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461.
462.
The variability in salinity and temperature in the southwest lagoon of New Caledonia (2100 km2) under non-storm conditions is analysed using a 4-year dataset (1997–2001). Seasonal and interannual variations in salinity are amplified nearshore. Temperature is larger in bays than in the open lagoon during summer, the reverse is true in winter. El Niño Southern Oscillation (ENSO) related nearshore temperature variations parallel those at regional scale, but with seasonal variations amplified. Haline stratification, if any, is enhanced in coastal areas. To cite this article: S. Ouillon et al., C. R. Geoscience 337 (2005).  相似文献   
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The molecular environment of iodine in reference inorganic and organic compounds, and in dry humic and fulvic acids (HAs and FAs) extracted from subsurface and deep aquifers was probed by iodine L3-edge X-ray absorption spectroscopy. The X-ray absorption near-edge structure (XANES) of iodine spectra from HAs and FAs resembled those of organic references and displayed structural features consistent with iodine forming covalent bonds with organic molecules. Simulation of XANES spectra by linear combination of reference spectra suggested the predominance of iodine forming covalent bonds to aromatic rings (aromatic-bound iodine). Comparison of extended X-ray absorption fine structure (EXAFS) spectra of reference and samples further showed that iodine was surrounded by carbon shells at distances comparables to those for references containing aromatic-bound iodine. Quantitative analysis of EXAFS spectra indicated that iodine was bound to about one carbon at a distance d (I-C) of 2.01(4)-2.04(9) Å, which was comparable to the distances observed for aromatic-bound iodine in references (1.99(1)-2.07(6) Å), and significantly shorter than that observed for aliphatic-bound iodine (2.15(2)-2.16(2) Å). These results are in agreement with previous conclusions from X-ray photoelectron spectroscopy and from electrospray ionization mass spectrometry. These results collectively suggest that the aromatic-bound iodine is stable in the various aquifers of this study.  相似文献   
465.
The effect of the small fraction of clays on the rheological behaviour of alpine debris flow is poorly understood. This is partly due to the complexity of the debris flow mineralogy and the broad particle size distribution. This study has investigated this issue by simulating an alpine debris flow with a mixture of well characterized fractions and then varying the clay fraction composition. Four samples were tested, ranging from a clay fraction made up of only kaolinite (1:1 type clay) to samples where 80 per cent of the kaolinite is replaced by bedeillite (a 2:1 type clay similar to smectite). Changing the content of 2:1 type clay has a strong influence on the behaviour of the whole material, despite its low weight fraction of around 2 per cent. The tests carried out on these reconstituted materials were compared with the results obtained for natural debris flow materials and showed some common trends: in particular, the rheological parameters for materials with and without 2:1 clays with respect to yield stress as a function of solid content. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
466.
A drop calorimetric study, between 900 and 1800 K, of amorphous SiO2, NaAlSi3O8, NaAlSi2O6, NaAlSiO4 and KAlSi3O8 shows the increase in heat capacity which results from glass transitions. For these glasses, the fictive temperature has a negligible effect on the heat capacity above room temperature, but it has an important influence on the enthalpy of formation as obtained from solution calorimetry. From these results and published Cp and enthalpy of solution data, several properties have been calculated: the enthalpies of fusion of high albite, nepheline, Jadeite and high sanidine, the thermodynamic functions of amorphous NaAlSi3O8 and KAlSi3O8 between 0 and 2000 K, and some mixing properties of liquids along the join SiO2-NaAlSi3O8. The latter data suggest that these liquids behave more closely as athermal solutions than as regular solutions.  相似文献   
467.
Marine reserves can create both benefits and costs to fishers. This article explores the perceptions of fishers in Kenya and Seychelles about displacement, spillover, and overall impacts of local marine reserves on their livelihoods. We test whether these perceptions are different among fishers from different geographic and socioeconomic conditions. Sixty-six percent of fishers had been displaced from marine reserves or coastal development and 90% believed they had caught fishes that spilled over from marine reserves. Poorer fishers in Kenya were both displaced from, and also felt like they benefited from, marine reserves. This highlights how people's experiences with marine reserves, both positive and negative, are affected by a range of social considerations that may not be incorporated in typical evaluations of ecological and economic marine reserve success.  相似文献   
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The ability of a large ensemble of regional climate models to accurately simulate heat waves at the regional scale of Europe was evaluated. Within the EURO-CORDEX project, several state-of-the art models, including non-hydrostatic meso-scale models, were run for an extended time period (20 years) at high resolution (12 km), over a large domain allowing for the first time the simultaneous representation of atmospheric phenomena over a large range of spatial scales. Eight models were run in this configuration, and thirteen models were run at a classical resolution of 50 km. The models were driven with the same boundary conditions, the ERA-Interim re-analysis, and except for one simulation, no observations were assimilated in the inner domain. Results, which are compared with daily temperature and precipitation observations (ECA&D and E-OBS data sets) show that, even forced by the same re-analysis, the ensemble exhibits a large spread. A preliminary analysis of the sources of spread, using in particular simulations of the same model with different parameterizations, shows that the simulation of hot temperature is primarily sensitive to the convection and the microphysics schemes, which affect incoming energy and the Bowen ratio. Further, most models exhibit an overestimation of summertime temperature extremes in Mediterranean regions and an underestimation over Scandinavia. Even after bias removal, the simulated heat wave events were found to be too persistent, but a higher resolution reduced this deficiency. The amplitude of events as well as the variability beyond the 90th percentile threshold were found to be too strong in almost all simulations and increasing resolution did not generally improve this deficiency. Resolution increase was also shown to induce large-scale 90th percentile warming or cooling for some models, with beneficial or detrimental effects on the overall biases. Even though full causality cannot be established on the basis of this evaluation work, the drivers of such regional differences were shown to be linked to changes in precipitation due to resolution changes, affecting the energy partitioning. Finally, the inter-annual sequence of hot summers over central/southern Europe was found to be fairly well simulated in most experiments despite an overestimation of the number of hot days and of the variability. The accurate simulation of inter-annual variability for a few models is independent of the model bias. This indicates that internal variability of high summer temperatures should not play a major role in controlling inter-annual variability. Despite some improvements, especially along coastlines, the analyses conducted here did not allow us to generally conclude that a higher resolution is clearly beneficial for a correct representation of heat waves by regional climate models. Even though local-scale feedbacks should be better represented at high resolution, combinations of parameterizations have to be improved or adapted accordingly.  相似文献   
470.
The occurrence and intensity of heatwaves is expected to increase with climate change. Early warnings of hot summers have therefore a great socio-economical value. Previous studies have shown that hot summers are preceded by a Southern European rainfall deficit during winter, and higher spring temperatures. Changes in the surface energy budget are believed to drive this evolution, in particular changes in the latent and sensible heat fluxes. However these have rarely been investigated due to the lack of long-term reliable observation data. In this study, we analyzed several data-derived gridded products of latent and sensible heat fluxes, based on flux tower observations, together with re-analyses and regional climate model simulations over Europe. We find that warm summers are preceded by an increase in latent heat flux in early spring. During warm summers, an increase in available energy results in an excess of both latent and sensible heat fluxes over most of Europe, but a latent heat flux decrease over the Iberian Peninsula. This indicates that, on average, a summertime soil-moisture limited evapotranspiration regime only prevails in the Iberian Peninsula. In general, the models that we analyzed overestimate latent heat and underestimate sensible heat as compared to the flux tower derived data-product. Most models show considerable drying during warm seasons, leading to the establishment of a soil-moisture limited regime across Europe in summer. This over-estimation by the current generation of models of latent heat and hence of soil moisture deficit over Europe in summer has potential consequences for future summertime climate projections and the projected frequency of heat waves. We also show that a northward propagation of drought during warm summers is found in model results, a phenomenon which is also seen in the flux tower data-product. Our results lead to a better understanding of the role of latent and sensible heat flux in summer heatwaves, and provide a framework for benchmark of modeling studies.  相似文献   
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