Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization   总被引：1，自引：0，他引：1  

Hoon Y. Jeong  Sung W. Park 《Geochimica et cosmochimica acta》2010,74(11):3182-5194

Oxidation of mackinawite (FeS) and concurrent mobilization of arsenic were investigated as a function of pH under oxidizing conditions. At acidic pH, FeS oxidation is mainly initiated by the proton-promoted dissolution, which results in the release of Fe(II) and sulfide in the solution. While most of dissolved sulfide is volatilized before being oxidized, dissolved Fe(II) is oxidized into green rust-like precipitates and goethite (α-FeOOH). At basic pH, the development of Fe(III) (oxyhydr)oxide coating on the FeS surface inhibits the solution-phase oxidation following FeS dissolution. Instead, FeS is mostly oxidized into lepidocrocite (γ-FeOOH) via the surface-mediated oxidation without dissolution. At neutral pH, FeS is oxidized via both the solution-phase oxidation following FeS dissolution and the surface-mediated oxidation mechanisms. The mobilization of arsenic during FeS oxidation is strongly affected by FeS oxidation mechanisms. At acidic pH (and to some extent at neutral pH), the rapid FeS dissolution and the slow precipitation of Fe (oxyhydr)oxides results in arsenic accumulation in water. In contrast, the surface-mediated oxidation of FeS at basic pH leads to the direct formation of Fe (oxyhydr)oxides, which provides effective adsorbents for As under oxic conditions. At acidic and neutral pH, the solution-phase oxidation of dissolved Fe(II) accelerates the oxidation of the less adsorbing As(III) to the more adsorbing As(V). This study reveals that the oxidative mobilization of As may be a significant pathway for arsenic enrichment of porewaters in sulfidic sediments.  相似文献   

Estimation of the methane flux from mud volcanoes along Chishan Fault,southwestern Taiwan     

Hung-Cheng Chang  Quo-Cheng Sung  Lei Chen 《Environmental Earth Sciences》2010,61(5):963-972

Because of the increasing public awareness of the greenhouse effect, geological emissions of methane (GEM) have gained more attention. The Intergovernmental Panel on Climate Change included GEM in the natural sources of methane category in the Fourth Assessment Report in 2007. The methane flux from mud volcanoes (MVs) is the second leading source within GEM. However, given that gas flux from MVs has been measured directly only in Sicily and Azerbaijan, the global methane estimation is still a conservative assumption based on limited data. The behavior of MV activities is seldom reported. This study attempts to estimate annual methane emissions through MVs by using a video recorder to record MV activities along the Chishan Fault and determining the bubble size and flux rate of each MV. Observation results, after a 1 year observation period, indicate that the annual emissions of the 19 MVs along the Chishan Fault are 0.1–0.2% of the global methane flux from MVs, highlighting that the methane emission from these MVs should not be neglected. In addition, the continuous monitoring of a particular MV disclosed periodic characteristics of MV activities. These results manifest the spatial and temporal variations of MV activities along the Chishan Fault. The spatial variations are related to the extensional kinematics of the Chishan fault, while the temporal variation relates to the earth-tide-related MV activities. The estimated annual methane emissions from the study are far more than those of previous studies and are still considered conservative. Results of this study may provide valuable information for researchers attempting to estimate the quantity of GEM.  相似文献   

Availability of coastal groundwater discharge as an alternative water resource in a large-scale reclaimed land,Korea     

Byung Sun Lee  Sung-Ho Song  Jin Sung Kim  Jae Yeon Um  Kyoungphile Nam 《Environmental Earth Sciences》2014,71(4):1521-1532

This study was conducted to identify the availability of coastal groundwater discharge (CGD), subsurface fluids flowing from inland through the coastal area to sea, as an alternative water resource for a large-scale reclaimed land. The behaviors of stable isotopes indicated that groundwater originated from inland precipitation and traveled as CGD along the coast line. Most of the groundwater samples collected from domestic wells installed along the old coast line were considered to be relatively fresh from the correlation analysis among chemical constituents. The average electrical conductivity (EC) values of the samples were identified as averaging 1,125–1,297 μS cm^?1, corresponding to appropriate crop growth. A weathered-rock layer in a small catchment within the reclaimed land was proved to be a main CGD pathway, with electrical resistivity anomalies ranging from 7 to 14 Ω m. Five monitoring wells were placed in this catchment to delineate the occurrence of CGD. Long-term vertical EC profiling results for the monitoring wells indicated that CGD occurs within a depth of 30 m below the ground surface. Annual monitoring data for groundwater level and EC demonstrated that the water quality of CGD was improved by introducing fresh terrestrial groundwater. A remarkable improvement in water quality (EC decrease of 900–1,600 μS cm^?1) of CGD was observed during the saline water pumping test that explains how CGD could be an alternative water resource for the reclaimed land.  相似文献   

Geochemical survey of rare earth elements (REEs) in the concealed ore body of Hongcheon,Korea     

Joo Sung Ahn  Seung-Jun Youm  Yong-Chan Cho  Seong-Cheon Shin  Wan-Hyoung Cho 《Environmental Earth Sciences》2014,72(6):2153-2161

Because of the risk of diminishing supplies of rare earth elements (REEs) worldwide due to China’s dominance over REE supply, the necessity of developing domestic resources of REE has been realized in other countries. To explore new ore bodies, a geochemical survey was conducted at one existing carbonatite REE deposit in the Hongcheon area of Korea. Proper sampling strategies and baseline data for the interpretation of the results were determined through a pilot study conducted in the area. Enrichment in the concentration of light REE (LREE) over that of heavy REE, which is typical in carbonatite-type deposits, was observed in stream sediments and heavy mineral samples collected during the geochemical survey. Maximum concentrations of LREE were 2,299 and 27,798 mg/kg for stream sediments and heavy minerals, respectively. Among LREEs, La and Ce are the dominant components of all REEs, comprising approximately 68 % of mean concentrations. Considering the distribution pattern of La + Ce contents and the associations with the existing outcropping ore bodies, the zone of prospective REE mineralization was determined to be in the south-western part of the area. A detailed follow-up soil survey of the zone found even higher concentrations of La and Ce (2,450 and 3,100 mg/kg, respectively), and suggested the possible extension of the existing ore bodies. Likewise, a systematic geochemical survey for REE is feasible for locating concealed ore bodies in the area, where the mineralization is mostly covered with soil, and rock outcrops are scarce.  相似文献   

Composition and exhalation flux of gases from mud volcanoes in Taiwan   总被引：3，自引：0，他引：3  

Tsanyao?Frank?YangEmail author  Gao-Hua?Yeh  Ching-Chou?Fu  Cheng-Chen?Wang  Te-Fang?Lan  Hsiao-Fen?Lee  Cheng-Hong?Chen  Vivek?Walia  Quo-Cheng?Sung 《Environmental Geology》2004,46(8):1003-1011

Many mud volcanoes are distributed along the tectonic sutures in southern Taiwan and can be divided into five zones based on their relative positions in different tectonic domains. Most active mud volcanoes are exhaling methane-dominated gases. Nevertheless, some gases show unusual carbon dioxide-dominated and/or nitrogen-excess compositions. This implies that there are multiple sources for the gas compositions of mud volcanoes in Taiwan.For better understanding the total amount of exhalation gases and its flux, the gas flow and compositions were continuously measured in the interval of two minutes at Chung-lun (CL) bubbling mud pool for a few months. The major compositions of gases exhaling from this site were 75~90% of CO₂ and 5~12% of CH₄. The amount of gases exhaling from the mud pool can be estimated to be about 1.4 ton/year for CH₄ and 28 ton/year for CO₂, respectively. The preliminary results of exhaling gas flux from the major vents of representative active mud volcanoes, yielded an estimated total CH₄ output of the mud volcanoes in Taiwan of ca. 29 ton/year during quiescent period.  相似文献   

Statistical relationship between two types of El Niño events and climate variation over the Korean Peninsula   总被引：3，自引：0，他引：3  

Jong-Seong Kug  Min-Seop Ahn  Mi-Kyung Sung  Sang-Wook Yeh  Hong-Sik Min  Young-Ho Kim 《Asia-Pacific Journal of Atmospheric Sciences》2010,46(4):467-474

Recently, a new type of El Niño (Warm-Pool El Niño) is more often observed than the conventional El Niño (Cold-Tongue El Niño); each has a distinctive spatial pattern. The two types of El Niño have different teleconnections; therefore their impacts on a specific region can be considerably different. In this study, we focus on statistical relationship between climate variation in Korea and the two types of El Niño. When the two types of El Niño are not separately considered, the statistical relation between climate variables in Korea and the El Niño events is weak in general. When the two types of El Niño are separately considered, however, each type exhibits significant relationship with climate variation in Korea. Therefore, consideration of two types of El Niño separately can potentially improve climate prediction over the Korean Peninsula.  相似文献   

Age and Growth of Southern Bluefin Tuna,Thunnus maccoyii,Based on Otolith Microstructure     

Ku  Jeong Eun  Lee  Sung Il  Kim  Doo Nam 《Ocean Science Journal》2021,56(4):413-423

Ocean Science Journal - Age and growth of southern bluefin tuna (SBT, Thunnus maccoyii) were estimated based on otoliths collected by Korean tuna longline vessels in the Atlantic and Indian Oceans...  相似文献   

Real Data Assimilation Using the Local Ensemble Transform Kalman Filter (LETKF) System for a Global Non-hydrostatic NWP model on the Cubed-sphere     

Seoleun Shin  Jeon-Ho Kang  Hyoung-Wook Chun  Sihye Lee  Kwangjae Sung  Kyoungmi Cho  Youngsoon Jo  Jung-Eun Kim  In-Hyuk Kwon  Sujeong Lim  Ji-Sun Kang 《Asia-Pacific Journal of Atmospheric Sciences》2018,54(1):351-360

An ensemble data assimilation system using the 4-dimensional Local Ensemble Transform Kalman Filter is implemented to a global non-hydrostatic Numerical Weather Prediction model on the cubed-sphere. The ensemble data assimilation system is coupled to the Korea Institute of Atmospheric Prediction Systems Package for Observation Processing, for real observation data from diverse resources, including satellites. For computational efficiency in a parallel computing environment, we employ some advanced software engineering techniques in the handling of a large number of files. The ensemble data assimilation system is tested in a semi-operational mode, and its performance is verified using the Integrated Forecast System analysis from the European Centre for Medium-Range Weather Forecasts. It is found that the system can be stabilized effectively by additive inflation to account for sampling errors, especially when radiance satellite data are additionally used.  相似文献   

UBVI CCD photometry of M35 (NGC 2168)     

H. Sung †  M. S. Bessell † 《Monthly notices of the Royal Astronomical Society》1999,306(2):361-370

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Probabilistic corrosion rate estimation model for longitudinal strength members of bulk carriers     

Jeom Kee Paik  Sung Kyu Kim  Sang Kon Lee 《Ocean Engineering》1998,25(10):837-860

Many bulk carrier losses have been reported of late, and one of the possible causes of such casualties is thought to be the structural failure of aging hulls in rough weather. Clearly, in such cases, vessels that start out being adequate somehow become marginal later in life. Fatigue and corrosion-related potential problems may be the most important factors affecting such age related vessel damage. With respect to fatigue, extensive studies have been done worldwide both experimentally and theoretically, and the results have been applied to some extent. However, in the case of corrosion effects, additional research is still needed to better understand, clarify and address the various strength uncertainties and their effects on structural behaviour. This paper develops a probabilistic corrosion rate estimation model for the longitudinal strength members of bulk carriers. The model is based on available statistical data for corrosion of existing bulk carriers. The corrosion data collected are documented for future use.  相似文献