The behaviour of a Cu(II) ion selective electrode in seawater; copper consumption capacity and copper determinations     

D. A. Romn  L. Rivera 《Marine Chemistry》1992,38(3-4)

Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater.  相似文献   

Multipole expansions for wave diffraction and radiation in deep water   总被引：1，自引：0，他引：1  

R. Eatock Taylor  C. S. Hu 《Ocean Engineering》1991,18(3)

A multipole expansion of the velocity potential is described for two- and three-dimensional wave diffraction and radiation problems. The velocity potential is expressed in terms of a series of multipole potentials. The wave terms and the local disturbance terms are represented by separated multipole potentials. Floating bodies and submerged bodies are treated in the same way. This approach differs from that of some other authors, who considered floating bodies and submerged bodies separately and derived entirely different multipoles. Semi-analytical solutions for a circular cylinder in two-dimensional motions are given. It is found that the local disturbance decays rapidly and steadily. The general application of the multipole expansion to arbitrary geometries is also presented, based on a method coupling multipoles to a boundary integral expression. Numerical results for several floating and submerged cylinders are presented.  相似文献   

Estimates of the characteristics of the horizontal turbulent exchange in the northwestern part of the Pacific Ocean     

M. S. Permyakov  T. I. Tarkhova  A. S. Sergienko 《Oceanology》2007,47(5):647-652

Estimates of the characteristics of the horizontal turbulent exchange (coefficients of horizontal exchange, scales of deviations of the velocity of geostrophic currents from the background flows, and horizontal scales of perturbations) in the upper ocean layer were obtained on the basis of the data of expeditions held in 1978 and 1980 in the northwestern part of the Pacific Ocean. It is shown that the characteristics of the horizontal turbulent exchange strongly depend on the structure of the background flows, and one of the causes of their variability is related to tropical cyclones. A tendency to a decrease (to different degrees) of the turbulent coefficients in the wake of a tropical cyclone is noted.  相似文献   

Study of the mutual influence of the El Niño-Southern Oscillation processes and the North Atlantic and Arctic Oscillations     

I. I. Mokhov  D. A. Smirnov 《Izvestiya Atmospheric and Oceanic Physics》2006,42(5):598-614

On the basis of the nonlinear techniques for the estimation of coupling between oscillatory systems from time series, we investigate the dynamics of climatic modes characterizing global and Northern Hemisphere (NH) processes. The North Atlantic Oscillation (NAO) and Arctic Oscillation indices and the El Niño-Southern Oscillation (ENSO) indices are analyzed in terms of the most reliable data from 1950 through 2004 and earlier data since the 19th century. These indices characterize changes in NH atmospheric pressure (specifically, sea-level pressure in the North Atlantic and NH extratropical latitudes as a whole) and in equatorial Pacific sea-surface temperature and sea-level pressure to which the strongest variations of global surface temperature and global climate on interannual time scales and of regional climatic anomalies in the NH are linked. The methods used are based on phase-dynamics modeling and nonlinear prediction models (a nonlinear version of Granger causality). From both methods and various ENSO indices, the inference about the ENSO effect on the NAO during the latter half of the 20th century and in the early 21st century is made with confidence probability of at least 0.95. The influence is characterized by a time delay of about two years. No inverse influence is found with a similar degree of reliability. Results of estimating the coupling between the ENSO and the NAO depend on the type of index that is used to describe the NAO. The ENSO effect on the NAO is detected with sufficient confidence when the NAO index is chosen to be a larger scale characteristic. However, when a more local index of the NAO is used, no statistically significant coupling to the ENSO is found. Increasing the length of the analyzed ENSO and NAO series (over more than 100 yr) does not lead to any more reliable detection of coupling. Analysis of the data for different time intervals during 1950–2004 has revealed a strengthening of the ENSO effect on the NAO, although this inference is not reliable.  相似文献   

An evaluation of multi-annual management strategies for ICES roundfish stocks     

Kell  L.T.; Pilling  G.M.; Kirkwood  G.P.; Pastoors  M.A.; Mesnil  B.; Korsbrekke  K.; Abaunza  P.; Aps  R.; Biseau  A.; Kunzlik  P.; Needle  C.L.; Roel  B.A.; Ulrich  C. 《ICES Journal of Marine Science》2006,63(1):12-24

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A community-wide intercomparison exercise for the determination of dissolved iron in seawater     

Andrew R. Bowie  Eric P. Achterberg  Peter L. Croot  Hein J.W. de Baar  Patrick Laan  James W. Moffett  Simon Ussher  Paul J. Worsfold 《Marine Chemistry》2006

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.  相似文献   

Dynamic evolution of the 1997–1999 El Niño–La Niña cycle in the southern California Current System     

R. J. Lynn  S. J. Bograd   《Progress in Oceanography》2002,54(1-4)

The development of the strongest El Niño event on record in the equatorial Pacific in 1997–1998 and the rapid transition to strong La Niña conditions in 1998–1999 had a large impact on the physical and biological environment of the West Coast. We investigate the evolution of the physical structure and circulation dynamics of the southern California Current System (CCS) during this period based on hydrographic data collected on 25 cruises over a 45-month period (February 1996–October 1999). The El Niño period was characterized by a significant increase in dynamic height, extreme water mass characteristics, a strengthening and broadening of the poleward nearshore flow, and a temporary reversal of net alongshore transport. By early 1999, conditions in the CCS had reversed. The data suggest that remotely driven forcing (propagating oceanic waves) contributed to the anomalies observed during the El Niño period, while the cool-water conditions of 1999 were most likely a result of anomalous local atmospheric forcing.  相似文献   

Nutrient variability during El Niño 1997–98 in the California current system off central California     

C. G. Castro  C. A. Collins  P. Walz  J. T. Pennington  R. P. Michisaki  G. Friederich  F. P. Chavez   《Progress in Oceanography》2002,54(1-4)

Nutrient conditions off central California during the 1997–98 El Niño are described. Data were collected on 11 cruises from March 1997 to January 1999 along a hydrographic section off central California, as well as every two weeks at a coastal station in Monterey Bay. Perturbations associated with El Niño are shown as anomalies of thermohaline and nutrient distributions along this section. The anomalies were obtained by subtracting seasonal averages for the period from April 1988 to April 1991 from the 1997–98 observations. The first indications of El Niño conditions (high sea levels) were observed at Monterey between late May and early June 1997, but the coastal nutricline did not begin to deepen until August 1997. It reached maximum depth of 130 dbar in January 1998 at the time that maximum sea level anomalies were observed. During this period: (1) the highest subsurface temperature anomalies coincided with subsurface nutrient anomaly minima at the depth of the pycnocline; (2) southern saline and nutrient-poor waters occupied the upper 80 dbar of the water column along the entire section; and (3) nitrate levels were close to zero in the euphotic zone, collapsing the potential new primary production in the coastal domain. At the end of February 1998, the nutricline shoaled to 40 dbar at the coast although it remained anomalously deep offshore. Higher temperatures and lower nutrient levels were observed for the entire section through August 1998 although in contrast with the previous winter, there was a strong freshening mainly due to an onshore movement of subarctic waters.  相似文献   

Targeted environmental monitoring for the effects of medicines used to treat sea-lice infestation on farmed fish   总被引：1，自引：0，他引：1  

Davies  I. M.; Rodger  G. K.; Redshaw  J.; Stagg  R. M. 《ICES Journal of Marine Science》2001,58(2):477-485

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Modelling the size selectivities of a trawl codend and an associated square mesh panel   总被引：8，自引：1，他引：8  

Zuur  G.; Fryer  R. J.; Ferro  R. S. T.; Tokai  T. 《ICES Journal of Marine Science》2001,58(3):657-671

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