermediate between a primitive-like mantle domain and a slightly depleted one almost unaffected by the recycling processes. This source could have originated from early depletion of the primitive mantle. Assuming a depletion 4.45 Gyr ago, ~10% melting of this slightly depleted source could explain the enriched trace element concentrations of the melt inclusions. 相似文献
250.
Claude Robin Pablo Samaniego Jean-Luc Le Pennec Michel Fornari Patricia Mothes Johannes van der Plicht 《Bulletin of Volcanology》2010,72(9):1109-1129
Fieldwork, radiometric (40Ar/39Ar and 14C) ages and whole-rock geochemistry allow a reconstruction of eruptive stages at the active, mainly dacitic, Pichincha Volcanic
Complex (PVC), whose eruptions have repeatedly threatened Quito, most recently from 1999 to 2001. After the emplacement of
basal lavas dated at ∼1100 to 900 ka, the eruptive activity of the old Rucu Pichincha volcano lasted from ∼850 ka to ∼150 ka
before present (BP) and resulted in a 15 × 20 km-wide edifice, which comprises three main building stages: (1) A lower stratocone
(Lower Rucu, ∼160 km3 in volume) developed from ∼850 to 600 ka; (2) This edifice was capped by a steeper-sided and less voluminous cone (the Upper
Rucu, 40–50 km3), the history of which started 450–430 ka ago and ended around 250 ka with a sector collapse; (3) A smaller (8–10 km3) but more explosive edifice grew in the avalanche amphitheatre and ended Rucu Pichincha's history about 150 ka ago. The Guagua
Pichincha volcano (GGP) was developed from 60 ka on the western flank of Rucu with four growth stages separated by major catastrophic
events. (1) From ∼60 to 47 ka, a basal effusive stratocone developed, terminating with a large ash-and-pumice flow event.
(2) This basal volcano was followed by a long-lasting dome building stage and related explosive episodes, the latter occurring
between 28–30 and 22–23 ka. These first two stages formed the main GGP (∼30 km3), a large part of which was removed by a major collapse 11 ka BP. (3) Sustained explosive activity and viscous lava extrusions
gave rise to a new edifice, Toaza (4–5 km3 in volume), which in turn collapsed around 4 ka BP. (4) The ensuing amphitheatre was partly filled by the ∼1-km3 Cristal dome, which is the historically active centre of the Pichincha complex. The average output rate for the whole PVC
is 0.29 km3/ka. Nevertheless, the chronostratigraphic resolution we obtained for Lower Rucu Pichincha and for the two main edifices of
Guagua Pichincha (main GGP and Toaza), leads to eruptive rates of 0.60–0.65 km3/ka during these construction stages. These output rates are compared to those of other mainly dacitic volcanoes from continental
arcs. Our study also supports an overall SiO2 and large-ion lithophile elements enrichment as the PVC develops. In particular, distinctive geochemical signatures indicate
the involvement of a new magma batch at the transition between Rucu and Guagua. At the GGP, the same phenomenon occurs at
each major collapse event marking the onset of the ensuing magmatic stage. Since the 11-ka-BP collapse event, this magmatic
behaviour has led to increasingly explosive activity. Four explosive cycles of between 100 and 200 years long have taken place
at the Cristal dome in the past 3.7 ka, and repose intervals between these cycles have tended to decrease with time. As a
consequence, we suggest that the 1999–2001 eruptive period may have initiated a new eruptive cycle that might pose a future
hazard to Quito (∼2 million inhabitants). 相似文献