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The anodic stripping voltammetry with physically-coating mercury film electrode was used to investigate the complexing action of trace heavy metals in seawater with organic ligands. The apparent copper complexing capacity of seawater was determined by titrating the organic ligands in natural seawater with standard ionic copper solution. The complexing actions of copper in seawater with humic acid (HA) or fulvic acid (FA) were investigated by titrating copper in seawater with HA or FA solution. The equilibrium time, electrodeposition potential, and effect of pH etc. were investigated respectively. The results show that the interaction of copper in seawater with organic matter is a fast process. At natural pH, HA or FA tend to act with copper in seawater to form nonlabile complexes. During experimental electrode process, these complexes did not significantly dissociate. The experimental results were calculated according to 1∶1 complex formation.  相似文献   
34.
The accuracy of the AE index as a measure of the joule heat production rate is examined for a typical substorm event on 18 March 1978 by estimating the global joule heat production rate, as a function of time, using data obtained from the IMS six meridian chains. In spite of the fact that the AE index had had an initial slow growth which was followed by a rapid growth, the joule heat production rate attained a high level during the slow growth and thus their variations were considerably different from those of the AE index. Therefore, although the AE index is statistically linearly related to the global joule heat production rate, one should be cautious in assuming that details of time variations of the AE index during individual events represent those of the joule heat production rate.  相似文献   
35.
Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH4). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
36.
严格论证了在对空间或地面目标的定位中,利用伪距测量观测模型的几何因子大于用台站间一次差分观测模型的几何因子.此外,台站间完全差分测量观测的定位精度优于不完全测量情形的定位精度.这些结果给人们在实际工作中采取何种定位方式提供了可靠的理论依据.  相似文献   
37.
通过对中国东部金成矿区域地质特征的分析,根据氢氧同位素及流体包裹体数据特征,表明中国东部金矿床成矿流体主要来自大气降水,其次为变质作用过程释放的水和岩浆分异水;成矿金属组分主要来自太古宙变质岩系。  相似文献   
38.
We present the new solar radiospectrograph of the University of Athensoperating at the Thermopylae Station since 1996. Observations cover thefrequency range from 110 to 688 MHz. The radiospectrograph has a 7-meterparabolic antenna and two receivers operating in parallel. One is a sweepfrequency receiver and the other a multichannel acousto-optical receiver.The data acquisition system consists of a front-end VME based subsystem anda Sun Sparc-5 workstation connected through Ethernet. The two subsystems areoperated using the VxWorks real-time package. The daily operation is fullyautomated: pointing of the antenna to the sun, starting and stopping theobservations at pre-set times, data acquisition, data compression by`silence suppression', and archiving on DAT tapes. The instrument can beused either by itself to study the onset and evolution of solar radio bursts or in conjunction with other instruments including theNançay Decametric Array and the WIND/WAVES RAD1 and RAD2 low frequencyreceivers to study associated interplanetary phenomena.  相似文献   
39.
THECONSTRUCTIONANDITSDEVELOPMENTOFTHEOVERSEASTRANSPORTSYSTEMINNORTHEASTCHINAGaoShali(高莎丽)(DepartmentofGeography,NortheastNorm...  相似文献   
40.
Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 106 tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002  相似文献   
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