高效液相色谱-紫外光谱分析氢醌-双(β-羟乙基)醚     

盛东  王美飞  练鸿振 《岩矿测试》2009,28(5):407-410

建立了高效液相色谱-紫外光谱法测定聚氨酯扩链剂氢醌-双(β-羟乙基)醚(HQEE)工业品中HQEE主含量和对苯二酚残留的方法。在氰基柱上,以甲醇-水-1%乙酸溶液(体积比10∶50∶40)为流动相,流速1.0 mL/min时,HQEE、对苯二酚及其他相关杂质得到良好分离,紫外光谱285 nm检测。方法简便、快捷,结果准确可靠,在工业生产中可有效地指导HQEE合成过程的质量控制。  相似文献   

电感耦合等离子体质谱法测定岩石样品中的锆铌铪钽两种预处理方法的比较   总被引：9，自引：8，他引：1  

时晓露  刘洪青  孙月婷  章勇  刘文长 《岩矿测试》2009,28(5):427-430

研究了微波消解酸溶和过氧化钠碱熔两种测定岩石样品中锆、铌、铪、钽前处理方法,利用电感耦合等离子体质谱法进行测定。对所选用不同种类的岩石国家标准物质样品进行了条件实验,结果表明:采用过氧化钠碱熔法处理岩石样品后,锆、铌、铪、钽的测量值准确度高,且相对标准偏差(RSD,n=10)小于6%,该方法更适用于岩石样品中锆、铌、铪、钽的测定。  相似文献   

煤炭资源勘探技术框架重构     

冯宏 《地质与勘探》2009,45(6):756-760

在我国第一能源-煤炭资源持续紧缺的形势下,50%的深部资源开发正面临许多新的地质勘探问题.矿井物探技术进步有力的推动着资源开发勘探方法的改变,在井下巷道中对下纽资源的纵深向勘探和水平向勘探技术的成熟,促使技术框架重构.在一井一面高强度开采的煤矿生产组织新模式下,采空区下深部资源勘探、安全地质条件评价和治理、基于"3S"的递推地质管理技术等是老矿区深部资源勘探急需的支撑技术,矿井与地面结合必然是煤炭资源勘探技术发展的方向.  相似文献   

江苏省东海县片麻状碱性花岗岩的成因及年代学研究   总被引：1，自引：0，他引：1       下载免费PDF全文

夏斌  李建峰  张玉泉  刘立文  何观生  王洪  王敏  杨之青 《地质科学》2009,44(1):213-230

江苏省东海地区位于苏鲁造山带的西南缘,区内广泛出露片麻状碱性花岗岩.本文对东海地区磨山、虎山和房山片麻状碱性花岗岩的产状、岩石结构构造、碱性铁镁矿物、元素地球化学和锆石成因及SHRIMP定年等综合研究结果表明：该类岩石具有高硅、富碱、富铁贫镁和含碱性铁镁矿物等特征,说明其为碱性花岗岩;岩体还保留有沉积岩特有的层理（走向北东、倾向南东等一致的产状）,长石等造岩矿物显示在固相条件下结晶的特征,以及继承锫石大部分是不同时代的岩浆或变质锆石碎屑等,均证实其原岩是沉积岩.SHRIMP定年对变质锆石的边部获得两组₂₀₆Pb-₂₃₈U加权平均年龄,分别为224.7±9.4 Ma和209.4±2.5～212±3.5Ma,反映了东海片麻状碱性花岗岩成岩时间属于印支期,相当于晚三叠世,变质锆石的核部₂₀₆Pb-₂₃₈U年龄变化于866～248 Ma,反映原岩时代不会早于晚古生代.  相似文献   

遥感反演和站点观测的地气温度分布特征差异     

王念  卢致宇  徐建红  张红  张霄羽 《遥感学报》2021,25(8):1848-1861

地表温度和近地表大气温度是地球系统、大气系统以及地—气相互作用物理过程的重要参量。在陆地—大气的相互作用过程中,水汽含量、NDVI指数、下垫面变化等因素会对地—气热量传输造成一定的影响。本文首先利用地表温度产品（MYD11A1）以及气温站点数据（GSOD）获得全国尺度下地表温度年最大值、近地面气温年最大值。在此基础上,使用趋势分析法分析2003年—2018年地、气温度年最大值时空分布特征及变化趋势,以及地—气温差气候倾向率变化趋势。最后,结合大气总水汽含量产品（MYD05）、NDVI指数（MYD13A3）、二氧化碳平均浓度增长率分析导致地表温度年最大值与近地面气温年最大值趋势发生变化的原因。研究结果表明：（1）在全国尺度下,2003年—2018年地表温度年最大值呈现北高南低的空间分布特征。近地面气温年最大值的空间分布与地表温度年最大值相反。大气总水汽含量年最大值在热带、亚热带季风气候区内总体较高。水汽含量既影响近地面气温的大小,同时也受到近地面气温的影响,因此,水汽含量年最大值与近地面气温年最大值表现出一定的空间分布一致性特征。（2）在2003年—2018年期间,地表温度年最大值的气候倾向率在空间上表现出北高南低的分布特征。近地面气温年最大值的气候倾向率在空间上也表现为北高南低,与地表温度年最大值的气候倾向率变化基本一致。但地表温度年最大值的变化幅度要大于近地面气温年最大值,并且在个别区域表现不一致。主要分布在天山地区、三江平原以及秦岭南侧地区,地—气年最大值变化趋势相反即地—气差减小。（3）大气总水汽含量年最大值的增加可造成近地面气温年最大值的增加,而植被覆盖度的上升可造成地表温度年最大值下降。但在天山地区大气总水汽含量与地—气差的响应不明显,但天山地区的近地面气温年最大值与CO₂平均浓度增长率的关系较为明显。（4）遥感数据反演的地表温度年最大值和站点观测的近地面气温年最大值空间分布表现出差异,但时间变化趋势基本一致。  相似文献   

面向对象的高分遥感影像信息提取技术研究   总被引：1，自引：0，他引：1  

常虹  詹福雷  杨国东  牛雪峰  张旭请  邵鹏  唐天琦 《测绘通报》2015,(1):99-101,130

以World View-2高分遥感影像数据为例,采用规则集开发的模式进行地图要素提取,对主要制图要素图像进行了分割、分类试验,实现了多尺度分割的层次构建和制图地物要素分级分类。  相似文献   

Analysis of energetic electron drop-outs in the upper atmosphere of Titan during flybys in the dayside magnetosphere of Saturn     

Z. Bebesi  N. Krupp  K. Szego  M. Fränz  Z. Nemeth  S.M. Krimigis  D.G. Mitchell  G. Erdos  D.T. Young  M.K. Dougherty 《Icarus》2012,218(2):1020-1027

We discuss the high energy electron absorption signatures at Titan during the Cassini dayside magnetospheric encounters. We use the electron measurements of the Low Energy Measurement System of the Magnetospheric Imaging Instrument. We also examine the mass loading boundary based on the ion data of the Ion Mass Spectrometer sensor of the Cassini Plasma Spectrometer. The dynamic motion of the Kronian magnetopause and the periodic charged particle flux and magnetic field variations – associated with the magnetodisk of Saturn – of the subcorotating magnetospheric plasma creates a unique and complex environment at Titan. Most of the analysed flybys (like T25–T33 and T35–T51) cluster at similar Saturn Local Time positions. However the instantaneous direction of the incoming magnetospheric particles may change significantly from flyby to flyby due to the very different magnetospheric field conditions which are found upstream of Titan within the sets of encounters.The energetic magnetospheric electrons gyrate along the magnetic field lines of Saturn, and at the same time bounce between the mirror points of the magnetosphere. This motion is combined with the drift of the magnetic field lines. When these flux tubes interact with the upper atmosphere of Titan, their content is depleted over approximately an electron bounce period. These depletion signatures are observed as sudden drop-outs of the electron fluxes. We examined the altitude distribution of these drop-outs and concluded that these mostly detected in the exo-ionosphere of Titan and sometimes within the ionosphere.However there is a relatively significant scatter in the orbit to orbit data, which can be attributed to the which can be attributed to the variability of the plasma environment and as a consequence, the induced magnetosphere of Titan. A weak trend between the incoming electron fluxes and the measured drop-out altitudes has also been observed.  相似文献   

The Asymmetrical Eruption of a Quiescent Filament and Associated Halo CME     

J. Yang  Y. Jiang  B. Yang  R. Zheng  D. Yang  J. Hong  H. Li  Y. Bi 《Solar physics》2012,279(1):115-126

We will present detailed observations of the asymmetrical eruption of a large quiescent filament on 24 November 2002, which was followed by a two-ribbon flare, three coronal dimmings, endpoint brightenings, and a very fast halo-type coronal mass ejection (CME). Before the eruption, the filament lay along the main neutral line (MNL) underneath a single-arcade helmet streamer with a simple bipolar configuration. However, photospheric magnetic fields on both sides of the filament showed an asymmetrical distribution, and the filament and MNL were not located just at the center of the streamer base but were closer to the eastern leg of the streamer arcade. Therefore, instead of erupting along the streamer’s symmetrical axis, the filament showed a nonradial and asymmetrical eruption. It lifted from the eastern flank of the streamer arcade to impact the western leg directly, leading to an asymmetrical CME that expanded westward; eventually the streamer was disrupted significantly. Accordingly, the opposite-polarity coronal dimmings at both sides of the filament forming in the eruption also showed an asymmetrical area distribution. We thus assume that the streamer arcade could guide the filament at the early eruption phase but failed to restrain it later. Consistent with previous results, these observations suggest that the global background magnetic field can impose additional action on the initial eruption of the filament and CME, as well as the dimming configuration.  相似文献   

A modified Raupach's model applicable for shear-stress partitioning on surfaces covered with dense and flat-shaped gravel roughness elements     

Huiru Li  Xueyong Zou  Mengcui Zhang  Liqiang Kang  Chunlai Zhang  Hong Cheng  Xiaoxu Wu 《地球表面变化过程与地形》2021,46(5):907-920

A commonly used measure to prevent soil wind erosion is to cover the surface with gravel. Gravel can inhibit soil erosion by covering the surface directly, changing the airflow field near the surface and sharing the shear stress of wind. Similar to other roughness elements, the protective effect of gravel on soil is usually expressed in terms of the ratio of the shear stress on the exposed soil surface to the total shear stress on the rough surface due to wind, i.e. through a shear-stress partitioning model. However, the existing shear-stress partitioning models, represented by Raupach's model (RM93), are only applicable when the lateral coverage of the roughness elements, λ < 0.10, and the applicability of the models to flat-shaped roughness elements is unclear. The purpose of this study is to verify the applicability of RM93 for dense and flat-shaped gravel roughness elements by using shear-stress data from wind-tunnel measurements pertaining to roughness elements with different densities (0.013 ≤ λ ≤ 0.318) and flat shapes (height-to-width ratios in the range 0.20 ≤ H/W ≤ 0.63), and to modify RM93 to enhance its predictive ability. The results indicate that RM93 cannot accurately predict the shear-stress partitioning for surfaces covered by densely distributed and flat-shaped gravel roughness elements. This phenomenon occurs because, when roughness elements are distributed densely or are flat-shaped, the proportion of the shear stress on the top surface of the roughness elements (τ_c) to the total shear stress (τ) is large; in this case, τ_c plays a dominant role and serves as an essential component in the shear-stress partitioning model. Consequently, RM93 is modified by incorporating τ_c into the calculation of τ. Under conditions of λ < 0.32 and H/W > 0.2, the modified RM93 can yield satisfactory predictions regarding the shear-stress partitioning.  相似文献   

云南地区强震前小震调制比特征分析     

孙楠  付虹  彭关灵  刘自凤 《地震地磁观测与研究》2021,42(5):82-89

利用调制比时空扫描方法,对1973—2014年云南地区M_S≥6.0地震进行回溯性研究,分析强震前区域小震调制比时空演化过程。结果显示,从小震调制比异常开始至发震的持续时间为1.5 a之内,调制比异常的最高值需大于0.57,强震多发生在调制比为最高值时或其后14个月内异常区边界或内部调制比显著高值附近,震级随异常持续时间的延长大致呈增加的趋势;小滇西—滇西北地区的强震多发生在调制期内;从分区来看,滇西南强震多发生在调制比为最高值（R_m≥0.57）后6个月内的异常边界处,尤其是3个月内,滇西北强震多发生在最高值（R_m≥0.67）后7—12月内异常区内显著高值附近,滇东北强震多发生在最高值（R_m≥0.67）时的异常区内。  相似文献