Major and trace element abundances in volcanic glass shards in visible tephras in SG93 and SG06 drillcore samples from Lake Suigetsu,central Japan,obtained using femtosecond LA–ICP–MS     

Seiji Maruyama  Keiji Takemura  Takafumi Hirata  Tohru Yamashita  Tohru Danhara 《第四纪科学杂志》2020,35(1-2):66-80

The major and trace element concentrations of volcanic glass shards from visible tephra layers in the SG93 and SG06 cores from Lake Suigetsu, central Japan, were determined by femtosecond laser ablation–inductively coupled plasma–mass spectrometry. The glass-shard analyses, together with the petrographic properties of the tephra samples, allow the Suigetsu tephra layers to be broadly classified into tephras derived from calderas on Kyushu Island, and from Daisen and Sambe volcanoes in the Chugoku district of southwest Japan. The layers correlated with tephras from Kuju caldera and Daisen volcano, and with the younger Sambe tephras, have adakitic elemental features. A Suigetsu tephra sample correlated with the Sambe−Kisuki tephra based on petrographic properties has an elemental pattern similar to that of the Toya tephra from Hokkaido Island, northeast Japan. This match implies that tephras from northeast Japan, as well as Kyushu–Chugoku tephras, are possible correlatives of the Suigetsu tephra layers. Both petrographic properties and major–trace element data of volcanic glass shards are essential for robust tephra correlations, and hierarchical cluster analysis proved additionally useful in statistically evaluating relationships among the tephras.  相似文献   

Respective influences of IOD and ENSO on the Tibetan snow cover in early winter   总被引：1，自引：0，他引：1  

Chaoxia Yuan  Tomoki Tozuka  Takafumi Miyasaka  Toshio Yamagata 《Climate Dynamics》2009,33(4):509-520

Using reanalysis data and snow cover data derived from satellite observations, respective influences of Indian Ocean Dipole (IOD) and El Niño/Southern Oscillation (ENSO) on the Tibetan snow cover in early winter are investigated. It is found that the snow cover shows a significant positive partial correlation with IOD. In the pure positive IOD years with no co-occurrences of El Niño, negative geopotential height anomalies north of India are associated with warm and humid southwesterlies to enter the plateau from the Bay of Bengal after rounding cyclonically and supply more moisture. This leads to more precipitation, more snow cover, and resultant lower surface temperature over the plateau. These negative geopotential height anomalies north of India are related to the equivalent barotropic stationary Rossby waves in the South Asian wave guide. The waves can be generated by the IOD-related convection anomalies over the western/central Indian Ocean. In contrast, in the pure El Niño years with no co-occurrences of the positive IOD, the anomalies of moisture supply and surface temperature over the plateau are insignificant, suggesting negligible influences of ENSO on the early winter Tibetan snow cover. Further analyses show that ENSO is irrelevant to the spring/early summer Tibetan snow cover either, whereas the IOD-induced snow cover anomalies can persist long from the early winter to the subsequent early summer.  相似文献   

A hydrocode calculation coupled with reaction kinetics of carbon compounds within an impact vapor plume and its implications for cometary impacts on Galilean satellites     

Ryo Ishimaru  Hiroki Senshu  Takafumi Matsui 《Icarus》2010,210(1):411-423

The synthesis of organic molecules via chemical reactions within impact vapor plumes has been proposed as a mechanism to supply organics on a planet. However, the kinetics of chemical reactions within a rapidly expanding vapor plume or quenching process of the reactions has not been studied extensively. In this study, we constructed a new numerical model that calculates kinetics of the entire chemical reactions within an impact vapor plume. Numerical results revealed that the semi-analytical models proposed so far, in which the final amount of a chemical species was given by the equilibrium abundance at the quenching temperature of the fastest reaction path involving the species, underestimates the yield of organic molecules, such as HCN, by up to a factor of 10. This is because the previously used assumption that a species can achieve equilibrium with the rest of the reaction system via the fastest reaction path involving the species is not necessarily valid. Our analysis of the high-temperature H/C/N/O reaction system suggests that the quenching of slow reactions divides the reaction network into smaller reaction sub-systems isolated from the rest of the reaction system. Then, the fastest reaction path cannot equilibrate an isolated reaction sub-system with the rest of the reaction system. Simulation of this actual disequilibrium mechanism requires a simultaneous numerical calculation of the entire reaction network, which is equivalent to conducting a full kinetic model calculation, such as our model. Our numerical code makes it possible to discuss quantitatively the impact chemistry for various situations, such as the Galilean satellites. In this study, our numerical model is applied to the delivery of organic molecules via cometary impact on the Galilean satellites. Our numerical results indicate that small-particle impacts would produce HCN efficiently. Resulting HCN may freeze out immediately and be deposited on satellite surfaces, where it may be eventually converted into complex organics via irradiation of charged particle. On the other hand, large-size impacts may form transient CH₄-N₂ atmospheres, in which complex organics (tholin) may be formed via energy deposition of UV and/or charged particle. Resulting complex organics may subsequently precipitate on the satellite surfaces without clear correlation with the locations of impact craters. Such distribution of complex organics created by chemical reactions within vapor plumes due to cometary impacts may explain an absorption (4.57 μm) on Galilean satellites nonassociated with observable (moderate- and large-size) impact craters.  相似文献   

The role of organic haze in Titan's atmospheric chemistry: II. Effect of heterogeneous reaction to the hydrogen budget and chemical composition of the atmosphere     

Yasuhito Sekine  Sébastien Lebonnois  Takafumi Matsui  Christopher P. McKay  Seiji Sugita 《Icarus》2008,194(1):201-211

One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C₄H₂ and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH₄ due to an episodic CH₄ release into Titan's atmosphere.  相似文献   

Sea water weathering effect on K-Ar age of submarine basalts     

Minoru Ozima  Kazuo Saito  Masahiko Honda  Sigeo Aramaki 《Geochimica et cosmochimica acta》1977,41(4):453-461

K-Ar dating and ⁴⁰Ar-³⁹Ar step heating experiments have been done for successive zones from the surface to the interior in two, altered dredged submarine basalts (16-2-6 and Aries V-23). The K contents show a systematic decrease (surface to the interior), whereas the K-Ar ages show a similar decrease in one sample (16-2-6) and almost no change in the other (Aries V-23).A simple diffusion model suggests that the K content decreases systematically from the surface to the interior, whereas the K-Ar age decreases or remains almost constant, depending on whether the times of solidification and of commencement of K-diffusion are close to each other or differ significantly. Comparison of the observed K content and K-Ar age variations within the rocks with the theoretical model then suggests that the solidification age of the sample Aries V-23 is much older than the commencement of the potassium-diffusion, the latter age perhaps being represented by the Eocene planktonic foraminifera on this sample. The ⁴⁰Ar-³⁹Ar isochron age obtained for the freshest specimen of Aries V-23 is 86.6 ± 3.7 m.y., supporting the above conclusion.The mathematical simulation indicates that an apparent concordance of the K-Ar age observed in some submarine basalts may be an artifact, only reflecting the significant gap between the solidification age and the time of the commencement of the K-diffusion in the rocks. Microprobe examination reveals that the potassium enrichment in the outer margin, is mainly due to K feldspar, which is an alteration product of plagioclase.  相似文献   

A Study on the Formation of Smectite in Silica Scales Precipitated from Geothermal Water: The Effect of Magnesium     

Yoshinobu Aramaki    Takushi Yokoyama  Yoshihiro Okaue  Akira Imai  Koichiro Watanabe 《Resource Geology》2005,55(3):281-284

Abstract. Silica scales containing large amounts of smectite were recently found in the pipelines for geothermal water at a geothermal power plant. To elucidate the mechanism of smectite formation, seven silica scale samples were characterized by powder X-ray diffraction, chemical analysis and ²⁷A1 MAS NMR. Smectite was present in samples with MgO levels above 10 wt% and Al₂O₃ levels below 10 wt%. In ²⁷A1 MAS NMR spectra, peaks assigned to both tetrahedrally and octahedrally coordinated aluminum (Al(4) and Al(6)) were observed for Mg-rich samples, whereas a peak due to Al(4) alone appeared in Mg-poor samples. From these observation and comparison between ²⁷A1 MAS NMR spectra for synthesized precipitates of Al₂O₃-SiO₂ containing MgO and not containing MgO, it is concluded that magnesium plays an important role in the stabilization of Al(6), and results in the formation of smectite  相似文献   

The Tsenkher structure in the Gobi-Altai, Mongolia: Geomorphological hints of an impact origin     

Goro Komatsu  John W. Olsen  Jens Orm  Gaetano Di Achille  David A. Kring  Takafumi Matsui 《Geomorphology》2006,74(1-4):164-180

The Tsenkher structure, in the Gobi-Altai region of Mongolia, was studied using a wide array of remote sensing data and field observations. The structure has a shallow, 3.6 km wide, central depression bordered by a near-circular ridge (putative crater rim) with breaches to the northwest. The central depression is obliterated partially by fluvial infill through these breaches. Outside the ridge, the western side is a rugged terrain, but the eastern half is characterized by a concentric outer ridge that occurs at about one radius distance from the inner ridge. Although intrusion, salt tectonics and maar crater hypotheses cannot be completely ruled out, its morphology strongly implies an impact origin for the Tsenkher structure. If of impact origin, it has a well-preserved morphology and its position in the basin fills indicates that the formation may have occurred relatively recently, sometime during the late Tertiary or Quaternary. The outer ridge morphology is similar to rampart craters on Mars, whose formation has been attributed to fluidization of a water-rich target layer and ejecta materials, or to atmospheric entrainment and deposition of ejected materials. However, other hypotheses including erosional remnant of ejecta blanket, erosional scarp of structural rim uplift, multi-ring or deeply eroded crater rim of a peak-ring crater are also possible at this stage. A complex fluvial and probable lacustrine history is envisaged within the Tsenkher structure. The structure is also associated with archaeology, including Paleolithic and Bronze Age remains.  相似文献   

Evolution of the composition of seawater through geologic time, and its influence on the evolution of life   总被引：2，自引：2，他引：0  

Tsuyoshi Komiya  Takafumi Hirata  Kouki Kitajima  Shinji Yamamoto  Takazo Shibuya  Yusuke Sawaki  Tomoko Ishikawa  Degan Shu  Yong Li  Jian Han 《Gondwana Research》2008,14(1-2):159

The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO₂ content (pCO₂) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO₂ condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO₂ through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.  相似文献   

柱端隔震夹层橡胶垫力学性能试验研究   总被引：3，自引：0，他引：3  

刘文光  周福霖  庄学真  加藤泰正  三山刚史  冯德民  郑炳辉  李峥嵘 《地震工程与工程振动》1999,19(3):121-126

本文详细地研究了夹层橡胶隔震垫的回转刚性,给出了回转刚性与竖向压力及切变形的相关性能。  相似文献   

A high‐T metamorphic complex derived from the high‐P Suo metamorphic complex in the Omuta district,northern Kyushu,southwest Japan          下载免费PDF全文

Kazuhiro Miyazaki  Takeshi Ikeda  Hirohisa Matsuura  Tohru Danhara  Hideki Iwano  Takafumi Hirata 《Island Arc》2017,26(5)

New U–Pb ages of zircons from migmatitic pelitic gneisses in the Omuta district, northern Kyushu, southwest Japan are presented. Metamorphic zonation from the Suo metamorphic complex to the gneisses suggests that the protolith of the gneisses was the Suo metamorphic complex. The zircon ages reveal the following: (i) a transformation took place from the high‐P Suo metamorphic complex to a high‐T metamorphic complex that includes the migmatitic pelitic gneisses; (ii) the detrital zircon cores in the Suo pelitic rocks have two main age components (ca 1900–1800 Ma and 250 Ma), with some of the detrital zircon cores being supplied (being reworked) from a high‐grade metamorphic source; and (iii) one metamorphic zircon rim yields 105.1 ±5.3 Ma concordant age that represents the age of the high‐T metamorphism. The high‐P to high‐T transformation of metamorphic complexes implies the seaward shift of a volcanic arc or a landward shift of the metamorphic complex from a trench to the sides of a volcanic arc in an arc–trench system during the Early Cretaceous. The Omuta district is located on the same geographical trend as the Ryoke plutono‐metamorphic complex, and our estimated age of the high‐T metamorphism is similar to that of the Ryoke plutono‐metamorphism in the Yanai district of western Chugoku. Therefore, the high‐T metamorphic complex possibly represents the western extension of the Ryoke plutono‐metamorphic complex. The protolith of the metamorphic rocks of the Ryoke plutono‐metamorphic complex was the Jurassic accretionary complex of the inner zone of southwest Japan. The high‐P to high‐T transformation in the Omuta district also suggests that the geographic trend of the Jurassic accretionary complex was oblique to that of the mid‐Cretaceous high‐T metamorphic field.  相似文献