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41.
对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。 相似文献
42.
43.
使用中国科学院紫金山天文台青海站13.7米射电望远镜于1996年12月至1997年1月对富碳拱星IRC 10216和CIT6的CO J=1-0跃迁(115GHz)进行了观测。在观测谱线的基础上得到了IRC 10216的视向速度和膨胀速度分别为一26.1km s~(-1)和14.8km s~(-1),CIT6的视向速度和膨胀速度分别为0.6km s~(-1)和13.8kms~(-1)。并对望远镜的射束及指向精度进行了研究。 相似文献
44.
Abstract— Abundances and isotopic compositions of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite were measured. The abundance ratios of spallogenic components in metal reveal a 3He deficiency which is due to the diffusive loss of parent isotopes, that is, tritium (Tilles, 1963; Schultz, 1967). The diffusive loss likely has been induced by thermal heating by the Sun during cosmic‐ray exposure (~160 Ma; Lavielle et al, 1999). Thermal process such as impact‐induced partial loss may have affected the isotopic composition of spallogenic Ne. The 129Xe/131Xe ratio of cosmogenic components in the metal indicates an enhanced production of epi‐thermal neutrons. The abundance ratios of spallogenic components in the graphite reveal that it contained small amounts of metal and silicates. The isotopic composition of heavy noble gases in graphite itself was obtained from graphite treated with HF/HCl. The isotopic composition of the etched graphite shows that it contains two types of primordial Xe (i.e., Q‐Xe and El Taco Xe). The isotopic heterogeneity preserved in the Bohumilitz graphite indicates that the Bohumilitz graphite did not experience any high‐temperature event and, consequently, must have been emplaced into the metal at subsolidus temperatures. This situation is incompatible with an igneous model as well as the impact melting models for the IAB‐IIICD iron meteorites as proposed by Choi et al. (1995) and Wasson et al (1980). 相似文献
45.
In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series. 相似文献
46.
This work deals with the possible solution of the solar neutrino problem in the framework of the resonant neutrino spin-flavor precession scenario. The event rate results from the solar neutrino experiments as well as the recoil electron energy spectrum from SuperKamiokande are used to constrain the free parameters of the neutrino in this model (Δm2 and μν). We consider two kinds of magnetic profiles inside the sun. For both cases, a static and a twisting field are discussed. 相似文献
47.
48.
R. A.Street KeithHorne T. A.Lister A.Penny Y.Tsapras A.Quirrenbach N.Safizadeh J.Cooke D.Mitchell A.Collier Cameron 《Monthly notices of the Royal Astronomical Society》2002,330(3):737-754
We report on the discovery of 25 variable stars plus 13 suspected variables found in the field of the open cluster NGC 6819. The stars were identified from time-series photometric data obtained on the Isaac Newton Telescope, La Palma, during two observing runs covering the 19 nights between 1999 June 22–30 and 1999 July 22–31 . The variables found include 12 eclipsing binaries with an additional three suspected, nine BY Draconis systems, plus four variables of other types, including one star believed to be a Cepheid. Three of the 15 eclipsing binaries are believed to be cluster members. Details of a further 10 suspected variable stars are also included. 相似文献
49.
W. J. Chaplin G. Houdek Y. Elsworth D. O. Gough G. R. Isaak R. New 《Monthly notices of the Royal Astronomical Society》2005,360(3):859-868
We investigate the frequency dependence of the power spectral density of low-degree solar p modes by comparing measurements with the results of a stochastic-excitation model. In the past it was common practice to use the total power in such investigations. Using the maximum of the power spectral density instead provides a direct comparison with the measured mode heights in the observed power spectrum. This method permits a more careful calibration of the adjustable parameters in the excitation model, a model which we present here, for the first time, in a format that precisely and unambiguously relates the amplitudes of the modes of oscillation to the Reynolds stress in the equilibrium model. We find that errors in the theory of the linear mode damping rates, particularly at low frequency, have a dramatic impact on the predictions of the mode heights in the spectral density, whereas parameter changes in the stochastic excitation model, within a plausible domain of parameter space, have a comparatively small effect. 相似文献
50.
An improved approach is given for deriving the physical parameters of a molecular cloud by its NH3 rotation-inversion hyperfine spectra. The optical depth τ0(1, 1) of NH3 (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature Tex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature TR ( 2, 1) between the NH3 levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH3 (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH3 and para-NH3 are also discussed.
This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained. 相似文献