排序方式： 共有43条查询结果，搜索用时 250 毫秒
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Yoshio Takahashi Tomoya Uruga Hajime Tanida Keiko H. Hattori 《Geochimica et cosmochimica acta》2007,71(21):5180-5190
Local atomic structures of Re and radiogenic Os in molybdenite from the Onganja mine, Namibia, were examined using X-ray absorption fine structure (XAFS). Rhenium LIII-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) show that the oxidation state of Re, the interatomic distances between Re and the neighboring atoms, and the coordination number of Re to S are very similar to those of Mo in molybdenite. The results confirm that Re is present as Re(IV) in the Mo site in molybdenite.Measurement of LIII-edge XANES and EXAFS of a minor concentration (8.55 ppm) of radiogenic Os was accomplished in fluorescence mode by removing the interfering X-rays from Re and other elements using a crystal analyzer system. The data indicate that the oxidation state of radiogenic Os is Os(III) and Os(IV) and clearly different from Os(II) in natural sulfide minerals, such as OsS2 (erlichmanite). XANES data also suggest that radiogenic Os does not form a secondary Os phase, such as OsS2 or Os metal, in molybdenite.EXAFS of radiogenic Os was successfully simulated assuming that Os is present in the Mo site in molybdenite. The data are consistent with the XANES data; Os does not form Os phases in molybdenite. The EXAFS simulation showed that the interatomic distance between Os and S is 2.27 Å, which is 0.12 Å smaller than the distances of Re-S and Mo-S (2.39 Å) in molybdenite. Similar valences and ionic sizes of Re and Mo in molybdenite support the fact that large amounts of Re can be incorporated into the Mo site as has been observed in previous studies, whereas the different properties of Os compared to Mo and Re suggested here support much lower abundance of common Os in molybdenite. This makes molybdenite an ideal mineral for the Re-Os geochronometer as shown in many studies. However, the shorter distance between radiogenic Os and S compared to those of Re-S and Mo-S in molybdenite suggests that the radiogenic Os has a smaller ionic size than Re(IV) and Mo(IV). Furthermore, Os may be partly present as Os(III). Smaller and lower charge Os can diffuse faster than larger and higher charge Re in molybdenite at a given set of conditions. Hence, our study provides an atomic-level explanation for the high mobility of Os compared to Re, which has been suggested by earlier workers using laser ablation ICP-MS. 相似文献
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A new technique for detecting colored macro plastic debris on beaches using webcam images and CIELUV 总被引：1，自引：0，他引：1
We have developed a technique for detecting the pixels of colored macro plastic debris (plastic pixels) using photographs taken by a webcam installed on Sodenohama beach, Tobishima Island, Japan. The technique involves generating color references using a uniform color space (CIELUV) to detect plastic pixels and removing misdetected pixels by applying a composite image method. This technique demonstrated superior performance in terms of detecting plastic pixels of various colors compared to the previous method which used the lightness values in the CIELUV color space. We also obtained a 10-month time series of the quantity of plastic debris by combining a projective transformation with this technique. By sequential monitoring of plastic debris quantity using webcams, it is possible to clean up beaches systematically, to clarify the transportation processes of plastic debris in oceans and coastal seas and to estimate accumulation rates on beaches. 相似文献
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Natural Hazards - To: Street-scale storm. 相似文献
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Assessment of digital camera-derived vegetation indices in quantitative monitoring of seasonal rice growth 总被引：4，自引：0，他引：4
Toshihiro Sakamoto Michio Shibayama Akihiko Kimura Eiji Takada 《ISPRS Journal of Photogrammetry and Remote Sensing》2011,66(6):872-882
A commercially available digital camera can be used in a low-cost automatic observation system for monitoring crop growth change in open-air fields. We developed a prototype Crop Phenology Recording System (CPRS) for monitoring rice growth, but the ready-made waterproof cases that we used produced shadows on the images. After modifying the waterproof cases, we repeated the fixed-point camera observations to clarify questions regarding digital camera-derived vegetation indices (VIs), namely, the visible atmospherically resistant index (VARI) based on daytime normal color images (RGB image) and the nighttime relative brightness index (NRBINIR) based on nighttime near infrared (NIR) images. We also took frequent measurements of agronomic data such as plant length, leaf area index (LAI), and aboveground dry matter weight to gain a detailed understanding of the temporal relationship between the VIs and the biophysical parameters of rice. In addition, we conducted another nighttime outdoor experiment to establish the link between NRBINIR and camera-to-object distance. The study produced the following findings. (1) The customized waterproof cases succeeded in preventing large shadows from being cast, especially on nighttime images, and it was confirmed that the brightness of the nighttime NIR images had spatial heterogeneity when a point light source (flashlight) was used, in contrast to the daytime RGB images. (2) The additional experiment using a forklift showed that both the ISO sensitivity and the calibrated digital number of the NIR (cDNNIR) had significant effects on the sensitivity of NRBINIR to the camera-to-object distance. (3) Detailed measurements of a reproductive stem were collected to investigate the connection between the morphological feature change caused by the panicle sagging process and the downtrend in NRBINIR during the reproductive stages. However, these agronomic data were not completely in accord with NRBINIR in terms of the temporal pattern. (4) The time-series data for the LAI, plant length, and aboveground dry matter weight could be well approximated by a sigmoid curve based on NRBINIR and VARI. The results confirmed that NRBINIR was more sensitive to all of the agronomic data for overall season, including the early reproductive stages. VARI had an especially high correlation with LAI, unless yellow panicles appeared in the field of view. 相似文献
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Soltanpour Mohsen Shamsnia S. Hadi Shibayama Tomoya Nakamura Ryota 《Ocean Dynamics》2020,70(2):165-186
Ocean Dynamics - Although the different aspects of wave-mud interaction have been studied by many researchers, few studies have been conducted on the effect of solitary wave on the particle... 相似文献
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A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO2 and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm2) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction. 相似文献
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The present study offers a two-dimensional horizontal wave propagation and morphodynamic model for muddy coasts. The model can be applied on a general three-dimensional bathymetry of a soft muddy coast to calculate wave damping, fluid mud mass transport and resulting bathymetry change under wave actions. The wave propagation model is based on time-dependent mild slope equations including the wave energy dissipation due to the wave-mud interaction of bottom mud layers as well as the combined effects of the wave refraction, diffraction and breaking. The constitutive equations of the visco-elastic–plastic model are adopted for the rheological behavior of fluid mud. The mass transport velocity within the fluid mud layer is calculated combining the Stokes’ drift, the mean Eulerian velocity and the gravity-driven mud flow. The results of the numerical model are compared against a series of conducted wave basin experiments, wave flume experiments and field observations. Comparisons between the computed results with both the field and laboratory data reveal the capability of the proposed model to predict the wave transformation and mud mass transport. 相似文献