Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

Simultaneous radio and optical observations of the mid-latitude atmospheric response to a major geomagnetic storm of 6–8 April 2000     

E. L. Afraimovich  Ya. F. Ashkaliev  V. M. Aushev  A. B. Beletsky  V. V. Vodyannikov  L. A. Leonovich  O. S. Lesyuta  Yu. V. Lipko  A. V. Mikhalev  A. F. Yakovets 《Journal of Atmospheric and Solar》2002,64(18)

Basic properties of the mid-latitude traveling ionospheric disturbances (TIDs) during the maximum phase of a major magnetic storm of 6–8 April 2000 are shown. Total electron content (TEC) variations were studied by using data from GPS receivers located in Russia and Central Asia. The nightglow response to this storm at mesopause and termospheric altitudes was also measured by optical instruments FENIX located at the observatory of the Institute of Solar-Terrestrial Physics (51.9°N,103.0°E), and MORTI located at the observatory of the Institute of Ionosphere (43.2°N, 77.0°E). Observations of the O (557.7 and 630.0 nm) emissions originating from atmospheric layers centered at altitudes of 90 and 250 km were carried out at Irkutsk and of the O₂(b¹∑_g⁺−X³∑_g⁻) (0-1) emission originating from an atmospheric layer centered at altitude of 94 km was carried out at Almaty. Our radio and optical measurement network observed a storm-induced solitary large-scale wave with duration of 1 h and a wave front width of no less than 5000 km, while it traveled equatorward with a velocity of 200 m/s from 62°N to 38°N geographic latitude. The TEC disturbance, basically displaying an electron content depression in the maximum of the F2 region, reveals a good correlation with growing nightglow emission, the temporal shift between the TEC and emission variation maxima being different for different altitudes. A comparison of the auroral oval parameters with dynamic spectra of TEC variations and optical 630 nm emissions in the frequency range 0.4–4 mHz (250–2500 s periods) showed that as the auroral oval expands into mid-latitudes, also does the region with a developed medium-sale and small-scale TEC structure.  相似文献   

Where did rotational shortening occur in the Himalayas? - Inferences from palaeomagnetic remagnetisations     

E. Schill  C. CrouzetP. Gautam  V.K. SinghE. Appel 《Earth and Planetary Science Letters》2002,203(1):45-57

In metacarbonates of the Lesser (LH) and Tethyan (TH) Himalayas of Kumaon/Garhwal (N-India) characteristic remanent magnetisations carried by pyrrhotite (unblocking temperatures: 250-330°C) and magnetite (demagnetising spectra: 15-50 mT) have been identified. Negative fold tests indicate remanence acquisition after the main folding phase, which is of short-wavelength character and occurs during the early orogenese of the Himalayas. A thermal or thermochemical origin of magnetisation is likely and the age of remanence acquisition is indicated to be about 40 Ma by ⁴⁰K/³⁹Ar cooling and ⁴⁰Ar/³⁹Ar crystallisation ages. In the Kumaon LH a long-wavelength tilting is indicated by a distribution of the remanence directions along a small-circle in N-S direction. Steepening of the remanence directions in the TH related to ramping on the Main Central Thrust (MCT) was not observed, in contrast to other related studies. In the Alaknanda valley of LH a 38±8 Ma age of remanence acquisition is supported by comparison of observed inclinations to the apparent polar wander path of India. Clockwise rotation of 20.3±11.7° (LH/Alaknanda valley) and 11.3±8.5° (TH) with respect to the Indian plate is observed, indicating that there is no significant evidence for rotational shortening along the MCT since about 40 Ma. Our results suggest that most of rotational underthrusting and oroclinal bending has not been accommodated by the MCT, but by the main thrusts south of it. The latest Miocene/Pliocene age of the Main Boundary Thrust indicates that oroclinal bending is a late-orogenic process.  相似文献   

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater     

Padinare V. Unnikrishna  Jeffrey J. McDonnell  Carol Kendall   《Journal of Hydrology》2002,260(1-4):38-57

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.  相似文献   

Studying Thermal Eutrophication in Cooling Reservoirs of Nuclear Power Plants     

Beznosov  V. N.  Kuchkina  M. A.  Suzdaleva  A. L. 《Water Resources》2002,29(5):561-566

The processes of thermal eutrophication of the cooling reservoirs of the Smolensk and Kursk nuclear power plants (NPP) were studied. Data characterizing changes in the concentrations of inorganic forms of nitrogen and phosphates in water during its heating in the NPP cooling system were obtained. Different aspects of the effect of heated water on the production–destruction processes are discussed. The conditions under which the intensity of thermal eutrophication can substantially increase were determined.  相似文献   

Structural Variations of Bottom Sediments in the Rybinsk Reservoir     

Zakonnov  V. V.  Poddubnyi  S. A. 《Water Resources》2002,29(2):181-190

Long-standing variations in the structure of bottom sediments within typical habitats of the aquatic life are characterized using the Volzhskii Pool of the Rybinsk Reservoir as an example. The role of hydrodynamic processes of the littoral zone in the formation of the ground complex of shallow water areas of the pool is discussed. The trends in variation in the quality of bottom substrate in fish habitats are analyzed. The peculiarities of long-standing variations in the distribution of types of bottom sediments in the entire reservoir are shown.  相似文献   

Analysis of Space and Time Variations in the Suspended Matter Distribution in Kaliningrad Bay of the Baltic Sea     

Chechko  V. A. 《Water Resources》2002,29(4):388-395

The distribution of suspension, its composition, and particle size characteristics are studied in Kaliningrad Bay. Zoning of the bay according to the water turbidity is made. The main factors controlling the formation and space and time variations in the suspended matter are determined.  相似文献   

The Hydrological Regime and the Peculiarities of Formation of the Po River Delta     

Mikhailova  M. V. 《Water Resources》2002,29(4):370-380

The peculiarities of the hydrological regime of the delta and near-shore zone of the Po River are discussed. The intrusion of salt seawater into the delta is described. The history of the Po Delta formation has been restored on the basis of the analysis of historical, archeological, and cartographic data. As shown, the peculiarities of hydrological and morphological processes in the Po River mouth are associated with natural and specifically with human-induced variations in sediment runoff of the river, with levee construction along branches, subsidence of deltaic deposits, and eustatic rise of the sea level.  相似文献   

Probabilistic Estimates of Water Level in the Ural River Mouth Reach at Interaction between the River Runoff and Positive Setups     

Polonskii  V. F.  Ostroumova  L. P. 《Water Resources》2002,29(5):497-505

A probabilistic technique is developed for assessing water level in the mouth reach of the Ural River in the course of interaction between the river runoff and irregular rises in the Caspian Sea level (positive setups) at the predicted background sea levels of –26.5 and –26.0 m abs.  相似文献   

Moment Tensor Inversion of Regional Phases: Application to a Mine Collapse     

V. Teyssoneyre  B. Feignier  J. Šilény  O. Coutant 《Pure and Applied Geophysics》2002,159(1-3):111-130

—?The aim of our study consists of analyzing potentially non-double-couple seismic events recorded at regional distances. In order to define the nature of the seismic source, a moment tensor inversion is carried out as this method is general enough not to initially constrain the source mechanism. In this paper we present an application to a seismic event induced by a mine collapse which occurred near the town of Halle in Germany. Because of its induced nature, many parameters such as the location and geometry of this seismic source are known. This information allows us to test the influence of inadequate propagation modeling on the moment tensor obtained from the inversion. Green's functions have been computed with the reflectivity method in a flat layered medium, using the European model EurID (Du et? al., 1998; Dufumier et al., 1997). From the inversion of P-wave seismograms recorded by the German Regional Seismic Network will, we obtained a source time function which can be decomposed into two subevents. The first one has a large isotropic part and a deviatoric mechanism with near vertical nodal planes. No volume change is observed for the second subevent, but a deviatoric component opposite of the first one. The addition of S-waves does not change the results of the inversion which are stable. Surface waves were not used because of their poor dispersion curves. Based on the moment tensor obtained from these inversions, the physical process at the source is compatible with a large cavity collapse.  相似文献