Chemical availability of arsenic and heavy metals in sediments from abandoned cinnabar mine tailings   总被引：1，自引：1，他引：0  

Raquel Larios  Rodolfo Fernández-Martínez  Verónica Silva  Isabel Rucandio 《Environmental Earth Sciences》2013,68(2):535-546

The understanding of the solid-phase speciation of arsenic in soils and sediments is important in the evaluations of its potential mobility and availability in the environment. The spoil heaps of abandoned mercury mines contain waste materials with high arsenic and heavy metals concentrations. The weathering of these tailings can cause their mobilization to the surroundings. In this work, the mobility and availability of arsenic and some heavy metals were evaluated in sediments from two heavily polluted mercury mining districts in Asturias (NW Spain). For this purpose, a slightly modified version of the Bureau Community of Reference sequential extraction scheme was applied to sediments. The total contents in the operationally defined fractions were analysed by inductively coupled plasma-atomic emission spectrometry. Extremely high total arsenic concentrations were found in all sediments ranging from 4,000 to 24,800 mg kg^?1. High easily mobilizable arsenic contents were found in the first mining area, related to the solubilization of Ca-bearing phases, supported by extracts analyses, X-ray diffraction results and the positive correlation found among the As and Ca fractionations. Ni and Zn were the most mobile among heavy metals, being Cr the least mobile, suggesting an anthropogenic origin due to the metallurgical processes, transport or dispersion generated from neighbour spoil heaps. In the second mining area, the bulk of As was concentrated in the residual phase, as well as Cr, Cu, Fe, Pb, Ti, indicating a mineralogical origin and the low availability of these elements. The strong correlations established between As and Fe and Ti distributions support the hypothesis that As is mainly associated to structural mineral phases in these sediments.  相似文献   

Century-scale nitrogen and phosphorus controls of the carbon cycle     

Fred T. Mackenzie  Leah May Ver  Abraham Lerman 《Chemical Geology》2002,190(1-4):13-32

In recent decades, humans have become a very important force in the Earth system, demonstrating that emissions (gaseous, liquid, and solid) are the cause of many of our environmental issues. These emissions are responsible for major global reorganizations of the biogeochemical cycles. The oceans are now a net sink of atmospheric CO₂, whereas in their preindustrial state they were a source; the trophic state of the coastal oceans is progressively moving toward increased heterotrophy; and the terrestrial realm is now vacillating between trophic states, whereas in preindustrial times it was autotrophic. In this paper, we present model calculations that underscore the role of human-induced perturbations in changing Earth's climate, specifically the role of anthropogenic nitrogen and phosphorus in controlling processes in the global carbon cycle since the year 1850 with projections to the year 2035. Our studies show that since the late 1940's emissions of nitrogen and phosphorus have been sequestered in the terrestrial living phytomass and groundwater. This nutrient-enhanced fertilization of terrestrial biota, coupled with rising atmospheric CO₂ and global temperature, has induced a sink of anthropogenic CO₂ that roughly balances the emission of CO₂ owing to land use change. In the year 2000, for example, the model-calculated terrestrial biotic sink was 1730 Mtons C/year, while the emission of CO₂ from changes in land use was 1820 Mtons C/year, a net flux of 90 Mtons C/year emitted to the atmosphere. In the global aquatic environment, enhanced terrestrial inputs of biotically reactive phosphorus (about 8.5 Mtons P/year) and inorganic nitrogen (about 54 Mtons N/year), have induced increased new production and burial of organic carbon in marine sediments, which is a small sink of anthropogenic CO₂. It is predicted that the response of the global land reservoirs of C, N, and P to sustained anthropogenic perturbations will be maintained in the same direction of change over the range of projected scenarios of global population increase and temperature change for the next 35 years. The magnitude of change is significantly larger when the global temperature increase is maximum, especially with respect to the processes of remobilization of the biotically important nutrients nitrogen and phosphorus.  相似文献   

Relations of field line resonances and upstream waves and the winter attenuation of pulsations     

J. Ver  H{o}  I. Best  M. Vellante  H. Lühr  M. de Lauretis  L. Holló  F. Märcz  J. Str  ues  utik 《Annales Geophysicae》1995,13(7):689-697

Using data on the occurrence frequency of geomagnetic pulsations of different periods from three observatories in Central Europe, conclusions are drawn about the occurrence of field line resonances and pulsations directly driven by upstream waves at L-values below 3. It was found that both types occur during the interval studied (first 6 months of the year 1991), but both the occurrence frequency of the two types and the characteristic period of the field line resonance change significantly as compared to other intervals. During Northern winter, pulsation activity is severely damped in solar maximum years, including the year 1991. The decrease in the activity of the pulsations is more significant at shorter periods.  相似文献   

Multivariable spatial prediction   总被引：1，自引：0，他引：1  

Jay M. Ver Hoef  Noel Cressie 《Mathematical Geology》1993,25(2):219-240

For spatial prediction, it has been usual to predict one variable at a time, with the predictor using data from the same type of variable (kriging) or using additional data from auxiliary variables (cokriging). Optimal predictors can be expressed in terms of covariance functions or variograms. In earth science applications, it is often desirable to predict the joint spatial abundance of variables. A review of cokriging shows that a new cross-variogram allows optimal prediction without any symmetry condition on the covariance function. A bivariate model shows that cokriging with previously used cross-variograms can result in inferior prediction. The simultaneous spatial prediction of several variables, based on the new cross-variogram, is then developed. Multivariable spatial prediction yields the mean-squared prediction error matrix, and so allows the construction of multivariate prediction regions. Relationships between cross-variograms, between single-variable and multivariable spatial prediction, and between generalized least squares estimation and spatial prediction are also given.  相似文献   

Bulge Migration and Pinnacle Reef Development, Devonian Appalachian Foreland Basin     

Ver Straeten CA  Brett CE 《The Journal of geology》2000,108(3):339-352

Detailed stratigraphic analyses of Late Emsian and Early Eifelian (Lower to Middle Devonian) carbonate-dominated strata in the northern Appalachian Basin indicate anomalous, locally varying relative sea level changes and inversions of topography. The distribution of a major basal-bounding unconformity, basinal pinnacle reefs, local absence of parasequences, and eastward migration of shallow marine carbonate lithofacies and related biofacies in the Onondaga Limestone and underlying strata mark the retrograde migration of an elongate, northeast-southwest-trending area of positive relief, bordered on its cratonward side by a similarly migrating basin of intermediate depth. These features are thought to represent the forebulge and back-bulge basin of the Appalachian foreland basin system as it developed during a time of relative quiescence within the Acadian Orogeny. However, the relatively small size of the bulgelike feature (ca. 80-100-km-wide, 20-50-m positive relief), its great distance from the probable deformation front (>400 km), and the lack of a well-developed foredeep immediately adjacent to the bulgelike feature may indicate that it represents a smaller-scale flexural high ("flexural welt") superposed over the cratonward edge of the larger-scale classical forebulge of the basin. Development of shallow-water reefs on the crest of the bulge during sea level lowstand, followed by migration of the bulge and widespread transgression, permitted growth of economically significant pinnacle reefs in the deep basin center. Further subsurface reef exploration should concentrate along the projected position of the bulge during the basal Onondaga lowstand.  相似文献   

Mineralogy and Geochemistry of Rural Road Dust and Nearby Mine Tailings: A Case of Ignored Pollution Hazard from an Abandoned Mining Site in Semi-arid Zone     

Del Rio-Salas  Rafael  Ayala-Ramírez  Yessi  Loredo-Portales  René  Romero  Francisco  Molina-Freaner  Francisco  Minjarez-Osorio  Christian  Pi-Puig  Teresa  Ochoa–Landín  Lucas  Moreno-Rodríguez  Verónica 《Natural Resources Research》2019,28(4):1485-1503

Natural Resources Research - Abandoned mine tailings are considered as one of the main sources of potentially toxic elements. Because of the lack of supervision, particularly from small-scale or...  相似文献   

Connections between whistlers and pulsation activity     

J. Verö  B. Zieger  J. Szendröi  M. Vellante  J. Střesgtik  H. Lühr  A. Best  A. Körmendi  J. Lichtenberger  T. Ménesi  P. Bencze  F. Märcz  V. Wesztergom 《Annales Geophysicae》2000,18(8):866-873

Simultaneous whistler records of one station and geomagnetic pulsation (Pc3) records at three stations were compared. In a previous study correlation was found between occurrence and L value of propagation/excitation for the two phenomena. The recently investigated simultaneous records have shown that the correlation is better on longer time scales (days) than on shorter ones (minutes), but the L values of the propagation of whistlers/excitation of pulsations are correlated, i.e. if whistlers propagate in higher latitude ducts, pulsations have periods longer than in the case when whistlers propagate in lower latitude ducts.  相似文献   

Das Erdstrom-Observatorium bei Nagycenk (Ungarn)     

Anton Ádám  Josef Verö 《Pure and Applied Geophysics》1958,39(1):126-151

Zusammenfassung Im ersten Teil des Artikels werden — nach einem kurzen geschichtlichen Rückblick — die Anlage und die technischen Einrichtungen des im IGJ bei Nagycenk (Ungarn) errichteten tellurischen Observatoriums dargelegt. Der zweite Teil beschäftigt sich mit der Bearbeitung der Registrierungen. Wir wollen in erster Richtung die Verteilung der Variationen von verschiedenen Perioden untersuchen, und wir ordneten deshalb, teils auf Grund der Gegebenheiten der Registrierungen, hauptsächlich aber der Untersuchung bei verschiedenen Typen wegen, die Variationen in 5, bzw.9 Klassen ein. Ausserdem führen wir die tellurischen Äquivalenten der magnetischen Phenomena (Bay, Sturm, usw) und die Grundlagen deren Einteilung an. Die Publikationen über Karakteristiken und Graphikons zweccks Erkennung der Eigenschaften der Variationen werden wir von Zeit zu Zeit forsetzen.

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Summary In the first part of the article the writers — after a brief historical note — acquaint with the question of the location of the telluric observatory, established during the IGY near Nagycenk (Hungary) and with its technical arrangements. The second part presents the preparation of the records. It was chiefly the distribution of the different periodic variations in our mind, and this is why we included the variations, partly based on the given conditions of the recording, but in first line on the examination of periods of the different types in 5, respectively in 9 classes. Moreover, we specify the telluric equivalents of magnetic phenomena (bay, storm, etc.) and the basic principles of the classification. We shall report periodically on the characterics and graphs concerning the feature of the variations.

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Evaluation of trenching,ground penetrating radar (GPR) and electrical resistivity tomography (ERT) for sinkhole characterization          下载免费PDF全文

Domingo Carbonel  Verónica Rodríguez  Francisco Gutiérrez  James P. McCalpin  Rogelio Linares  Carles Roqué  Mario Zarroca  Jesús Guerrero  Ira Sasowsky 《地球表面变化过程与地形》2014,39(2):214-227

This paper explores the suitability and advantages of combining the trenching technique with geophysical surveys [ground penetrating radar (GPR) and electrical resistivity tomography (ERT)] for sinkhole characterization in a mantled karst area. The approach is applied to two active sinkholes concealed by anthropogenic deposits and formed by contrasting subsidence mechanisms; collapse and sagging. The ERT section acquired across the collapse sinkhole images the clayey fill of the depression as an obvious low resistivity area, showing the approximate location of the sinkhole edges. Spatially dense GPR surveys provide information on the position of the boundaries of the concealed subsidence structures and their three‐dimensional (3D) internal geometry, revealing the dominant subsidence mechanism. We illustrate the impact of several factors on the quality of the GPR data such as sinkhole size, nominal frequency of the antennas, antenna shielding, and the presence of backfilled excavations and above‐surface objects. Trenches provided detailed information on the subsurface structure of the sinkhole, subsidence magnitude, partitioning of the strain, and the position of the sinkhole edges, especially when they are deep enough and excavated across the central sector and perpendicular to the boundaries. The stratigraphic and structural relationships observed in the trench were then used to infer the spatial evolution of the sinkholes (e.g. enlargement), their kinematic behavior (episodic versus progressive), and to differentiate discrete subsidence events and their associated magnitude. Numerical dates were used to estimate average subsidence rates and the recurrence of subsidence events. Such integrated data sets may be used as an objective basis to forecast the future behavior of potentially damaging sinkholes and to assess the associated hazard and risk. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Upstream waves and field line resonances: simultaneous presence and alternation in Pc3 pulsation events     

J. Verõ  H. Lühr  M. Vellante  I. Best  J. Střeštik  J. Cz. Miletits  L. Holló  J. Szendrõi  B. Zieger 《Annales Geophysicae》1997,16(1):34-48

Based on a detailed study of Pc3 events at an array between L = 1.5 and 3 in Central Europe, the authors found quick changes between upstream waves (UW, i.e. pulsation directly driven by UW) and field line resonance (FLR, i.e. azimuthal oscillations of geomagnetic field lines). The alternation of the two types is especially characteristic (and the UW part stronger) if the interplanetary magnetic field (IMF) is highly variable. Events due to field line resonance may have a structure consisting of multiple lines with frequencies differing by about 10%, corresponding to neighbouring shells of field lines separated by about 100 km at the surface. This coincides with previous findings (about 10% at a meridional distance of 80 km). The frequency of the UW type is well correlated with the frequency of waves in the interplanetary medium. Additionally, there are signals of unidentified origin which also seem to be influenced by IMF.  相似文献