土壤中氟的形态分析   总被引：11，自引：3，他引：8  

桂建业  韩占涛  张向阳  刘福亮 《岩矿测试》2008,27(4):284-286

以宁夏盐池地区高氟土壤为例,采用连续提取法对土壤样品中各形态氟进行提取,离子色谱法测定各形态氟的含量。根据研究目的及土壤特点将氟的形态划分为水溶态、离子交换态、可还原态、可氧化态及残渣态5种形态;对各种形态连续提取过程中使用的提取液进行了选择。采用建立的方法获得提取土壤中F-的检出限为0.76μg/g;方法精密度(RSD,n=7)各形态氟为水溶态氟11.3%,离子交换态氟13.5%,可还原态氟10.7%,可氧化态氟8.9%。  相似文献   

An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting   总被引：1，自引：0，他引：1  

Mauro Lo Cascio  Yan Liang  Nobumichi Shimizu  Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Simple models for dynamic melting in an upwelling heterogeneous mantle column: Analytical solutions     

Yan Liang 《Geochimica et cosmochimica acta》2008,72(15):3804-3821

Several lines of evidence suggest that the melt generation and segregation regions of the mantle are heterogeneous, consisting of chemically and lithologically distinct domains of variable size and dimension. Partial melting of such heterogeneous mantle source regions gives rise to a diverse range of basaltic magmas. In order to better assess the role of source heterogeneity during mantle melting, we have undertaken a theoretical study of trace element distribution and fractionation during concurrent melting and melt migration in an upwelling, chemically heterogeneous, two-porosity double lithology melting column. Analytical solutions for the abundance of a trace element in the matrix and channel were obtained under the assumptions that the porosity, melt and solid velocities, and solid-melt partition coefficients are constant and uniform. For simplicity, we neglected diffusion and dispersion in the melt. Chemical source heterogeneities of arbitrary size and shape were integrated into the simple melting models by allowing trace element abundance in the source region to vary as a function of time and space. Concurrent melting and melt migration in an upwelling heterogeneous mantle may be approximated as a quasi-steady state problem in which time-dependent concentration patterns produced by melting of heterogeneous source regions are superimposed on a reference steady-state concentration distribution established by melting of the ambient or background mantle. Chromatographic fractionation is especially important for the matrix melt and solid when chemical heterogeneities are involved during melting and melt migration in the mantle, giving rise to significant phase-shift between two incompatible trace elements in the matrix melt and scattered correlations among incompatible trace elements in residual peridotites. Mixing is the chief mass transfer process in the dunite channel where the chromatographic effect is negligible for most of the incompatible trace elements. The lack of chromatographic fractionation among incompatible trace elements and isotopic ratios in MORB suggests either most MORB are channel melts or mixing in magma conduit and chamber is very efficient such that the phase-shift is averaged out during magma transport and storage processes. Advection brings melt produced by smaller-degree of melting in the deeper part of the melting column to the overlying melting region, increasing the incompatible trace element abundance in the matrix and the channel. This advection-induced self-enrichment is especially important when heterogeneous sources are involved and may account for some of the enriched incompatible trace element patterns observed in residual peridotite that were previously interpreted to be a result of mantle metasomatism. Systematic studies of high-resolution spatially correlated mantle samples may help to constrain the melting history and the size and nature of chemical heterogeneities in the mantle.  相似文献   

浙西南淡竹花岗闪长岩中锆石的成因研究及其地质意义   总被引：11，自引：0，他引：11  

汪相  陈洁  罗丹 《地质论评》2008,54(3):387-398

本文对浙西南地区淡竹花岗闪长岩中的锆石群进行了形态学、地球化学和年代学的系统研究。研究结果表明, 该花岗闪长岩中存在两种不同类型的锆石: 岩浆锆石和变质锆石。前者为自形—半自形的长柱状晶体, 无色透明, 富含岩浆和矿物包裹体, 其背散射电子图像 (BSE图像) 显示出均匀的内部构造 (少数具有韵律环带构造), 其晶型指数落在钙碱性系列花岗闪长岩的范围内; 后者大多数以增生边的形式围绕岩浆锆石生长, 极少量呈他形的粒状晶体, 呈黄褐色—半透明, 其BSE图像亦呈现均匀的内部构造。这两类锆石在化学成分上有较大的差异, 表现为岩浆锆石比变质锆石明显地富U、Th、Y等阳离子置换元素。锆石LAICPMS UPb定年分析结果表明, 岩浆锆石和变质锆石分别形成于1875±33 Ma和209±12 Ma两个不同的时代, 为浙闽运动和印支运动在浙西南地区的表现提供了有力的客观证据。  相似文献   

晚三叠世松潘甘孜和川西前陆盆地的物源对比：构造演化和古地理变迁的线索   总被引：3，自引：0，他引：3  

邓飞  贾东  罗良  李海滨  李一泉  武龙 《地质论评》2008,54(4):561-573

为了研究龙门山褶皱冲断带两侧的松潘甘孜和川西前陆盆地在大地构造和沉积学方面存在的联系,笔者等分别在松潘甘孜东缘马尔康—理县地区和川西前陆盆地都江堰地区进行了采样和碎屑锆石的LAICPMS UPb定年工作。269颗锆石的定年结果显示,中—晚三叠世拉丁期—诺利期松潘甘孜复理石盆地东缘沉积地层中的碎屑锆石年龄主要集中在250~280 Ma、1800~1900 Ma和2400~2500 Ma、200~245 Ma、400~450 Ma,对应的物源主要为东昆仑岛弧、华北陆块基底、义敦岛弧以及北秦岭。与之相比,川西前陆盆地诺利期—瑞替期的须家河组地层中的碎屑锆石年龄大致主要集中在1800~1900 Ma和2400~2500 Ma、720~850 Ma、950~1200 Ma、400~450 Ma。该统计结果总体上继承了松潘甘孜数据体的特征,揭示出须家河组物源来自西部——松潘甘孜褶皱带的再旋回沉积和龙门山前陆冲断带。  相似文献   

南海西部海域新生代构造古地理演化及其对油气勘探的意义   总被引：6，自引：2，他引：4       下载免费PDF全文

谢锦龙  黄冲  向峰云 《地质科学》2008,43(1):133-153

南海西部海域构造复杂,主要发育有北东—北东东向、北西向和近南北向3组深大断裂。其中,北西向断裂与板块汇聚、碰撞有关,多具走滑性质;北东—北东东向断裂具有与中国东部裂谷盆地相似的发育特点,呈张扭性质;近南北向断裂可能是南海在扩张活动期间于洋、陆壳过渡部位形成的走滑调节断裂,是洋盆扩张的西部边界。新生代里,南海经历了4次成盆事件与3期扩张活动,盆地经历了古新世—中始新世陆缘断陷、渐新世—早中新世扩展与中中新世以来的热沉降3个演化阶段。陆缘断陷阶段的充填系列主要是北东—北东东向与北西向的河流—冲积扇、湖泊沼泽等陆相沉积及火山岩等;盆地扩展阶段表现为中-小型断陷、断-坳陷逐渐复合与联合为大-中型坳陷,古地理格局逐渐由河流与湖沼陆相环境演变为滨海至浅海相的沉积环境;热沉降阶段的成盆活动逐渐减弱以至停止,地层表现超覆,盆地出现联合迹象。结合以往勘探与油气资源调查成果分析,认为南海西部海域陆架陆坡区发育的大-中型沉积盆地石油地质条件良好,蕴藏着丰富的油气资源,勘探潜力巨大。  相似文献   

祁连山近期七一冰川融水径流特征分析   总被引：3，自引：1，他引：2  

宋高举  王宁练  陈亮  贺建桥  蒋熹  武小波 《冰川冻土》2008,30(2):321-328

利用2006年8月1日-9月30日的实测水文数据,对"七一"冰川融水径流产汇流特征进行了分析,并揭示出该冰川日消融特征.通过对冰川融水量的估算以及径流模数的计算,并与过去的观测结果进行对比,表明近些年来"七一"冰川消融强度和消融量都在增大,而且2006年消融量为近几年观测的最大值.虽然不同年份消融量不一样,但"七一"冰川总的趋势是一直处于萎缩状态,随着全球变暖,"七一"冰川的萎缩可能将继续下去.通过对设立在沿冰川下游方向两个不同的水文断面进行对比分析,结果表明"七一"冰川融水径流在向下游运动过程中有部分水入渗为河谷潜流,观测期内两个相距不到2 km的水文断面间渗漏损耗占近1/3左右.  相似文献   

中国大别山东南缘首次发现大坝陨坑构造   总被引：2，自引：0，他引：2  

向缉熙  许林根  向钒  石乾华吴思本  张新元张宜勇 《中国地质》2008,35(5):869-878

简介首次在大别山东南缘安徽省境内发现的大坝陨坑构造。经初步评价,知陨坑呈椭圆形,长轴呈北北东向,长约19km,短轴长约12km,最大坑深约2km,是一个有中央隆起区的复杂型陨坑。在卫片上陨坑显示环形影像,地貌形态为一洼地。陨坑基座保存尚好,可对它直观和追索陨坑构造边界。形成于230Ma左右的各类撞击变质岩石系列齐全,其中含有柯石英等典型的撞击变质矿物及撞击碎理等超微构造,特别是在陨坑基座内壁普遍发现有鉴别陨坑构造最可靠的标志——干裂自角砾岩,都证明大坝环形影像是一个典型的陨星撞击坑构造。它的发现,具有很大的科学及经济意义,对今后褶皱山区寻找和研究陨坑构造具有示范和指导作用,同时大大丰富了建设大别山世界地质公园的地质依据。无庸置疑此发现将促进大别山旅游业的发展及陨星撞击科普知识的传播。  相似文献   

川西108国道高位崩塌成因与运动特征   总被引：2，自引：0，他引：2  

胥良  李云贵  刘艳梅 《水文地质工程地质》2008,35(3):28-31

2007年5月25日于川西108国道某段发生的高位崩塌造成了重大人员伤亡和财产损失。综合地质调查、三维激光扫描技术、爆破振动效应分析以及历史崩塌与降雨关系的统计分析,得出了地形高陡、岩体破碎及降雨诱发等是崩塌产生的主要原因,爆破振动对其也有轻微间接影响。根据边坡形态及塌落高度,运用运动学原理及能量法还对崩塌体的撞击速度及冲击力进行了计算分析。  相似文献   

基于泡沫钻进中消泡装置的试验研究     

徐良  孙友宏 《探矿工程》2008,35(6):5-7

泡沫钻进过程中,会产生很多泡沫,如不及时清除,会造成施工现场泡沫的大量堆积,影响正常的生产。因此,选择合适的消泡方法在泡沫钻进过程中是非常重要的环节。选用机械消泡法中的缝隙式消泡器,建立消泡装置室内试验台进行试验,取得了良好的效果,消泡率可达86%。  相似文献