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71.
Of recent, adsorption process has gained a lot of attention as a cheap and effective means of removing trace metals from wastewater prior to discharge into water bodies. Being flexible in design and operation, the process has enabled an optimal recovery of trace metals such that the treated effluents meet the desired standards for waste disposal. Mercury is a toxicant released into the environment from natural and anthropogenic sources. It is notorious for having an unusual tendency to bio‐accumulate and persist in the food chain. Presence of mercury in food, especially those of aquatic sources has drastic implications on human health. Therefore, efforts have been made to develop and optimize low‐cost activated carbon (AC) as adsorbents for scavenging mercury from aqueous effluents. Herein, how mercury accumulates across the food chain, its health implications, and the recent advancement in the use of low‐cost ACs as adsorbent for trapping mercury from wastewater are highlighted. Relationship between the mercury removal efficiency and the surface morphology of the adsorbents as well as the influence of prevailing experimental condition on the sorption process were addressed. Challenges and future prospects of the use of low‐cost adsorbents in addressing mercury pollution in the environment are discussed.  相似文献   
72.
Natural Resources Research - The significant body of research on lithology identification in recent years has laid emphasis on the improvement of classification performance using hybrid machine...  相似文献   
73.
A one dimensional time-dependent model of the neutral and ion chemistry of the middle atmosphere has been used to examine the production of odd hydrogen (H, OH, and HO2) during charged particle precipitation. At altitudes above about 65 km, odd hydrogen production depends on the ionization rate, and the atomic oxygen and water vapor densities. Odd hydrogen production is shown to exhibit diurnal and other time dependent variations during such an event at these altitudes, and the assumption that two odd hydrogen particles are always produced per ionization is reexamined.  相似文献   
74.
Issues in sediment toxicity and ecological risk assessment   总被引:8,自引:0,他引:8  
This paper is based on a facilitated Workshop and Roundtable Discussion of key issues in sediment toxicology and ecological risk assessment (ERA) as applied to sediments that was held at the Conference on Dredged Material Management: Options and Environmental Considerations. The issues addressed included how toxicity is defined and perceived, how it is measured, and how it should be used within the context of ERA to support management decisions. The following conclusions were reached regarding scientific considerations of these issues. Toxicity is a measure of hazard and not a risk per se. Thus, toxicity testing is a means but not the end to understand risks of sediments. Toxicity testing cannot presently be replaced by chemical analyses to define hazard. Toxicity test organisms need to be appropriate to the problem being addressed, and the results put into context relative to both reference and baseline comparisons to understand hazard. Use of toxicity tests in sediment ERAs requires appropriate endpoints and risk hypotheses, considering ecological not just statistical significance, and recognizing that hazard does not equate to risk. Toxicity should be linked to population and community response to support decision-making, assessing possible genotypic adaptations that can influence risk estimates, and addressing uncertainty. Additionally, several key scientific issues were identified to improve future sediment ERAs, including the need to improve basic understanding of ecological mechanisms and processes, recognition of variability in the assessment process, and an improved focus and ability to assess risks to populations and communities.  相似文献   
75.
There are few published seismic (P- and S-waves) properties for seafloor bedrocks. At low pressures (1 to 10 MPa), velocities and attenuations are determined mainly by open microcracks. At higher pressures, the microcracks close, and the velocities and attenuations depend primarily on the matrix porosity. We have investigated both the relationships between the acoustic, petrophysical, and geological properties of the rocks at 40 MPa pressure and the effect of microcracks on the acoustic properties at 10 MPa pressure. In this paper we discuss the former; the latter will be discussed separately. P- and S-wave velocity and attenuation measurements were carried out on a suite of seabed sedimentary and igneous rocks at effective pressures from 10 to 40 MPa at ultrasonic frequencies. The porosities and permeabilities of the rocks ranged from 0% to 32% and 0 to 110 mDarcy, respectively. Characterization of the rocks revealed that most of the sandstones have a substantial clay content (kaolinite, illite, and chlorite) and fractures. Most of the igneous rocks are chloritized. The seismic properties of the rocks are markedly lower than those of similar continental rocks because of the microporosity formed by the alteration of feldspars, micas, and mafic minerals to clays (e.g., chloritization of pyroxenes) and the corresponding reduction of the elastic moduli. The results of this study suggest that the values of velocities and quality factors used for ocean acoustic propagation models are lower than normally assumed.  相似文献   
76.
This paper describes the development of tsunami scenarios from the National Seismic Hazard Maps for design of coastal infrastructure in the Pacific Northwest. The logic tree of Cascadia earthquakes provides four 500-year rupture configurations at moment magnitude 8.8, 9.0, and 9.2 for development of probabilistic design criteria. A planar fault model describes the rupture configurations and determines the earth surface deformation for tsunami modeling. A case study of four bridge sites at Siletz Bay, Oregon illustrates the challenges in modeling of tsunamis on the Pacific Northwest coast. A nonlinear shallow-water model with a shock-capturing scheme describes tsunami propagation across the northeastern Pacific as well as barrier beach overtopping, bore formation, and detailed flow conditions at Siletz Bay. The results show strong correlation with geological evidence from the six paleotsunamis during the last 2800 years. The proposed approach allows determination of tsunami loads that are consistent with the seismic loads currently in use for design of buildings and structures.  相似文献   
77.
Mathematical modelling of the ascent of free fluid through relatively strong rock, deep in the Earth's mantle, presents a challenge in geomechanics. Here the medium is considered as fluid-saturated, porous, elastic and bounded, and the fluid enters at a point source. An explicit finite difference method is developed for the numerical solution to the problem of the dilatation of a fluid-saturated porous elastic sphere due to a point fluid source of constant strength at the centre of the sphere. A cubic spline interpolant is used to evaluate a definite integral which occurs in the boundary condition for the pore fluid pressure at the surface of the sphere. The numerical solutions for the dilatation and pore fluid pressure are compared with analytical solutions and the absolute and relative errors of the numerical solutions are calculated. When the fluid source is switched on, the pore fluid pressure starts to decrease, reaches a minimum value and then steadily increases. The initial time rate of decrease of the pore fluid pressure is independent of the radial distance from the source. It decreases as the radius of the sphere increases and vanishes for a point fluid source in an infinite porous elastic medium.  相似文献   
78.
Mercury holds answers to several critical questions regarding the formation and evolution of the terrestrial planets. These questions include the origin of Mercury's anomalously high ratio of metal to silicate and its implications for planetary accretion processes, the nature of Mercury's geological evolution and interior cooling history, the mechanism of global magnetic field generation, the state of Mercury's core, and the processes controlling volatile species in Mercury's polar deposits, exosphere, and magnetosphere. The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission has been designed to fly by and orbit Mercury to address all of these key questions. After launch by a Delta 2925H-9.5, two flybys of Venus, and two flybys of Mercury, orbit insertion is accomplished at the third Mercury encounter. The instrument payload includes a dual imaging system for wide and narrow fields-of-view, monochrome and color imaging, and stereo; X-ray and combined gamma-ray and neutron spectrometers for surface chemical mapping; a magnetometer; a laser altimeter; a combined ultraviolet–visible and visible-near-infrared spectrometer to survey both exospheric species and surface mineralogy; and an energetic particle and plasma spectrometer to sample charged species in the magnetosphere. During the flybys of Mercury, regions unexplored by Mariner 10 will be seen for the first time, and new data will be gathered on Mercury's exosphere, magnetosphere, and surface composition. During the orbital phase of the mission, one Earth year in duration, MESSENGER will complete global mapping and the detailed characterization of the exosphere, magnetosphere, surface, and interior.  相似文献   
79.
In the quiet lower thermosphere, photolysis of N2 produces translationally excited N(4S) and N(2D) atoms. A fraction of these N(4S) atoms may react rapidly with O2 while still translationally hot. This results in substantially larger calculated NO densities than those obtained if translational excitation is not considered. The sensitivity of the calculated NO density in the lower thermosphere to this process is examined.  相似文献   
80.
Density models for the Moon, including the effects of temperature and pressure, can satisfy the mass and moment of inertia of the Moon and the presence of a low density crust indicated by the seismic refraction results only if the lunar mantle is chemically or mineralogically inhomogeneous. IfC/MR 2 exceeds 0.400, the inferred density of the upper mantle must be greater than that of the lower mantle at similar conditions by at least 0.1 g cm–3 for any of the temperature profiles proposed for the lunar interior. The average mantle density lies between 3.4 and 3.5 g cm–3, though the density of the upper mantle may be greater. The suggested density inversion is gravitationally unstable, but the implied deviatoric stresses in the mantle need be no larger than those associated with lunar gravity anomalies. UsingC/MR 3=0.400 and the recent seismic evidence suggesting a thin, high density zone beneath the crust and a partially molten core, successful density models can be found for a range of temperature profiles. Temperature distributions as cool as several inferred from the lunar electrical conductivity profile would be excluded. The density and probable seismic velocity for the bulk of the mantle are consistent with a pyroxenite composition and a 100 MgO/(MgO+FeO) molecular ratio of less than 80.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.  相似文献   
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