Spatiotemporal changes in cadmium contamination in the Seine estuary (France)     

Jean-François Chiffoleau  Dominique Auger  Emmanuelle Chartier  Pierre Michel  Isabelle Truquet  André Ficht  Jean-Louis Gonzalez  Louis-Alexandre Romana 《Estuaries and Coasts》2001,24(6):1029-1040

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.  相似文献   

Surfactant Solutions Developed for NAPL Recovery in Contaminated Aquifers   总被引：2，自引：0，他引：2  

Richard Martel  Pierre J. Gélinas 《Ground water》1996,34(1):143-154

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Residual Diesel Measurement in Sand Columns After Surfactant/Alcohol Washing     

Richard Martel  Pierre J. Gélinas 《Ground water》1996,34(1):162-167

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The 1883 event     

Pierre Thierry  Laurent Stieltjes  Emmanuel Kouokam  Pierre Nguéya  Paul M. Salley 《GeoJournal》1992,28(2):86-86

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Petrology of the Great Abitibi Dyke, Superior Province, Canada     

ERNST  RICHARD E.; BELL  KEITH 《Journal of Petrology》1992,33(2):423-469

The Great Abitibi Dyke (GAD) which can be traced northeast,for >> 700 km, across the Abitibi Belt in the southeasternSuperior Province of the Canadian Shield, is composed of olivinegabbro to monzodiorite, weakly saturated to undersaturated insilica. All rocks of the GAD can be derived by mainly plagioclase andolivine fractionation from a parental magma corresponding incomposition to chilled margin samples. Two units can be distinguished,a marginal unit (Unit 1) representing 0–50% crystallizationand a central unit (Unit 2), found over about half of the dykelength, representing 50–70% crystallization. Modelling,using Pearce elemental ratio analysis, quantifies the fractionationhistory and allows mass–balance calculations over thepresent exposure level of the dyke. The approximate balancebetween the amounts of cumulate and fractionated rocks suggeststhat Unit 1 differentiated essentially in situ as a closed system.In contrast, Unit 2 rocks were formed by loss of substantialplagioclase and olivine from the parental magma. This fractionatemust have either been lost to depth or left behind in an externalchamber. Unit 2 rocks show depletion in plagioclase and enrichmentin mafic minerals along strike towards the southwest (deeperexposure level?), a trend explained by density stratification.Regional variation in Unit 1 chemistry is interpreted in termsof lateral magma injection towards the northeast from the locusof Keweenawan rift volcanism. Feldspar, olivine, and augitecompositions are linearly correlated with equilibrium temperatureand extent of magma evolution. The parent magma had a trace element chemistry correspondingto a ‘within–plate’ setting and was probablyderived from an incompatible–element enriched mantle similarto the source for ocean island basalts (OIBs).  相似文献   

Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction   总被引：10，自引：0，他引：10  

Pascal Philippot  Pierre Chevallier  Christian Chopin  Jean Dubessy 《Contributions to Mineralogy and Petrology》1995,121(1):29-44

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.  相似文献   

Phase Diagrams to Optimize Surfactant Solutions for Oil and DNAPL Recovery in Aquifers   总被引：2，自引：0，他引：2  

Richard Martel  Pierre J. Gelinas  Jacques E. Desnoyers  Anne Masson 《Ground water》1993,31(5):789-800

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Bay of Biscay and Pyrenees     

Pierre Choukroune  Xavier Le Pichon  Michel Seguret  Jean-Claude Sibuet 《Earth and Planetary Science Letters》1973,18(1):109-118

The different hypotheses proposed for the creation of the Bay of Biscay are reviewed. New geological and geophysical data collected in the last two years in the Bay and in the Pyrenean domain give new insight into the tectogenesis of the Pyrenees. Geological data of the Pyrenean area provide tight constraints on the hypothesis of formation of the Bay. The most probable hypothesis is an opening by rotation of the Iberian Peninsula around a pole of rotation situated near Paris, which resulted in strike-slip motion along the North Pyrenean fault during the Upper Mesozoic. A progressive westward migration of the pole initiated in the late Cretaceous blocked the motion along the fault and led to the main Eocene tectogenetic Pyrenean phase.  相似文献   

Polarization of a periodic solar microwave burst     

Pierre Kaufmann 《Solar physics》1976,50(1):197-199

No fluctuations in polarization have been found during a 7 GHz solar burst showing 17 s periodic pulses in intensity. Polarization effects can be produced by the propagation media in the active centre, which are not affected directly by the burst source, but situated more deeply than the observed heights at that microwave frequency.  相似文献   

Direct simulation of solute recycling in irrigated areas     

Ellen Milnes  Pierre Perrochet 《Advances in water resources》2006

Solute recycling from irrigation can be described as the process that occurs when the salt load that is extracted from irrigation wells and distributed on the fields is returned to the groundwater below irrigated surfaces by deep percolation. Unless the salt load leaves the system by means of drains or surface runoff, transfer to the groundwater will take place, sooner or later. This can lead to solute accumulation and thus to groundwater degradation, particularly in areas where extraction rates exceed infiltration rates (semi-arid and arid regions). Thus, considerable errors can occur in a predictive solute mass budget if the recycling process is not accounted for in the calculation. A method is proposed which allows direct simulation of solute recycling. The transient solute response at an extraction well is shown to be a superposition of solute mass flux contributions from n recycling cycles and is described as a function of the travel time distribution between a recycling point and a well. This leads to an expression for a transient ‘recycling source’ term in the advection–dispersion equation, which generates the effect of solute recycling. At long times, the ‘recycling source’ is a function of the local capture probability of the irrigation well and the solute mass flux captured by the well from the boundaries. The predicted concentration distribution at steady state reflects the maximum spatial concentration distribution in response to solute recycling and can thus be considered as the solute recycling potential or vulnerability of the entire domain for a given hydraulic setting and exploitation scheme. Simulation of the solute recycling potential is computationally undemanding and can therefore, for instance, be used for optimisation purposes. Also, the proposed method allows transient simulation of solute recycling with any standard flow and transport code.  相似文献