Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel   总被引：1，自引：0，他引：1  

Anne?Smekens  Ricardo?Henrique?Moreton?Godoi  Patrick?Berghmans  René?Van?GriekenEmail author 《Journal of Atmospheric Chemistry》2005,52(1):45-62

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.  相似文献   

Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil     

Fernando?Henrique?Bucco?TallaricoEmail author  Neal?Jesse?McNaughton  David?Ian?Groves  Ian?R.?Fletcher  Bernardino?Ribeiro?Figueiredo  Jéssica?Beatriz?Carvalho  José?Luzimar?Rego  Alfredo?Rossetto?Nunes 《Mineralium Deposita》2004,39(1):68-86

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin  相似文献   

Model prediction capacity of ephemeral gully evolution in conservation tillage systems     

Eduardo Luquin  Miguel A. Campo-Bescós  Rafael Muñoz-Carpena  Ronald L. Bingner  Richard M. Cruse  Henrique G. Momm  Robert R. Wells  Javier Casalí 《地球表面变化过程与地形》2021,46(10):1909-1925

Ephemeral gully (EG) erosion has an important impact on agricultural soil losses and increases field surface hydrology connectivity and transport of pollutants to nearby water bodies. Watershed models including an EG component are scarce and not yet properly evaluated. The objective of this study is to evaluate the capacity of one such tool, AnnAGNPS, to simulate the evolution of two EG formed in a conservation tillage system. The dataset for model testing included runoff measurements and EG morphological characteristics during 3 years. Model evaluation focused on EG evolution of volume, width, and length model outputs, and included calibration and testing phases and a global sensitivity analysis (GSA). While the model did not fully reproduce width and length, the model efficiency to simulate EG volume was satisfactory for both calibration and testing phases, supporting the watershed management objectives of the model. GSA revealed that the most sensitive factors were EG depth, critical shear stress, headcut detachment exponent coefficient b, and headcut detachment leading coefficient a. For EG outputs the model was additive, showing low sensitivity to interactions between the inputs. Prediction of EG spatial evolution on conservation tillage systems requires improved development of gully erosion components, since many of the processes were developed originally for traditional tillage practices or larger channel systems. Our results identify the need for future research when EG form within conservation tillage systems, in particular to study gully headcut, soil erodibility, and width functions specific to these practices.  相似文献   

Camacho inlet southern Brazil - Instability causes and user conflicts     

Guilherme Vieira da Silva João Luiz Baptista de Carvalho  Antonio Henrique da Fontoura Klein 《Ocean & Coastal Management》2011,54(8):569-576

Inlet stabilization is a common practice in Brazil, as it is worldwide. In this paper we present results of the analysis of the stabilization practices of the Camacho Inlet, located in Santa Catarina State, southern Brazil. This inlet is maintained intermittently, in accordance with a regime designed to benefit both local fishermen and rice farmers. Fishermen require this inlet to be open as a navigation channel during the fishing season; rice farmers needs it closed during the irrigation period to allow the pumping of fresh water from the Congonhas River which drains into the Camacho’s backbarrier lagoon. An additional complication arises from the tendency of this inlet to close naturally due to infilling by dune migration. Aerial images spanning a 65 year time period (1938-2003) were analyzed, demonstrating the variability in the inlet’s width between 0 (closed) and 360 m. The analysis of inlet stability and user needs indicate that an appropriate solution is the implementation of an annual inlet dredging program in the austral autumn. This would allow for the inlet to remain open from May to September and then close naturally for the rest of the year, providing for a backbarrier fresh water reservoir during the irrigation period.  相似文献   

Stratigraphic evolution of the nearshore to fluvial plain of the Upper Cuyo Group,Neuquén,Argentina     

Henrique P. Kern  Ernesto L. C. Lavina  Paulo S. G. Paim  Hctor A. Leanza 《Sedimentology》2019,66(7):2686-2720

The upper portion of the Cuyo Group in the Zapala region, south‐eastern Neuquén Basin (Western Argentina), encompasses marine and transitional deposits (Lajas Formation) overlain by alluvial rocks (Challacó Formation). The Challacó Formation is covered by the Mendoza Group above a second‐order sequence boundary. The present study presents the stratigraphic framework and palaeophysiographic evolution of this Bajocian to Eo‐Calovian interval. The studied succession comprises the following genetic facies associations: (i) offshore and lower shoreface–offshore transition; (ii) lower shoreface; (iii) upper shoreface; iv) intertidal–subtidal; (v) supratidal–intertidal; (vi) braided fluvial to delta plain; (vii) meandering river; and (viii) braided river. The stratigraphic framework embraces four third‐order depositional sequences (C1 to C4) whose boundaries are characterized by the abrupt superposition of proximal over distal facies associations. Sequences C1 to C3 comprise mostly littoral deposits and display well‐defined, small‐scale transgressive–regressive cycles associated with fourth‐order depositional sequences. Such high‐frequency cycles are usually bounded by ravinement surfaces associated with transgressive lags. At last, the depositional sequence C4 delineates an important tectonic reorganization probably associated with an uplift of the Huincul Ridge. This is suggested by an inversion of the transport trend, north‐westward during the deposition of C1 to C3 depositional sequences (Lajas Formation) to a south‐west trend during the deposition of the braided fluvial strata related to the C4 depositional sequence (Challacó Formation).  相似文献   

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success     

Jordana Borini Freire  Rafael M. Sousa  Karla Taufner  Maria TW Carneiro  Henrique R Filgueiras  Dominik Lenz  Paulo Dias Ferreira  Denise C Endringer 《Marine Ecology》2021,42(1):e12633

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.  相似文献   

Magnitude of latent heat in thermally loaded clays     

Sergio Samat  Laurent Brochard  Ioannis Stefanou 《国际地质力学数值与分析法杂志》2020,44(14):1926-1957

Temperature changes are known to induce specific couplings in clay, in particular, an anomalously high thermal pressurization in undrained conditions or a thermal compaction in drained conditions, both of which are potential threats for the mechanical stability and sealing capacity of the geomaterials. Thermodynamical analysis of those peculiar thermomechanical couplings points to a potentially important latent energy, which in turn could limit the temperature change upon heating or cooling. The direct measurement of latent energy developed during a laboratory geomechanical test is challenging. Instead, proper identification of thermal hardening in conventional experiments with temperature changes provides an alternative route to estimate latent energy. In this work, existing laboratory thermomechanical tests of clays are analyzed with a rigorous thermodynamic framework to quantify the magnitude of latent energy in thermomechanically loaded clays. A thermodynamically consistent constitutive model for fully saturated clays that combines two key features, (a) the temperature dependence of the blocked energy and (b) the framework of bounding plasticity, is proposed. The performance of the model is validated by reproducing results obtained in laboratory tests for Boom and Opalinus clays. The thermomechanical loads considered to validate the model performance were then used to estimate the percentage of work that remains latent in the clayey material during plastic yielding. We find that the magnitude of latent energy is quite significant, typically a few tens of percent of the total dissipated energy, and increases significantly with temperature. Accordingly, it is expected to play an important role in the thermomechanical response of clays.  相似文献   

Spatially filtered ridge regression (SFRR): A regression framework to understanding impacts of land cover patterns on urban climate          下载免费PDF全文

Chao Fan  Sergio J. Rey  Soe W. Myint 《Transactions in GIS》2017,21(5):862-879

Understanding the impacts of land cover pattern on the heat island effect is essential for sustainable urban development. Conventional model fitting methods have restricted ability to produce accurate estimates of the land cover‐temperature association due to the lack of procedures to address two important issues: spatial dependence in proximal spatial units and high correlations among predictor variables. In this study, we seek to develop an effective framework called spatially filtered ridge regression (SFRR) to estimate the variations in the quantity and distribution of land surface temperature (LST) in response to various land cover patterns. The SFRR effectively integrates spatial autoregressive models and ridge regression, and it achieves reliable parameter estimates with substantially reduced mean square errors. We show this by comparing the performance of the SFRR to other widely adopted models using Monte Carlo simulation followed by an empirical study over central Phoenix. Results highlight the great potential of the SFRR in producing accurate statistical estimates, providing a positive step toward informed and unbiased decision‐making across a wide variety of disciplines. (Code and data to reproduce the results in the case study are available at: https://github.com/cfan13/SFRRTGIS.git .)  相似文献   

Performance of CMORPH,TMPA, and PERSIANN rainfall datasets over plain,mountainous, and glacial regions of Pakistan     

Yawar?HussainEmail author  Frédéric?Satgé  Muhammad?Babar?Hussain  Hernan?Martinez-Carvajal  Marie-Paule?Bonnet  Martin?Cárdenas-Soto  Henrique?Llacer?Roig  Gulraiz?Akhter 《Theoretical and Applied Climatology》2018,131(3-4):1119-1132

The present study aims at the assessment of six satellite rainfall estimates (SREs) in Pakistan. For each assessed products, both real-time (RT) and post adjusted (Adj) versions are considered to highlight their potential benefits in the rainfall estimation at annual, monthly, and daily temporal scales. Three geomorphological climatic zones, i.e., plain, mountainous, and glacial are taken under considerations for the determination of relative potentials of these SREs over Pakistan at global and regional scales. All SREs, in general, have well captured the annual north-south rainfall decreasing patterns and rainfall amounts over the typical arid regions of the country. Regarding the zonal approach, the performance of all SREs has remained good over mountainous region comparative to arid regions. This poor performance in accurate rainfall estimation of all the six SREs over arid regions has made their use questionable in these regions. Over glacier region, all SREs have highly overestimated the rainfall. One possible cause of this overestimation may be due to the low surface temperature and radiation absorption over snow and ice cover, resulting in their misidentification with rainy clouds as daily false alarm ratio has increased from mountainous to glacial regions. Among RT products, CMORPH-RT is the most biased product. The Bias was almost removed on CMORPH-Adj thanks to the gauge adjustment. On a general way, all Adj versions outperformed their respective RT versions at all considered temporal scales and have confirmed the positive effects of gauge adjustment. CMORPH-Adj and TMPA-Adj have shown the best agreement with in situ data in terms of Bias, RMSE, and CC over the entire study area.  相似文献   

SlugIn 1.0: A Free Tool for Automated Slug Test Analysis          下载免费PDF全文

Sergio Martos‐Rosillo  Carolina Guardiola‐Albert  Alberto Padilla Benítez  Joaquín Delgado Pastor  Antonio Azcón González  Juan José Durán Valsero 《Ground water》2018,56(3):362-365

The correct characterization of aquifer parameters is essential for water‐supply and water‐quality investigations. Slug tests are widely used for these purposes. While free software is available to interpret slug tests, some codes are not user‐friendly, or do not include a wide range of methods to interpret the results, or do not include automatic, inverse solutions to the test data. The private sector has also generated several good programs to interpret slug test data, but they are not free of charge. The computer program SlugIn 1.0 is available online for free download, and is demonstrated to aid in the analysis of slug tests to estimate hydraulic parameters. The program provides an easy‐to‐use Graphical User Interface. SlugIn 1.0 incorporates automated parameter estimation and facilitates the visualization of several interpretations of the same test. It incorporates solutions for confined and unconfined aquifers, partially penetrating wells, skin effects, shape factor, anisotropy, high hydraulic conductivity formations and the Mace test for large‐diameter wells. It is available in English and Spanish and can be downloaded from the web site of the Geological Survey of Spain. Two field examples are presented to illustrate how the software operates.  相似文献