Titan-aegirine from early Tertiary ash layers in northern Denmark     

J.G Rønsbo  A.K Pedersen  J Engell 《Lithos》1977,10(3):193-204

Microprobe analyses on a xenocrystic suite of salites, aegirine-augites, aegirines, titan-aegirines and acmites from a lower Tertiary ash layer in northern Denmark are presented. The sodic pyroxenes show an unusual titan-enrichment and up to 42 mol.% of the component $\text{NaTi}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{4+}}\text{M}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{2+}}\text{Si}{}_3\text{O}{}_6\text{(}\text{M = Fe}{}^{\mathrm{2+}}\text{,}\text{Mn or Mg}\text{)}$, is estimated. Optical absorption measurements show no evidence for Ti³⁺. The titan-aegirines were formed during late to post-magmatic crystallization in a system with a high Ti⁴⁺/Fe²⁺ ratio and were followed by acmite showing enrichment in jadeite. Comparison with experimentally investigated titan-aegirine indicates crystallization far below the Mn₂O₃Mn₃O₄f₀₂ buffer.  相似文献   

A shale buchite xenolith with Al-armalcolite and native iron in a lava from Asuk,Disko, central West Greenland     

Asger Ken Pedersen 《Contributions to Mineralogy and Petrology》1979,69(1):83-94

A native iron bearing buchite xenolith enclosed in basalt in a native iron bearing lava from Disko is similar in chemistry, apart from volatile components, to unheated Mesozoic to early Tertiary carbonaceous shale sediments from West Greenland, believed to have been the major contaminant and reducing agent causing the formation of the native iron in the volcanic rocks on Disko. The shale buchite has preserved original sedimentary lamination and experienced only a comparatively short-lived heating which allowed only short-range equilibration. The xenolith contains native iron and graphite, while the immediately enclosing basalt does not, and demonstrates the indigenous reducing properties of the shales when heated to high (1,150–1,200 ° C) temperatures at low pressures. Sedimentary clastic iron titanium oxide grains have reacted with the immediately surrounding matrix and completely recrystallized to aggregates of rutile and Al-armalcolite with up to 24 mol% Al₂TiO₅. The Al-armalcolites contain 5 to 11 mol% of the anosovite (Ti₃O₅) component. They show a considerable variation in iron-magnesium ratio due to small-scale variations in bulk chemistry to varying f _O2 and to the effects of progressive melting of the sediment. Glassy veins in the buchite, formed along original fractures in the sediment, contain an assemblage of cordierite, low Ca-pyroxene, plagioclase, ilmenite, ferropseudobrookite-rich armalcolite, iron metal, troilite and acid glass, and crystallized under higher oxygen fugacities than the buchite interior, probably due to influx from the less reduced enclosing basalt magma.  相似文献   

The Lyngen Gabbro: the lower crust of an Ordovician Incipient Arc     

Astri?J.?S.?KvassnesEmail author  Anita?Hetland?Strand  Heidi?Moen-Eikeland  Rolf?Birger?Pedersen 《Contributions to Mineralogy and Petrology》2004,148(3):358-379

We present evidence for the origin of the Lyngen Gabbro of the Ordovician Lyngen Magmatic Complex in Troms, Northern Norway. The two magmatic suites of the Lyngen Gabbro strike parallel NNE-SSW, and have distinct magmatic signatures. We define these signatures by using major and trace-element analyses together with selected major- and trace-element mineral analyses and ¹⁴³Nd/¹⁴⁴Nd-isotope whole-rock analyses of gabbroic to tonalitic plutonic rocks from seven detailed cross-sections from this large gabbro-complex. The Western suite of the Lyngen Gabbro precipitated from magma that may have been derived from the same system as the associated volcanic rocks. The gabbros have high An-content (An_>90) of their plagioclases relative to co-existing mafic minerals. Together with somewhat high _Nd(t) values (+6), this implies that the parental magmas were hydrous tholeiites similar to those found in back arc basins today. The Eastern suite, on the other hand, consist of cumulates that were precipitated from melts resembling those of ultra-depleted high-Ca boninitic magmas found in fore-arcs. Extremely high-An plagioclases (An_>95) co-exist with evolved mafic minerals and oxides, and the _Nd(t) values are lower (+4) than in the Western suite. The Eastern suite has no volcanic counterpart, but dikes intersecting the suites have compositions that possibly represent its parental magma. The oceanic Rypdalen Shear Zone generally separates the two suites in the north, but several non-tectonic transitions from boninitic to tholeiitic signatures southwards advocate that the magmatism happened concurrently. The magmatic proximity between the suites, the hydrous magmatism and the absence of a silicic or calc-alkaline mature arc section, suggests that the Lyngen Gabbro formed in the Iapetus Ocean under conditions presently found in incipient arcs later emplaced as outer arc highs.  相似文献   

Acidic compounds in biodegraded petroleum     

Tanja Barth  Sylvi Hiland  Per Fotland  Kjell Magne Askvik  Bent Skaare Pedersen  Anna Elisabet Borgund 《Organic Geochemistry》2004,35(11-12):1513

Twelve oil samples have been characterised by titration, FT-IR and chromatographic analysis to determine the differences between the organic acid composition of biodegraded and non-biodegraded oils. The biodegraded oils have higher total acid and total base contents, both by titration and extraction. The molecular weight ranges of the extracted acids are lowest in the biodegraded oils, and the equivalent weight calculations indicate a dominance of multi-functional molecules. Gel permeation chromatography gives a molecular weight range with most of the molecules between 300 and 500 g/mol. FT-IR shows that the extracted acids from biodegraded oils are more carboxylic and aliphatic while the non-degraded oils are more phenolic. Molecular analysis of the derivatised extracts give UCM envelopes for biodegraded oils, and no molecular identification. The results indicate that the acidic constituents in biodegraded oils are a product of the biodegradation, as the composition is very different from the non-biodegraded oils.  相似文献   

Lithospheric structure of the Tornquist Zone resolved by nonlinear P and S teleseismic tomography along the TOR array   总被引：1，自引：1，他引：1  

Z. Hossein Shomali  Roland G. Roberts  Laust B. Pedersen  the TOR Working Group 《Tectonophysics》2006,416(1-4):133

The main aim of the TOR project is to study the lithospheric–asthenospheric boundary structure under the Sorgenfrei–Tornquist Zone, across northern Germany, Denmark and southern Sweden. Relative arrival-time residuals of teleseismic P and S phases from 51 earthquakes, recorded by 150 seismic stations along the TOR array, were used to delineate the transition zone in the studied area. The effects of crustal structures were investigated by correcting the teleseismic residuals for travel-time variations in the crust based on a 3D crustal model derived from other data. The inversion was carried out for S phases. The results were then compared with the corresponding P-wave models. As expected, the derived models show that the relatively old and cold Baltic Shield has higher velocity at depth than the younger lithosphere farther South. The models show two sharp and distinct increases in depth to velocities which are low compared to our reference model, as we move from South to North. The location and sharpness of these boundaries suggests that the features resolved are, at least partially, compositional in origin, presumably related to mantle depletion. A sharp and steep subcrustal boundary is found roughly coincident with the southern edge of Sweden. This is below where the edge of the Baltic Shield is usually placed, based on surface geological evidence (the Sorgenfrei–Tornquist Zone). Another less significant transition is recognised more or less beneath the Elbe-lineament. Relatively high d(V_p / V_s) ratios under the central part of the profile (Denmark) indicate relatively low S-velocity in an area where a gravity high supports the hypothesis of extensive mafic intrusions.  相似文献   

Temporal development of the 1999 intrusive episode in the Eyjafjallajökull volcano, Iceland, derived from InSAR images     

Rikke Pedersen  Freysteinn Sigmundsson 《Bulletin of Volcanology》2006,68(4):377-393

Eyjafjallajökull volcano, located in southern Iceland, is characterized by its quiet nature. Only about a handful of earthquakes associated with the volcanic system had been detected prior to the 1990s. Earthquake swarms did, however, occur in 1994 and 1999. Here we investigate the spatio-temporal evolution of a magmatic intrusion associated with the 1999 earthquake swarm via analysis of produced surface deformation. A series of interferometric synthetic aperture radar (InSAR) images, spanning various periods of the intrusion, show that in 1999 surface deformation occurred mainly on the southern flanks of the volcano. The deformation amounts to more than 20 cm of range change. Inverse modeling resolves the deformation source to be a sill intrusion at 6.3 km depth. Sill opening was up to 1 m and the total intruded volume amounts to ～0.03 km³. The InSAR data display a migration of the center of deformation through time, enabling us to create time-dependant sill-opening models. Furthermore, we investigate the spatio-temporal distribution of earthquakes and find that the distribution supports the InSAR derived model and additionally provides indications for a possible site of a feeder channel. Magmatic flow-rate estimates indicate an initial intrusion rate of 4–6 m³/s, declining over a few weeks.  相似文献   

震后地形变与孔隙压力瞬态变化的相互关系   总被引：1，自引：0，他引：1  

Paul Segall  Rikke Pedersen  曹玲玲  孙小龙 《国际地震动态》2006,(7):102-106

大震改变地壳的应力,从而触发地震及其余震。一系列随时间变化的过程,包括余滑、孔隙流体的流动、下地壳和上地幔粘性的张驰、断层附近应力和孔隙压力调整以及地震的触发进程。然而,尽管进行过多次尝试,但通过直接场地的观测,很难将这些过程区分开来。这里我们采用一种星载雷达干涉图和冰岛南部地震带两个6.5级地震地热井水位变化过程结合的测量法。干涉图记录到的形变既不能用余滑也不能用粘-弹性张驰来解释,但它与地震发生后最初两个月孔隙弹性物质的回跳一致,这可以用地震引起水位变化的快速恢复(1—2个月)来证实,相反余震序列的持续时间达到3.5年,这表明余震的持续时间并不是由孔隙流体的流动控制的,但是,因为表面应变是由地壳浅部孔隙压力的变化控制的,因此,我们不能排除在余震发生深度存在较长时间的孔隙压力瞬态变化。余震的持续时间与随速度和状态变化的摩擦定律控制的地震活动变化速率模型是一致的。  相似文献   

Helium isotope composition of the early Iceland mantle plume inferred from the Tertiary picrites of West Greenland     

D.W. Graham  L.M. Larsen  B.B. Hanan  M. Storey  A.K. Pedersen  J.E. Lupton 《Earth and Planetary Science Letters》1998,160(3-4):241-255

Picrites from the 61 million year old Vaigat Formation of the Nuussuaq Peninsula in West Greenland have ³He/⁴He ratios trapped in olivine phenocrysts which range up to 30 times the atmospheric ratio. These high values, measured during gas extraction by crushing in vacuum, are similar to the highest magmatic ³He/⁴He ratios found in young terrestrial volcanic rocks. By analogy with young basalts, in which crushing selectively extracts magmatic helium, any significant cosmogenic ³He appears to be absent in these picrites. Additional evidence for the absence of cosmogenic helium is provided by fusion results on the crushed olivine powders and by a single stepwise crushing experiment, in which only magmatic and radiogenic helium components are resolvable. The West Greenland picrites have Pb, Nd and Sr isotope compositions which overlap those found in picrites from Iceland and in basalts from Loihi Seamount, localities which today also have high ³He/⁴He ratios. Isotopic variations in He, Pb, Nd and Sr for the West Greenland picrites are interpreted to largely result from interaction of the early Iceland mantle plume with the upper mantle during plume ascent and dispersion beneath the continental lithosphere. The presence of high ³He/⁴He ratios in West Greenland, and the onset of magmatism across the North Atlantic Volcanic Province near 62 Ma, supports the hypothesis for very rapid dispersion (>1 m/year) of mantle plume head material during the earliest stages of plume impact, as predicted in recent numerical simulations of plume behavior during thermal mantle convection with non-Newtonian rheology.  相似文献   

Reconstructing the Palaeoclimate of Jæren, Southwestern Norway, for the Period 1821–1850, from Historical Documentary Records     

Elisabeth Kastellet  Atle Nesje  & Einar Solheim Pedersen 《Geografiska Annaler: Series A, Physical Geography》1998,80(1):51-65

Documentary data provide long time series and sometimes high-resolution, detailed data from historical times to the present and can give valuable information about palaeoclimate, and for the prediction of future climates. In this paper, documentary data containing qualitative information on climate, in the form of a diary written by the farmer I.G. Grude, and two newspapers, were used for the reconstruction of the palaeoclimate at Jæren, in the county of Rogaland, in southwestern Norway, during the period 1821–50. An index method to quantify the qualitative climate data was developed and used for a low-resolution reconstruction of winter, summer and annual temperatures. A high-resolution climate reconstruction of temperature and precipitation for the winter of 1837/38 is also presented, making use of a method that keeps the climate data in a qualitative form. The climate reconstructions are compared to an instrumental temperature series from Bergen, for the same period. The two data sets are in good agreement except for summer temperature (annual temperature: r = 0.75, winter temperature: r = 0.77, summer temperature: r = 0.44). Compared to average temperatures during 1961–90, the instrumental data from Bergen during the 1821–50 period show slightly different temperatures: annual average was 0.3°C lower, winter 0.4°C lower, and summer 0.1°C lower than at present, implying conditions consistent with the "Little Ice Age" climate.  相似文献   

Delayed fractionation of basaltic lavas     

Sven Maaløe  Rolf B. Pedersen  D. James 《Contributions to Mineralogy and Petrology》1988,98(4):401-407

The phenocryst cores of the basaltic lavas from Jan Mayen and Hawaii display a range in compositions. The textural features of the phenocrysts also vary, both euhedral and skeletal phenocrysts are present in the same thin section. Apparently the basaltic magmas underwent crystallization within a temperature interval of 50–200° C before they became fractionated. The fractionates of basaltic lavas are therefore average compositions of the phenocryst assemblages rather than liquidus compositions. This type of fractionation is called delayed fractionation. It is considered that most tholeiitic and alkalic basaltic lavas undergo delayed fractionation.  相似文献