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371.
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373.
Kostas Glampedakis Lars Samuelsson Nils Andersson 《Astrophysics and Space Science》2007,308(1-4):607-611
The presence of a magnetic field in a neutron star interior results in a dynamical coupling between the fluid core and the
elastic crust. We consider a simple toy-model where this coupling is taken into account and compute the system’s mode oscillations.
Our results suggest that the notion of pure torsional crust modes is not useful for the coupled system, instead all modes
excite Alfvén waves in the core. However, we also show that among a rich spectrum of global MHD modes the ones most likely
to be excited by a fractured crust are those for which the crust and the core oscillate in concert. For our simple model,
the frequencies of these modes are similar to the “pure crustal” frequencies. We advocate the significant implications of
these results for the attempted theoretical interpretation of QPOs during magnetar flares in terms of neutron star oscillations.
相似文献
374.
The time required at a field site to obtain a few measurements of saturated hydraulic conductivity (Ks) will allow for many measurements of soil air permeability (ka). This study investigates if ka measured in situ (ka, in situ) can be a substitute for measurement of Ks in relation to infiltration and surface runoff modelling. Measurements of ka, in situ were carried out in two small agricultural catchments. A spatial correlation of the log‐transformed values existed having a range of approximately 100 m. A predictive relationship between Ks and ka measured on 100‐cm3 soil samples in the laboratory was derived for one of the field slopes and showed good agreement with an earlier suggested predictive Ks–ka relationship. In situ measurements of Ks and ka suggested that the predictive relationships also could be used at larger scale. The Ks–ka relationships together with the ka, in situ data were applied in a distributed surface runoff (DSR) model, simulating a high‐intensity rainfall event. The DSR simulation results were highly dependent on whether the geometric average of ka, in situ or kriged values of ka, in situ was used as model input. When increasing the resolution of Ks in the DSR model, a limit of 30–40 m was found for both field slopes. Below this limit, the simulated runoff and hydrograph peaks were independent of resolution scale. If only a few randomly chosen values of Ks were used to represent the spatial variation within the field slope, very large deviations in repeated DSR simulation results were obtained, both with respect to peak height and hydrograph shape. In contrast, when using many predicted Ks values based on a Ks–ka relationship and measured ka, in situ data, the DSR model generally captured the correct hydrograph shape although simulations were sensitive to the chosen Ks–ka relationship. As massive measurement efforts normally will be required to obtain a satisfactory representation of the spatial variability in Ks, the use of ka, in situ to assess spatial variability in Ks appears a promising alternative. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
375.
Manuela A. Fehr Per S. Andersson Carl-Magnus Mörth 《Geochimica et cosmochimica acta》2008,72(3):807-826
Holocene sediments from the Gotland Deep basin in the Baltic Sea were investigated for their Fe isotopic composition in order to assess the impact of changes in redox conditions and a transition from freshwater to brackish water on the isotope signature of iron. The sediments display variations in δ56Fe (differences in the 56Fe/54Fe ratio relative to the IRMM-14 standard) from −0.27 ± 0.09‰ to +0.21 ± 0.08‰. Samples deposited in a mainly limnic environment with oxygenated bottom water have a mean δ56Fe of +0.08 ± 0.13‰, which is identical to the mean Fe isotopic composition of igneous rocks and oxic marine sediments. In contrast, sediments that formed in brackish water under periodically euxinic conditions display significantly lighter Fe isotope signatures with a mean δ56Fe of −0.14 ± 0.19‰. Negative correlations of the δ56Fe values with the Fe/Al ratio and S content of the samples suggest that the isotopically light Fe in the periodically euxinic samples is associated with reactive Fe enrichments and sulfides. This is supported by analyses of pyrite separates from this unit that have a mean Fe isotopic composition of −1.06 ± 0.20‰ for δ56Fe. The supply of additional Fe with a light Fe isotopic signature can be explained with the shelf to basin Fe shuttle model. According to the Fe shuttle model, oxides and benthic ferrous Fe that is derived from dissimilatory iron reduction from shelves is transported and accumulated in euxinic basins. The data furthermore suggest that the euxinic water has a negative dissolved δ56Fe value of about −1.4‰ to −0.9‰. If negative Fe isotopic signatures are characteristic for euxinic sediment formation, widespread euxinia in the past might have shifted the Fe isotopic composition of dissolved Fe in the ocean towards more positive δ56Fe values. 相似文献
376.
Per S. Andersson Don Porcelli Göran Björk Örjan Gustafsson 《Geochimica et cosmochimica acta》2008,72(12):2854-2867
The neodymium concentration, CNd, and isotopic composition, εNd, in seawater have been determined in the water column at five sites in the Barents Sea-Fram Strait area where most of the water exchange between the Arctic Ocean and the North Atlantic takes place. In the main Arctic Ocean inflow branch across the Barents Sea the concentration and isotopic composition (CNd = 15.5 pmol/kg and εNd = −10.8) are similar to those reported for the northeastern Nordic Seas, which is consistent with this region being a source area for the Arctic inflow. Due to the addition of Nd from Svalbard shelf sediments, the CNd in the surface waters above 150 m, in the Fram Strait inflow branch is higher by a factor of 2 and the εNd is shifted to lower values (−11.8).In the stratified Nansen Basin, where cold low salinity water overlies warmer Atlantic water the CNd and εNd do not vary with the vertical temperature-salinity structure but are essentially constant and similar to those of the Atlantic inflow throughout the entire water column, down to 3700 m depth, which indicates that the Nd is to a large extent of Atlantic origin.Compared to the Atlantic inflow water, the Nd in the major Arctic Ocean outflow, the Fram Strait, show higher CNd in the surface waters above 150 m, and a higher εNd (−9.8) throughout the entire water column down to 1300 m depth. Sources for the more radiogenic Nd isotopic composition in deep water of the Fram Strait outflow most likely involve boundary exchange with sediments on the shelf and slope as the water passes along the Canadian archipelago. River water is a possible source in the surface water but it also seems likely that Pacific water Nd, modified by interactions on the shelf, is an important component in the Fram Strait surface outflow. Changes in the relative proportions of inflow of river water and flow of Pacific water through the Arctic Ocean could thus influence the isotopic composition of Nd in the North Atlantic. 相似文献
377.
378.
Sandra McLaren Malcolm W. Wallace Stephen J. Gallagher John A. Miranda Guy R. Holdgate Laura J. Gow Ian Snowball Per Sandgren 《Quaternary Science Reviews》2011,30(9-10):1086-1111
The Murray Basin is a low-lying but extensive intracratonic depocentre in southeastern Australia, preserving an extraordinary record of Late Neogene sedimentation. New stratigraphic and sedimentologic data allow the long-term evolution of the basin to be re-evaluated and suggest a significant role for: (1) tectonism in controlling basin evolution, and (2) progressive and step-wise climatic change beginning in the early Pleistocene. Tectonic change is associated with regional uplift, occurring at approximately the same rate from the early Pliocene until the present day, and possibly associated with changing mantle circulation patterns or plate boundary processes. This uplift led to the defeat and re-routing of the Murray River, Australia’s major continental drainage system. Key to our interpretation is recognition of timing relationships between four prominent palaeogeographic features – the Loxton-Parilla Sands strandplain, the Gambier coastal plain, palaeo megalake Bungunnia and the Kanawinka Escarpment. Geomorphic and stratigraphic evidence suggest that during the Early Pliocene the ancestral Murray River was located in western Victoria, flowing south along the Douglas Depression. Relatively small amounts of regional uplift (<200 m) defeated this drainage system, dramatically changing the palaeogeography of southeastern Australia and forming Plio-Pleistocene megalake Bungunnia. At its maximum extent Lake Bungunnia covered more than 50,000 km2, making it one of the largest known palaeo- or modern-lakes in an intracontinental setting. Magnetostratigraphic constraints suggest lake formation c. 2.4 Ma. The formation of Lake Bungunnia influenced the Pliocene coastal dynamics, depriving the coastline of a sediment source and changing the coastal system from a prograding strandline system to an erosional one. Erosion during this period formed the Kanawinka Escarpment, a palaeo sea-cliff and one of the most prominent and laterally extensive geomorphic features in southeastern Australia. Marine sediments c. 800 ka to c. 1.16 Ma represent the time of re-establishment of depositional coastal dynamics and of a permanent outlet for the Murray River. This age range is consistent with our best estimate of the age of the youngest Lake Bungunnia sediments and points towards an early Pleistocene age for the demise of the lake system. The youngest Lake Bungunnia sediment, present on a number of distinct terraces, suggests that progressive, step-wise climatic change played a role in the demise of the lake. However, in order for the ancestral Murray River system to have been able to breach the pre-existing tectonic dam, it is likely that tectonic change and/or temporarily enhanced discharge was also significant. This scenario indicates that the modern Murray River has only been in existence for at most 700 ka. 相似文献
379.
380.
Coordination chemistry and hydrolysis of Fe(III) in a peat humic acid studied by X-ray absorption spectroscopy 总被引:2,自引:0,他引:2
The speciation of iron (Fe) in soils, sediments and surface waters is highly dependent on chemical interactions with natural organic matter (NOM). However, the molecular structure and hydrolysis of the Fe species formed in association with NOM is still poorly described. In this study extended X-ray absorption fine structure (EXAFS) spectroscopy was used to determine the coordination chemistry and hydrolysis of Fe(III) in solution of a peat humic acid (5010-49,200 μg Fe g−1 dry weight, pH 3.0-7.2). Data were analyzed by both conventional EXAFS data fitting and by wavelet transforms in order to facilitate the identification of the nature of backscattering atoms. Our results show that Fe occurs predominantly in the oxidized form as ferric ions and that the speciation varies with pH and Fe concentration. At low Fe concentrations (5010-9920 μg g−1; pH 3.0-7.2) mononuclear Fe(III)-NOM complexes completely dominates the speciation. The determined bond distances for the Fe(III)-NOM complexes are similar to distances obtained for Fe(III) complexed by desferrioxamine B and oxalate indicating the formation of a five-membered chelate ring structure. At higher Fe concentrations (49,200 μg g−1; pH 4.2-6.9) we detect a mixture of mononuclear Fe(III)-NOM complexes and polymeric Fe(III) (hydr)oxides with an increasing amount of Fe(III) (hydr)oxides at higher pH. However, even at pH 6.9 and a Fe concentration of 49,200 μg g−1 our data indicates that a substantial amount of the total Fe (>50%) is in the form of organic complexes. Thus, in environments with significant amounts of organic matter organic Fe complexes will be of great importance for the geochemistry of Fe. Furthermore, the formation of five-membered chelate ring structures is in line with the strong complexation and limited hydrolytic polymerization of Fe(III) in our samples and also agrees with EXAFS derived structures of Fe(III) in organic soils. 相似文献