Occurrence modes and cleaning potential of sulfur and some trace elements in a high-sulfur coal from Pu’an coalfield,SW Guizhou,China     

Wei Cheng  Qin Zhang  Ruidong Yang  Yingzhong Tian 《Environmental Earth Sciences》2014,72(1):35-46

In this research, a float-sink test was applied to a Late Permian high-sulfur coal collected from Pu’an coalfield, Southwest in Guizhou, China. To investigate the occurrence modes and the mobility of various trace elements, as well as the cleaning potential of some harmful elements in density separation, coal quality parameters and concentrations of 46 elements of 7 density fractionated samples were determined and statistically analyzed. Results show that larger size and higher density fractions have higher total sulfur content and ash yield than the smaller and lower ones. In fact, most (74.39 %) of the total sulfur occurs in the inorganic matter. Affinity and correlation analysis show that Mo and Ni have apparently strong organic affinity, whereas Rh, Cs, Sr, Co, Nb, Zr, V, Ga, Sc, Be, Ge, Hf, Th, U, Ag, As, In, Cu, Cd, Ta, Li, TI, and Ba are mostly in the heavy fractions. Rare earth element (REE) patterns for the seven density fractions present good uniformity and show that they are of right-inclined pattern type characterized by Light REE (LREE, La ~ Eu) enrichment relative to Heavy REE (HREE, Gd ~ Lu) and pronounced negative δ _Eu anomalies. This suggests that REE was mainly derived from basalt-weathered materials. LRREE/HREE ratio variations reveal that LREE has stronger affinity with the organic matter relative to the HREE, while high LRREE/HREE in heavy fractions may be related to pyrite. Supposing the maximum sulfur content of the cleaned coal is 1.00 %, the theoretical removal ratios of Co, TI, and Ba are as high as 90.94, 93.73, and 92.29 %, respectively, while those of As, Ni and Mo are only 56.33, 48.85, and 45.05 %, respectively. As these figures change with different maximum sulfur contents required for the cleaned coal, not only the decrease of sulfur and ash in coal washing, but also the mobility of some harmful trace elements should be taken into consideration.  相似文献   

A Comparison of Modified Fuzzy Weights of Evidence,Fuzzy Weights of Evidence,and Logistic Regression for Mapping Mineral Prospectivity     

Daojun Zhang  Frits Agterberg  Qiuming Cheng  Renguang Zuo 《Mathematical Geosciences》2014,46(7):869-885

Weights of evidence and logistic regression are two of the most popular methods for mapping mineral prospectivity. The logistic regression model always produces unbiased estimates, whether or not the evidence variables are conditionally independent with respect to the target variable, while the weights of evidence model features an easy to explain and implement modeling process. It has been shown that there exists a model combining weights of evidence and logistic regression that has both of these advantages. In this study, three models consisting of modified fuzzy weights of evidence, fuzzy weights of evidence, and logistic regression are compared with each other for mapping mineral prospectivity. The modified fuzzy weights of the evidence model retains the advantages of both the fuzzy weights of the evidence model and the logistic regression model; the advantages being (1) the predicted number of deposits estimated by the modified fuzzy weights of evidence model is nearly equal to that of the logistic regression model, and (2) it can deal with missing data. This method is shown to be an effective tool for mapping iron prospectivity in Fujian Province, China.  相似文献   

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China     

A‐Juan Pang  Sheng‐Rong Li  M. Santosh  Qing‐Yu Yang  Bao‐Jian Jia  Cheng‐Dong Yang 《Geological Journal》2014,49(1):52-68

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

华北地台南缘霍邱安阳山地区八公山群地层时代归属（青白口纪）：来自碎屑锆石年代学的制约   总被引：2，自引：0，他引：2       下载免费PDF全文

李双应  程成  王松  彭亮  稽在飞  杨栋栋 《地质科学》2014,(2):608-617

分布于华北地台南缘,霍邱-固始交界安阳山地区的八公山群,由一套碎屑岩和碳酸盐岩组成。最近,人们在碳酸盐岩中发现、珊瑚等化石,确定灰岩时代为晚石炭世。但是,碎屑岩的地质时代仍然没有定论。碎屑岩由粉砂质泥岩、石英砂岩、粉砂岩等组成,厚度大于780 m。石英砂岩为中-厚层状,中细粒结构,成分成熟度和结构成熟度高,石英含量高达95%以上,属于滨海-陆棚沉积。应用LA-ICP-MS对石英砂岩中碎屑锆石U-Pb年代学研究表明,样品HQ2106和HQ2204最年轻的碎屑锆石U-Pb年龄分别为860±22.2 Ma（YSG）,877±22.6 Ma（YSG）,前者代表了地层的最大沉积年龄,它们也得到锆石年龄加权平均值（YC1σ和YC2σ）的支持。因此,研究区八公山群碎屑岩地层时代属于青白口纪（拉伸纪）。该研究结果将为华北地台南缘前寒武纪地层划分对比以及构造演化历史重塑提供重要依据。  相似文献   

卫星热红外遥感技术在火山区地热探测中的应用——以内蒙古锡林郭勒火山区为例   总被引：1，自引：0，他引：1       下载免费PDF全文

彭芬  黄少鹏  时庆金  程玉祥  荆勇河 《地质科学》2014,(3):899-914

能源的全球性短缺以及全球环境问题的日益加剧,使得绿色新能源的研究与开发成为当今世界许多国家的一项重要任务。地热资源作为其中一员其重要性日益凸显。在地热资源的勘查中,传统的地质和地球物理勘探投入高、难度大,而遥感技术具有经济、高效、覆盖范围广等优势,已逐渐成为地热资源探测与调查的一种新技术手段。地热能开发的首选地区往往是新生代火山活动区,因其在相对较小的深度内就能获得很高的温度。本文综述了国内外利用遥感技术探测火山地热的发展历史和研究现状,介绍了这项技术在美国黄石公园、日本阿苏火山以及我国长白山火山和腾冲火山的应用。同时选取内蒙古锡林郭勒盟新生代火山活动构造区作为实例,利用美国NASA陆地卫星Landsat-7 ETM+第6波段的红外遥感数据反演了研究区的地表温度,结合ETM+7-4-1波段组合影像的地质构造解译结果以及其它相关资料对研究区地表温度分布进行了分析。结果表明,区内红外遥感地表温度异常区多位于北东东与北西向构造的交汇处或与环形构造密切相关。本文圈定了7个地表温度异常区作为这一地区下一步地热资源勘查的远景区。  相似文献   

An Experimental Study of Crack Coalescence Behaviour in Rock-Like Materials Containing Multiple Flaws Under Uniaxial Compression   总被引：4，自引：1，他引：3  

X. P. Zhou  H. Cheng  Y. F. Feng 《Rock Mechanics and Rock Engineering》2014,47(6):1961-1986

Experiments on man-made flawed rock-like materials are applied extensively to study the mechanical behaviour of rock masses as well as crack initiation modes and crack coalescence types. A large number of experiments on specimens containing two or three pre-existing flaws were previously conducted. In the present work, experiments on rock-like materials (formed from a mixture of sand, plaster, limestone and water at mass ratio of 126:9:9:16) containing multiple flaws subjected to uniaxial compression were conducted to further research the effects of the layout of pre-existing flaws on mechanical properties, crack initiation modes and crack coalescence types. Compared with previous experiments in which only three types of cracks were found, the present experiments on specimens containing multiple flaws under uniaxial compression revealed five types of cracks, including wing cracks, quasi-coplanar secondary cracks, oblique secondary cracks, out-of-plane tensile cracks and out-of-plane shear cracks. Ten types of crack coalescence occurred through linkage among wing cracks, quasi-coplanar secondary cracks, oblique secondary cracks, out-of-plane shear cracks and out-of-plane tensile cracks. Moreover, the effects of the non-overlapping length and flaw angle on the complete stress–strain curves, the stress of crack initiation, the peak strength, the peak strain and the elastic modulus were also investigated in detail.  相似文献   

Characteristics of gas disaster in the Huaibei coalfield and its control and development technologies     

Liang Wang  Yuan-ping Cheng  Feng-hua An  Hong-xing Zhou  Sheng-li Kong  Wei Wang 《Natural Hazards》2014,71(1):85-107

The Huaibei coalfield is in the East China Economic Area, which is rich in coal and gas resources. However, hundreds of coal and gas outburst accidents have occurred because of the complex geological structures of the coalfield. Based on theoretical analysis and field statistics, the characteristics of regional geological structures and the coal measure strata evolution in the Huaibei coalfield were researched, and gas resource distribution and gas parameters were statistically analyzed to determine the dominant controlling factors of gas occurrence and gas dynamic disaster. The results indicated that the Huaibei coalfield has undergone complex tectonic evolution, causing obvious differences in gas storage in different blocks of different mining areas, which exhibits a pattern of high amounts of gas in the south and east, and low amounts of gas in the north and west. The coal seam and gas occurrence have a bipolar distribution in the coalfield caused by multiple tectonic movements, and they are deeply buried. Horizontal tectonic stress plays a dominant role in gas outburst, and the thermal evolution and trap effects of magma intrusion increase the possibility and extent of gas outburst. Considering coal seam and gas occurrence characteristics in the coalfield, we propose a new technology for deep coal reservoir reconstruction which combined present underground regional gas control methods and surface well extraction methods. The technology has three effects: developing gas resources, improving coal mining safety level and reducing greenhouse gas emissions, which has been practiced to be effective in coal mines in the Huaibei coalfield.  相似文献   

Application of in-seam directional drilling technology for gas drainage with benefits to gas outburst control and greenhouse gas reductions in Daning coal mine,China     

Shouqing Lu  Yuanping Cheng  Jinmin Ma  Yuebing Zhang 《Natural Hazards》2014,73(3):1419-1437

Gas outburst disasters are becoming more serious as the underground coal mines become deeper in China, and a thick zone of deformed coal provides conditions favorable to coal and gas outbursts. The Daning coal mine’s main mining seam is the No. 3 coal seam with coal and gas outburst hazard, which often contains two normal coal sub-layers and one deformed sub-layer. Considering both the geological conditions of the coal seam and applications of the in-seam directional longhole drilling technology, a new schematic diagram of in-seam directional longholes for gas drainage is developed. The two borehole layout models of longwall panel and main entries for gas outburst disasters control have been successfully applied. The gas drainage rates of both models are >70 %, and the residual gas contents are both <8 m³/t, which can be considered that the gas outburst disasters were effectively controlled. To better guide gas drainage, gas drainage normal and failure modes have been obtained. Although in-seam directional longhole technology has been successfully applied for regional gas drainage with benefits to gas outburst control, there are also some problems that are detrimental to greenhouse gas reductions in gas drainage and gas utilization. The three main problems are air leakage failure in gas drainage, decreasing gas concentration and a low gas utilization ratio. To address the problems mentioned above, five improvements are suggested.  相似文献   

安徽沙溪斑岩型铜金矿床成岩序列及成岩成矿年代学研究   总被引：10，自引：7，他引：3  

王世伟  周涛发  袁峰  范裕  俞沧海  葛岭虹  石诚  池月余 《岩石学报》2014,30(4):979-994

沙溪矿床是长江中下游成矿带中典型的斑岩型铜金矿床,位于庐枞盆地北外缘、郯庐断裂内,矿床成岩成矿时代确定对该矿床成因研究及区域成矿规律的认识具有重要意义。在详细野外地质工作的基础上,采集沙溪矿床与成矿有关的主要岩浆岩样品(粗斑闪长玢岩、黑云母石英闪长玢岩、中斑石英闪长玢岩、细斑石英闪长玢岩和闪长玢岩)和与黄铜矿密切共生的辉钼矿,分别利用Cameca、LA-ICP-MS U-Pb和Re-Os同位素定年方法,获得矿床内主要岩浆岩的成岩年龄(130.60±0.97Ma、129.30±1.00Ma、127.10±1.50Ma、129.46±0.97Ma和126.7±2.1Ma)以及成矿年龄(130.0±1.0Ma),并重新厘定了沙溪岩体从早到晚岩浆的侵位序列。通过区域对比,提出长江中下游存在两阶段斑岩型铜金矿化,沙溪矿床为长江中下游成矿带第二阶段形成的斑岩型矿床,沙溪矿床的成岩成矿作用既不同于庐枞盆地,也不同于断隆区第一阶段的斑岩矿床,而是受郯庐断裂和长江断裂动力学演化联合作用的产物。  相似文献   

中国萤石矿床分类   总被引：7，自引：0，他引：7       下载免费PDF全文

王吉平商朋强  熊先孝杨辉艳 唐尧 《中国地质》2014,41(2):315-325

通过对中国萤石矿床的成矿作用研究,综合考虑萤石矿床的成因类型和工业类型,将中国萤石矿床划分为沉积改造型、热液充填型和伴生型3种矿床类型。在全面分析萤石矿典型矿床的成矿条件、控矿因素和成矿作用的基础上,总结成矿要素,以相同或相似的二级成矿必要要素组合确定沉积改造型、热液充填型萤石矿床的亚类型,沉积改造型进一步划分出2个矿床式,热液充填型划分出5个矿床式,伴生型按伴生主矿种划分出4个矿床式。文章分析了每一个矿床式的成矿地质背景,成矿条件、矿床特征、控矿因素和成矿作用,总结了每一个矿床式的二级成矿必要要素。  相似文献