Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition     

G. M. da Costa  E. Van San  E. De Grave  R. E. Vandenberghe  V. Barrón  L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.  相似文献   

Crack damage stress as a composite function of porosity and elastic matrix stiffness in dolomites and limestones   总被引：4，自引：0，他引：4  

V. Palchik  Y. H. Hatzor 《Engineering Geology》2002,63(3-4):233-245

Twenty-five uniaxial compression tests were performed to determine stress at onset of dilation, referred to herein as “the crack damage stress,” in heterogeneous dolomites and limestones. A simplified model for crack damage stress (σ_cd) is developed here using porosity, elastic modulus, Poisson's ratio and three empirical coefficients. The model shows that when porosity decreases and elastic modulus increases, σ_cd rapidly increases and approaches its maximum value. On the other hand, when porosity increases and elastic modulus decreases, σ_cd rapidly decreases and approaches its minimum value. The proposed model is validated for six heterogeneous limestone and dolomite formations which are widely distributed in Israel.  相似文献   

The Port Mouton Shear Zone: intersection of a regional fault with a crystallizing granitoid pluton   总被引：2，自引：0，他引：2  

D. Barrie Clarke  Krista L. McCuish  Ron H. Vernon  Victor Maksaev  Brent V. Miller   《Lithos》2002,61(3-4):141-159

The peraluminous tonalite–monzogranite Port Mouton Pluton is a petrological, geochemical, structural, and geochronological anomaly among the many Late Devonian granitoid intrusions of the Meguma Lithotectonic Zone of southern Nova Scotia. The most remarkable structural feature of this pluton is a 4-km-wide zone of strongly foliated (040/subvertical) monzogranites culminating in a narrow (10–30 m), straight, zone of compositionally banded rocks that extends for at least 3 km along strike. The banded monzogranites consist of alternating melanocratic and leucocratic compositions that are complementary to the overall composition of that part of the pluton, suggesting an origin by mineral–melt and mineral–mineral sorting. Biotite and feldspar are strongly foliated in the plane of the compositional bands. These compositional variations and foliations originated by a process of segregation flow during shearing of the main magma with a crystallinity of 55–75%. Subsequent minor brittle fracturing of feldspars, twinning of microcline, development of blocky sub-grains in quartz, and kinking of micas demonstrate overprinting by a high-temperature deformation straddling the monzogranite solidus. Small folds and late sigmoidal dykes indicate dextral movement on the shear zone. This Port Mouton Shear Zone (PMSZ) is approximately co-linear with the only outcrops of Late Devonian mafic intrusions in the area, two of which are syn-plutonic with well-developed mingling textures in the marginal tonalite of the Port Mouton Pluton. Also closely co-linear with the mafic intrusions are a granitoid dyke that extends well beyond the outer contact of the Port Mouton Pluton, a swarm of large aligned angular xenolithic slabs, a zone of thin wispy schlieren banding, a large Be-bearing pegmatite, and a breccia pipe with abundant garnetiferous metapelitic xenoliths. In various ways, the shear zone may control all of these features. The Port Mouton Shear Zone is parallel to many other NE-trending faults and shear zones in the northern Appalachians, probably related to the docking of the Meguma Zone along the Cobequid–Chedabucto Fault system.  相似文献   

Environmental response to a large, explosive rhyolite eruption: sedimentology of post-1.8 ka pumice-rich Taupo volcaniclastics in the Hawke''s Bay region, New Zealand     

B. Segschneider  C. A. Landis  V. Manville  J. D. L. White  C. J. N. Wilson 《Sedimentary Geology》2002,150(3-4):275-299

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Confinement Effects and Energy Balance Analyses for Buckling Failure Under Eccentric Loading Conditions     

V. N. Kazakidis 《Rock Mechanics and Rock Engineering》2002,35(2):115-126

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Heavy metal concentrations in surficial sediments from accreting and eroding areas along the coast of Guyana   总被引：1，自引：0，他引：1  

V. Lakhan  K. Cabana  P. LaValle 《Environmental Geology》2002,42(1):73-80

. Surficial sediments sampled from accreting and eroding areas along the coast of Guyana were examined for concentrations of heavy metals; aluminum, copper, chromium, iron, nickel, lead, vanadium and zinc. Twenty-four samples were collected, 12 from each of the eroding and accreting areas. For granulometric composition determination, samples were separated into particle-size fractions using sieving and hydrometer procedures. The consideration of three grain-size fractions (4.0, 5.0, and greater than 5.0 phi), plus 24 bulk samples less than 4.0 phi in diameter, required analyzing a total of 96 samples for the presence of heavy metals. The analysis employed was aquaregia digestion, followed by inductively coupled plasma optical emission spectroscopy. The statistical techniques of discriminant analysis, analysis of variance, and correlation and regression were used to analyze all obtained data. Discriminant analysis revealed that metal concentrations were statistically unique to each area. From the analysis of variance, and correlation and regression, it was discovered that the grain size of the sediment had a pronounced effect on the spatial distribution of heavy metals. The accreting area, with finer sediments, accumulated higher concentrations of heavy metals.  相似文献   

The effect of acoustic waves on spectral-line profiles in the solar atmosphere: Observations and theory     

R. I. Kostyk  E. V. Khomenko 《Astronomy Reports》2002,46(11):925-931

The fine structure of the FeI λ 532.4185-nm line of neutral iron is studied with high spatial (0.5″) and temporal (9.3 s) resolution using observations of a quiet region at the center of the solar disk. The character of the line asymmetry depends strongly on the nature of the velocity field, i.e., on whether it is due to convective or wave motions. The magnitude of the asymmetry due to acoustic waves is comparable to that due to convective motions. The propagation of acoustic waves in moving granules and intergranular lanes is studied by solving a system of hydrodynamical equations in a three-dimensional model for the solar atmosphere. The temporal variations in the bisector of the line synthesized in a non-LTE approximation agree well with the observational data.  相似文献   

Disk wind in young binaries and its impact on the infrared excesses of young stars     

V. P. Grinin 《Astronomy Reports》2002,46(5):380-389

We consider the effect of binarity of young stars on the spectral energy distribution of the IR radiation from circumstellar dust. The formation of a common dust envelope in a binary system with a low-mass secondary component is strongly affected by the disk wind from the secondary. The small velocities in peripheral areas of the wind are such that it can be partially or entirely captured by the primary, even when the distance between the components is up to several astronomical units. As a result, an envelope with a rather complex spatial and kinematic structure is formed. Its mass is many orders of magnitude smaller than that of the accretion disk around the binary. However, the thermal radiation emitted by dust particles of the envelope can be comparable to the total radiation of the accretion disk. This result is discussed in the context of the deficit at near-IR wavelengths (2–10µm) in current models for accretion disks around young stars.  相似文献   

A Model for the polar motion of the deformable Earth adequate for astrometric data     

L. D. Akulenko  S. A. Kumakshev  Yu. G. Markov  L. V. Rykhlova 《Astronomy Reports》2002,46(1):74-82

Refined analytical expressions for the frequencies corresponding to the Chandler motion of the pole and the diurnal rotation of the deformable Earth are derived. Numerical estimates of the period and amplitude of the polar oscillations are presented. The trajectory of the Chandler polar motion derived via numerical modeling is in qualitative and quantitative agreement with experimental data from the International Earth Rotation Service (IERS). An evolutionary model describing slow variations in the Earth’s rotation parameters under the action of the dissipative moments of the tidal gravitational forces on time scales considerably longer than the precession period of the Earth’s axis is constructed. The axis of the Earth’s figure tends to approach the angular momentum vector of the proper rotation.  相似文献   

Modeling groundwater-surface water interactions including effects of morphogenetic depressions in the Chernobyl exclusion zone   总被引：1，自引：0，他引：1  

A. Bixio  G. Gambolati  C. Paniconi  M. Putti  V. Shestopalov  V. Bublias  A. Bohuslavsky  N. Kasteltseva  Y. Rudenko 《Environmental Geology》2002,42(2-3):162-177

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