Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family     

Romain de Mesmay  Pierre Metzger  Vincent Grossi  Sylvie Derenne 《Organic Geochemistry》2008,39(7):879-893

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.  相似文献   

Millennium-long recession of limestone facades in London     

Peter Brimblecombe  Carlota M. Grossi 《Environmental Geology》2008,56(3-4):463-471

Historical data on the temperature and precipitation data for London has been combined with output from the Hadley Model to estimate the climate of London for the period 1100–2100 CE. This has been converted to other parameters such as freeze–thaw frequency and snowfall relevant to the weathering of stone facades. The pollutant concentrations have been estimated for the same period, with the historical values taken from single box modelling and future values from changes likely given current policy within the metropolis. These values are used in the Lipfert model to show that the recession from karst weathering dominates across the period, while the contributions of sulphur deposition seem notable only across a shorter period 1700–2000 CE. Observations of the late seventeenth century suggest London architects witnessed a notable increase in the recession rate and attributed “fretting quality” to “smoaks of the sea-coal”. The recession rates measured in the late twentieth century lend some support to the estimates from the Lipfert model. The recession looks to increase only slightly, and frost shattering will decrease while salt weathering is likely to increase.  相似文献   

Contribution of Sponge Spicules to the Composition of Biogenic Silica in the Ligurian Sea     

Giorgio  Bavestrello  Riccardo  Cattaneo-Vietti  Carlo  Cerrano  Stefania  Cerutti Michele  Sará 《Marine Ecology》1996,17(1-3):41-50

Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.  相似文献   

Assumption and elimination of trace elements in Adélie penguins from Antarctica: a preliminary study     

Ancora S  Volpi V  Olmastroni S  Focardi S  Leonzio C 《Marine environmental research》2002,54(3-5):341-344

The concentration and distribution of some trace elements were determined in stomach contents, excreta and feathers of Adélie penguins (Pygoscelis adeliae) breeding at Edmonson Point (Terra Nova Bay-Antarctica). In these materials obtained by non-destructive methods, concentrations of mercury, cadmium and lead measured were used to establish natural levels of these metals in the penguins' diet. An intake-excretion hypothesis was formulated.  相似文献   

Comments on free and damped vibrations of an orthotrophic rectangular plate with one edge free while the rest are elastically restrained against rotation by M. Barbaros Okan     

P. A. A. Laura  R. O. Grossi  L. Ercoli 《Ocean Engineering》1983,10(2):139

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Biomarkers of Exposure and Effects for Assessing Toxicological Risk of Endocrine Disrupters in Top Predators of the Mediterranean Sea     

M. Cristina Fossi  Silvia Casini  Letizia Marsili  Stefania Ancora  Gabriele Mori  Giovanni Neri  Antonella Ausili  Teresa Romeo  Alessandra Moscatelli  Giuseppe Notarbartolo Di  Sciara 《Marine Ecology》2002,23(S1):184-189

Abstract. Endocrine Disrupting Chemicals (EDCs) have the potential to alter hormone pathways that regulate reproductive processes in wildlife and fisheries. In this research the unexplored hypothesis that Mediterranean top predator species (such as large pelagic fish and marine mammals) are potentially at risk due to EDCs is investigated. In the Mediterranean environment, top predators accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, incurring high toxicological risk. Here we illustrate the need to develop sensitive biomarkers for evaluation of toxicological risk in top marine predators (Xiphias gladius, Thunnus thynnus thynnus) and non-lethal techniques, such as non-destructive biomarkers, for the hazard assessment of threatened species exposed to EDCs, such as marine mammals ( Stenella coeruleoalba, Tursiops truncatus, Delphinus delphis and Balaenoptera physalus ).  相似文献   

Acknowledgement of referees for Volume 77 (2015)     

Roberto Scandone  Stefania Bartolini  Joan Martí 《Bulletin of Volcanology》2016,78(1):1-19

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Evaluating soil erosion by water in a small alpine catchment in Northern Italy: comparison of empirical models     

Berteni  Francesca  Barontini  Stefano  Grossi  Giovanna 《中国地球化学学报》2021,40(4):507-524

Acta Geochimica - To quantify water erosion rates and annual soil loss in mountainous areas, two different empirical models were used to estimate the effects of soil erosion in a small mountain...  相似文献   

Characterization of volcanic thermal anomalies by means of sub-pixel temperature distribution analysis     

Valerio Lombardo  Maria Fabrizia Buongiorno  Stefania Amici 《Bulletin of Volcanology》2006,68(7-8):641-651

The simultaneous solution of the Planck equation (involving the widely used “dual-band” technique) using two shortwave infrared (SWIR) bands allows for an estimate of the fractional area of the hottest part of an active lava flow (f _h) and the background temperature of the cooler crust (T _c). The use of a high spectral and spatial resolution imaging spectrometer with a wide dynamic range of 15 bits (DAIS 7915) in the wavelength range from 0.501 to 12.67 μm resulted in the identification of crustal temperature and fractional areas for an intra-crater hot spot at Mount Etna, Italy. This study indicates the existence of a relationship between these T _c and f _h extracted from DAIS and Landsat TM data. When the dual band equation system is performed on a lava flow, a logarithmic distribution is obtained from a plot of the fractional area of the hottest temperature vs. the temperature of the cooler crust. An entirely different distribution is obtained over active degassing vents, where increases in T _c occur without any increase in f _h. This result indicates that we can use scatter plots of T _c vs. fh to discriminate between different types of volcanic activity, in this case between degassing vents and lava flows, using satellite thermal data.  相似文献   

Study of temperature and precipitation variations in Italy based on surface instrumental observations   总被引：1，自引：0，他引：1  

Tiziano Colombo  Vinicio Pelino  Stefania Vergari  Paolo Cristofanelli  Paolo Bonasoni 《Global and Planetary Change》2007,57(3-4):308-318

In this paper we present a study concerning the climatic behaviour of two principal observables, temperature and precipitation as obtained from the measurements carried out at 50 Italian meteorological stations, since 1961. Analyses of WMO Climate Normals (CliNo) from 1961 to 1990 have been performed dividing the 50 Italian stations in three different classes: mountain (11 stations), continental (17) and coastal areas (21).The comparison of the CliNo 1961–1990 with the trend of temperature and precipitation for the period 1991–2000 showed a sharp significant increase of summer temperatures over Italy starting from 1980. This phenomenon was particularly evident for mountain stations, where a significant temperature increase has been recorded also during the autumn. Moreover, the analysis of precipitation data permitted to point out that, starting from 1980, mountain stations have been affected by a significant increase of precipitation events during autumn and winter, while for the rest of the Italian territory a reduction of precipitations has been recorded during early spring.  相似文献