Diffuse volcanic degassing and thermal energy release from Hengill volcanic system, Iceland     

Pedro A. Hernández  Nemesio M. Pérez  Thráinn Fridriksson  Jolie Egbert  Evgenia Ilyinskaya  Andri Thárhallsson  Gretar ívarsson  Gestur Gíslason  Ingvi Gunnarsson  Birgir Jónsson  Eleazar Padrón  Gladys Melián  Toshiya Mori  Kenji Notsu 《Bulletin of Volcanology》2012,74(10):2435-2448

We report the first detailed study of spatial variations on the diffuse emission of carbon dioxide (CO₂) and hydrogen sulfide (H₂S) from Hengill volcanic system, Iceland. Soil CO₂ and H₂S efflux measurements were performed at 752 sampling sites and ranged from nondetectable to 17,666 and 722?g?m^?2?day^?1, respectively. The soil temperature was measured at each sampling site and used to evaluate the heat flow. The chemical composition of soil gases sampled at selected sampling sites during this study shows they result from a mixing process between deep volcanic/hydrothermal component and air. Most of the diffuse CO₂ degassing is observed close to areas where active thermal manifestations occur, northeast flank of the Hengill central volcano close to the Nesjavellir power plant, suggesting a diffuse degassing structure with a SSW?CNNE trend, overlapping main fissure zone and indicating a structural control of the degassing process. On the other hand, H₂S efflux values are in general very low or negligible along the study area, except those observed at the northeast flank of the Hengill central volcano, where anomalously high CO₂ efflux and soil temperatures were also measured. The total diffuse CO₂ emission estimated for this volcanic system was about 1,526?±?160?t?day^?1 of which 453?t?day^?1 (29.7?%) are of volcanic/hydrothermal origin. To calculate the steam discharge associated with the volcanic/hydrothermal CO₂ output, we used the average H₂O/CO₂ mass ratio from 12 fumarole samples equal to 88.6 (range, 9.4?C240.2) as a representative value of the H₂O/CO₂ mass ratios for Hengill fumarole steam. The resulting estimate of the steam flow associated with the gas flux is equal to 40,154?t?day^?1. The condensation of this steam results in thermal energy release for Helgill volcanic system of 1.07?×?10¹⁴?J?day^?1 or to a total heat flow of 1,237?MW_t.  相似文献   

A preparation zone for volcanic explosions beneath Naka-dake crater,Aso volcano,as inferred from magnetotelluric surveys     

Wataru Kanda  Yoshikazu Tanaka  Mitsuru Utsugi  Shinichi Takakura  Takeshi Hashimoto  Hiroyuki Inoue 《Journal of Volcanology and Geothermal Research》2008

The 1st crater of Naka-dake, Aso volcano, is one of the most active craters in Japan, and known to have a characteristic cycle of activity that consists of the formation of a crater lake, drying-up of the lake water, and finally a Strombolian-type eruption. Recent observations indicate an increase in eruptive activity including a decrease in the level of the lake water, mud eruptions, and red hot glows on the crater wall. Temporal variations in the geomagnetic field observed around the craters of Naka-dake also indicate that thermal demagnetization of the subsurface rocks has been occurring in shallow subsurface areas around the 1st crater. Volcanic explosions act to release the energy transferred from magma or volcanic fluids. Measurement of the subsurface electrical resistivity is a promising method in investigating the shallow structure of the volcanic edifices, where energy from various sources accumulates, and in investigating the behaviors of magma and volcanic fluids. We carried out audio-frequency magnetotelluric surveys around the craters of Naka-dake in 2004 and 2005 to determine the detailed electrical structure down to a depth of around 1 km. The main objective of this study is to identify the specific subsurface structure that acts to store energy as a preparation zone for volcanic eruption. Two-dimensional inversions were applied to four profiles across the craters, revealing a strongly conductive zone at several hundred meters depth beneath the 1st crater and surrounding area. In contrast, we found no such remarkable conductor at shallow depths beneath the 4th crater, which has been inactive for 70 years, finding instead a relatively resistive body. The distribution of the rotational invariant of the magnetotelluric impedance tensor is consistent with the inversion results. This unusual shallow structure probably reflects the existence of a supply path of high-temperature volcanic gases to the crater bottom. We propose that the upper part of the conductor identified beneath the 1st crater is mainly composed of hydrothermally altered zone that acts both as a cap to upwelling fluids supplied from deep-level magma and as a floor to infiltrating fluid from the crater lake. The relatively resistive body found beneath the 4th crater represents consolidated magma. These results suggest that the shallow conductor beneath the active crater is closely related to a component of the mechanism that controls volcanic activity within Naka-dake.  相似文献   

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS     

Ze‐Hua Liu  Takeshi Hashimoto  Yoichi Okumura  Yoshinori Kanjo  Satoshi Mizutani 《洁净——土壤、空气、水》2010,38(2):181-188

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.  相似文献   

A unique, (almost) unaltered spinel-rich fine-grained inclusion in Kainsaz     

B. B. Holmberg  A. Hashimoto 《Meteoritics & planetary science》1992,27(2):149-153

Abstract We report a unique, spinel-rich, extremely porous fine-grained inclusion in the Kainsaz (CO3) meteorite. This inclusion is the least altered fine-grained inclusion yet discovered, having escaped almost entirely the secondary alterations experienced by Allende fine-grained inclusions. The inclusion is comprised of loosely packed 5–30 μm spinel grains mantled by thin layers of melilite, anorthite, and diopsidic pyroxene. The inclusion, which has over 30 vol% void space, is one of the most spinel-rich, most porous fine-grained inclusions seen to date. The mineralogy of the inclusion matches that which has been predicted for a precursor of the altered mineral assemblages of Allende fine-grained inclusions, though a lack of interstitial material in the Kainsaz inclusion reduces the likelihood of a direct genetic relationship between the two (Allende fine-grained inclusions contain abundant interstitial material). Its mineralogical composition confirms that the precursors of other, more altered, fine-grained inclusions were assemblages of refractory minerals exclusively.  相似文献   

Isophot Mapping Observations of a Mira-Type AGB Star R Hya     

O. Hashimoto  H. Izumiura 《Astrophysics and Space Science》1997,255(1-2):349-350

Far-infrared mapping observations of a Mira-type AGB star R Hya were carried out with the imaging photo-polarimeter ISOPHOT. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

ISO-SWS Observations of the Time Variability of Oxygen-righ Mira Variables     

T. Onaka  I. Yamamura  T. de Jong  T. Tanabé  O. Hashimoto  H. Izumiura 《Astrophysics and Space Science》1997,255(1-2):331-337

We present the first observation of variation of the infrared spectrum of circumstellar dust emission around an oxygen-rich Mira variable star, Z Cyg, over an entire light variation cycle, based on the periodic SWS01 observations. The 10 μm and 20 μm ‘silicate features’ become stronger relative to the photospheric emission at maximum that at minimum. In addition, the relative intensity of the 10 μm to the 20 μm features increases at maximum, indicating an increase of the temperature of circumstellar dust grain. A simple model analysis suggests enhanced dust formation near the photosphere around maximum, leading to a scenario that dust nucleation may have occurred near minimum and the dust grains may have subsequently grown till maximum. The strong observed variation suggests that the variability must be taken into account in the interpretation of the infrared spectra of oxygen-rich Mira variables. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Tectonic incorporation of the upper part of oceanic crust to overriding plate of a convergent margin: An example from the Cretaceous–early Tertiary Mugi Mélange, the Shimanto Belt, Japan     

Eisei Ikesawa  Gaku Kimura  Katsushi Sato  Kotoe Ikehara-Ohmori  Yujin Kitamura  Asuka Yamaguchi  Kohtaro Ujiie  Yoshitaka Hashimoto   《Tectonophysics》2005,401(3-4):217-230

A tectonic mélange exposed on land is examined to reveal relationships between mélange formation, underplating, and deformation mechanisms, focusing on the deformation of basaltic rocks. The studied Mugi Mélange of the Shimanto Belt is composed of a shale matrix surrounding various blocks of sandstone, pelagic sediments, and basalts. The mélange was formed during Late Cretaceous to early Tertiary times in a subduction zone under P–T conditions of 150–200 °C and 6–7 km depth as estimated from vitrinite reflectance and quartz veins fluid inclusions. The mélange represents a range of deformation mechanisms; pressure solution with micro-scale cataclasis in the shale matrix, brittle tension cracking in the blocks, and ubiquitous strong cataclasis in the basal portion of basaltic layers. The cataclastic deformation in the basalts suggests a breakage of a topographic high in the seismogenic depth.  相似文献