Velocities of compressional and shear waves in limestones   总被引：2，自引：1，他引：2  

Solomon Assefa  Clive McCann  Jeremy Sothcott 《Geophysical Prospecting》2003,51(1):1-13

Carbonate rocks are important hydrocarbon reservoir rocks with complex textures and petrophysical properties (porosity and permeability) mainly resulting from various diagenetic processes (compaction, dissolution, precipitation, cementation, etc.). These complexities make prediction of reservoir characteristics (e.g. porosity and permeability) from their seismic properties very difficult. To explore the relationship between the seismic, petrophysical and geological properties, ultrasonic compressional‐ and shear‐wave velocity measurements were made under a simulated in situ condition of pressure (50 MPa hydrostatic effective pressure) at frequencies of approximately 0.85 MHz and 0.7 MHz, respectively, using a pulse‐echo method. The measurements were made both in vacuum‐dry and fully saturated conditions in oolitic limestones of the Great Oolite Formation of southern England. Some of the rocks were fully saturated with oil. The acoustic measurements were supplemented by porosity and permeability measurements, petrological and pore geometry studies of resin‐impregnated polished thin sections, X‐ray diffraction analyses and scanning electron microscope studies to investigate submicroscopic textures and micropores. It is shown that the compressional‐ and shear‐wave velocities (V_p and V_s, respectively) decrease with increasing porosity and that V_p decreases approximately twice as fast as V_s. The systematic differences in pore structures (e.g. the aspect ratio) of the limestones produce large residuals in the velocity versus porosity relationship. It is demonstrated that the velocity versus porosity relationship can be improved by removing the pore‐structure‐dependent variations from the residuals. The introduction of water into the pore space decreases the shear moduli of the rocks by about 2 GPa, suggesting that there exists a fluid/matrix interaction at grain contacts, which reduces the rigidity. The predicted Biot–Gassmann velocity values are greater than the measured velocity values due to the rock–fluid interaction. This is not accounted for in the Biot–Gassmann velocity models and velocity dispersion due to a local flow mechanism. The velocities predicted by the Raymer and time‐average relationships overestimated the measured velocities even more than the Biot model.  相似文献   

Biomarkers in marbled flounder (Pleuronectes yokohamae) from contaminated and reference sites in South Korea     

Jee Hyun Jung  R.F. Addison  Un Hyuk Yim  Sang Hee Hong  Sungyong Ha  Won Joon Shim   《Marine pollution bulletin》2009,58(11):1754-1759

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ARD generation and corrosion potential of exposed roadside rockmass at Boeun and Mujoo,South Korea     

Sang Woo Ji  Young Wook Cheong  Gil Jae Yim  Jayanta Bhattacharya 《Environmental Geology》2007,52(6):1033-1043

Acid rock drainage (ARD) is a longstanding problem often associated with the resulting corrosion due to the acidity generated from sulfidic oxidation. To evaluate characteristics of ARD and corrosion, samples from the road side rock mass of Boeun and Mujoo were analysed using X-ray diffraction, acid/base accounting and Leaching tests. The results indicated that many samples had a pyritic origin and can be regarded as acid-generating rocks. The Leaching test showed that the average pH of the leachates of samples from both Boeun and Mujoo were moderately acidic, ranging from 3 to 4. Interestingly, as acidity increases from pH 4, the SO₄₋, Fe, Al and Mg concentrations increase abnormally. Samples from roadside slope of Mujoo showed high corrosive potential. Maximum sulfide oxidation rate of a sample taken from Mujoo was as high as 5,166 mg/kg/week.  相似文献   

A preliminary report of persistent organochlorine pollutants in the Yellow Sea   总被引：5，自引：0，他引：5  

Oh JR  Choi HK  Hong SH  Yim UH  Shim WJ  Kannan N 《Marine pollution bulletin》2005,50(2):217-222

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The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere: II. Odd hydrogen     

S. Solomon  D.W. Rusch  J.C. Gérard  G.C. Reid  P.J. Crutzen 《Planetary and Space Science》1981,29(8):885-893

A one dimensional time-dependent model of the neutral and ion chemistry of the middle atmosphere has been used to examine the production of odd hydrogen (H, OH, and HO₂) during charged particle precipitation. At altitudes above about 65 km, odd hydrogen production depends on the ionization rate, and the atomic oxygen and water vapor densities. Odd hydrogen production is shown to exhibit diurnal and other time dependent variations during such an event at these altitudes, and the assumption that two odd hydrogen particles are always produced per ionization is reexamined.  相似文献   

Issues in sediment toxicity and ecological risk assessment   总被引：8，自引：0，他引：8  

Chapma PM  Ho KT  Munns WR  Solomon K  Weinstein MP 《Marine pollution bulletin》2002,44(4):271-278

This paper is based on a facilitated Workshop and Roundtable Discussion of key issues in sediment toxicology and ecological risk assessment (ERA) as applied to sediments that was held at the Conference on Dredged Material Management: Options and Environmental Considerations. The issues addressed included how toxicity is defined and perceived, how it is measured, and how it should be used within the context of ERA to support management decisions. The following conclusions were reached regarding scientific considerations of these issues. Toxicity is a measure of hazard and not a risk per se. Thus, toxicity testing is a means but not the end to understand risks of sediments. Toxicity testing cannot presently be replaced by chemical analyses to define hazard. Toxicity test organisms need to be appropriate to the problem being addressed, and the results put into context relative to both reference and baseline comparisons to understand hazard. Use of toxicity tests in sediment ERAs requires appropriate endpoints and risk hypotheses, considering ecological not just statistical significance, and recognizing that hazard does not equate to risk. Toxicity should be linked to population and community response to support decision-making, assessing possible genotypic adaptations that can influence risk estimates, and addressing uncertainty. Additionally, several key scientific issues were identified to improve future sediment ERAs, including the need to improve basic understanding of ecological mechanisms and processes, recognition of variability in the assessment process, and an improved focus and ability to assess risks to populations and communities.  相似文献   

Large angular motions of tethered surface buoys     

J. W. Leonard  K. Idris  S. C. S. Yim 《Ocean Engineering》2000,27(12):290

A three-dimensional coupled analysis of the interaction of a floating buoy and its mooring is studied. External loads include hydrodynamic forces, tether tensions, wind loads and system weight and buoyancy. Nonlinearities include large rotational and translational motions and non-conservative fluid loads. The mooring problem is formulated as a nonlinear two-point-boundary-value-problem. At each instant in time, the mooring problem is solved by direct integration using a successive iterative algorithm to satisfy boundary conditions. Buoy kinetic and kinematic equations are derived assuming large angles represented by Euler parameters. Coupling between the buoy and the mooring is enforced by matching the velocities of the tether and buoy at the attachment point. A predictor-corrector coupling algorithm is used with multiple sizes of time steps used to provide stability for the separate mooring and buoy models. Numerical results are compared to experimental responses of three types of buoys (sphere, spar and disc) subject to both regular and irregular waves.  相似文献   

Seismic and Petrophysical Relationships from UK Continental Shelf Rocks at Elevated Pressures     

Solomon Assefa  Clive McCann  Jeremy Sothcott 《Marine Georesources & Geotechnology》2000,18(2):119-140

There are few published seismic (P- and S-waves) properties for seafloor bedrocks. At low pressures (1 to 10 MPa), velocities and attenuations are determined mainly by open microcracks. At higher pressures, the microcracks close, and the velocities and attenuations depend primarily on the matrix porosity. We have investigated both the relationships between the acoustic, petrophysical, and geological properties of the rocks at 40 MPa pressure and the effect of microcracks on the acoustic properties at 10 MPa pressure. In this paper we discuss the former; the latter will be discussed separately. P- and S-wave velocity and attenuation measurements were carried out on a suite of seabed sedimentary and igneous rocks at effective pressures from 10 to 40 MPa at ultrasonic frequencies. The porosities and permeabilities of the rocks ranged from 0% to 32% and 0 to 110 mDarcy, respectively. Characterization of the rocks revealed that most of the sandstones have a substantial clay content (kaolinite, illite, and chlorite) and fractures. Most of the igneous rocks are chloritized. The seismic properties of the rocks are markedly lower than those of similar continental rocks because of the microporosity formed by the alteration of feldspars, micas, and mafic minerals to clays (e.g., chloritization of pyroxenes) and the corresponding reduction of the elastic moduli. The results of this study suggest that the values of velocities and quality factors used for ocean acoustic propagation models are lower than normally assumed.  相似文献   

Assessment of pollution and ecological risk of heavy metals in the surface sediments of Ulsan Bay,Korea     

Kongtae Ra  Joung-Keun Kim  Sang Hee Hong  Un Hyuk Yim  Won Joon Shim  Seung-Yong Lee  Young-Ok Kim  Jaesoo Lim  Eun-Soo Kim  Kyung-Tae Kim 《Ocean Science Journal》2014,49(3):279-289

Heavy metal concentrations in the surface sediments of specially managed Ulsan Bay were investigated to determine metal distribution, pollution status and its ecological risk using pollution indices (enrichment factor and geo-accumulation index), potential ecological risk index and sediment quality guidelines (SQGs). The order of mean concentration (mg/kg) of metals was Zn (361.9) > Cu (95.6) > Pb (90.7) > Cr (64.7) > Ni (32.2) > Co (16.6) > As (15.8) > Cd (0.40) > Hg (0.16) in sediments of Ulsan Bay. Spatial distribution of metals in sediments showed a significantly higher concentration near industrial complexes, indicating that metal pollution is caused by anthropogenic sources. The results of enrichment factor (EF) and geo-accumulation index (I_geo) showed that sediments were significantly accumulated with Cu, Zn, As, Cd, Pb and Hg, indicating moderate to very severe enrichment (pollution) by these metals. Based on the potential ecological risk index, Hg and Cd posed a very high and a considerable potential ecological risk. Cu and As posed a moderate potential ecological risk, while, other metals (Cr, Co, Ni, Zn and Pb) rarely posed any potential ecological risk to the coastal environments. The sediments in Ulsan Bay showed a very high level of ecological risk, dominated by Hg and Cd. Metal concentrations in sediments were 80% for Cu, 96.7% for Zn, 50% for As, 70% for Pb and 50% for Hg above the threshold effects level (TEL), respectively.  相似文献   

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)   总被引：1，自引：0，他引：1  

Jung JH  Kim M  Yim UH  Ha SY  An JG  Won JH  Han GM  Kim NS  Addison RF  Shim WJ 《Marine pollution bulletin》2011,62(8):1859-1866

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.  相似文献