Determination of Uranium in Thirty-six Geological Reference Samples by Fluorimetry and Extractive Spectrophotometry     

Yutaka KANAI  Noboru IMAI  Shigeru TERASHIMA 《Geostandards and Geoanalytical Research》1986,10(1):73-76

The uranium contents of 36 geological reference samples have been determined by fluorimetry after ion-exchange separation, and spectrophotometry using Arsenazo III after solvent extraction with tri-n-octylphosphine oxide. The agreement between present results and published data is generally good. The methods of fluorimetry and spectrophotometry proved very convenient in the determination of uranium in geological materials.  相似文献   

Partitioning of elements between majorite garnet and melt and implications for petrogenesis of komatiite   总被引：5，自引：1，他引：5  

Eiji Ohtani  Iwao Kawabe  Junko Moriyama  Yoshihiko Nagata 《Contributions to Mineralogy and Petrology》1989,103(3):263-269

Partitioning of elements between majorite garnet and ultrabasic melt has been studied at 16 GPa and 1950° C. Ca, Ti, La, Sm, Gd, Zr, Hf, Fe, Ni, Mn, K, and Na are enriched in the melt, whereas Al, Cr, V, Sc and Yb are concentrated in majorite garnet. Thus, majorite garnet fractionation by partial melting could produce chemical heterogeneities in these elements deviating from chondritic abundance. Using the partitioning behaviour of elements between majorite garnet and ultrabasic melt, the petrogenesis of komatiite is discussed. A simple model to explain the chemical varieties of komatiites is as follows. Aluminadepleted komatiite was generated by partial melting of the primitive mantle at 200–650 km depth, and alumina-enriched komatiite is the product of remelting of the residual solid at the same depths, whereas alumina-undepleted komatiite was formed by partial melting of the primitive upper mantle at depths shallower than 200 km. We suggest the possibility of large-scale chemical layering or heterogeneity in the early Archean upper mantle as an alternative model for komatiite genesis; shallower mantle depleted in majorite garnet and the underlying mantle enriched in majorite garnet. Alumina-depleted and alumina-enriched komatiites in the early Archean might be generated by a high degree of partial melting of the layered mantle. Such chemical layering could have been homogenized by the late Archean. This explains the observations that alumina-depleted and alumina-enriched komatiites were generally formed in the early Archean but alumina-undepleted komatiite was erupted in the late Archean.  相似文献   

Heating and reconnection of the emerging magnetic flux-tubes and the role of the interchange instability     

Yutaka Uchida  Takashi Sakurai 《Solar physics》1977,51(2):413-429

We propose in the present paper that the basic behaviors of newly-emerged magnetic regions (NEMR) as seen in EUV and soft X-rays from space are interpreted by the interchange instability of the magnetic field of NEMR in the global situation surrounding it.It is shown that the situation with the NEMR is unstable against the interchange instability, and a continual relaxation to the lower energy state, or a continual invasion of the magnetic flux of the NEMR to the ambient region in the form of fine bundles or thin sheets, will take place in a short time scale of ₁ L/V _A following the change in the boundary condition at the photosphere. The second and the final relaxation is shown to be the enhanced Joule dissipation in a time scale of hours to several days occurring in the thin current sheets on the interface of this intermingled structure which is distributed in a large volume. This hypothesis may provide an explanation for the heating of NEMR to an X-ray emitting temperature, which is otherwise rather difficult to explain. The observed fast reconnection without appreciable flares (except for some smaller brightenings) is another aspect which can be explained in the present hypothesis. Namely, since the situation with the NEMR is unstable for the interchange from the beginning, the stressed configuration is relaxed before storing appreciable energy in the form of magnetic stress and therefore without a drastic release of a large amount of stored stress energy in the form of a flare.  相似文献   

Optimal placement of sensors on buildings subjected to intermediate‐storey excitation according to QN control method     

Liping Xing  Eizaburo Tachibana  Yutaka Inoue 《地震工程与结构动力学》2002,31(1):1-13

An algorithm to calculate direct velocity feedback gain with limited number of sensors is developed in a simple way such that a certain performance index is minimized according to QN control method. If a limited number of velocity outputs can be measured, full velocity responses of the whole structure can be interpolated based on the mode shapes. By defining the performance index function as a combination of the structure's velocity responses and control forces only, feedback gain can be determined according to QN control method with the external excitation being taken into account throughout the entire algorithm. Control forces are then regulated by the time‐invariant feedback gain matrix. The effective location of the active control devices for a building structure subjected to intermediate‐storey excitation has been determined to be in the three floors adjacent to the vibration source. Hence for the purpose of this paper, only the optimal placement of sensors is verified. It is shown in this paper that if the dynamic behaviour of the structure is well described by a mathematical model, sufficient response reduction effect can be achieved according to the new DVFC algorithm, and the degradation of control performance due to time delay can also be verified. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Audio frequency magneto-telluric survey of Norikura Volcano in central Japan     

Kiyoshi Fuji-ta  Yasuo Ogawa  Masahiro Ichiki  Satoru Yamaguchi  Yutaka Makino 《Journal of Volcanology and Geothermal Research》1999,90(3-4)

Norikura Volcano has not been active during the last 10,000 years in spite of the activity of the surrounding volcanic mountains. To study past volcanic activities, geological studies were carried out extensively. However, quite a few geophysical investigations were conducted to contribute to volcanology. Our objective is to detect the present subsurface structure of Norikura Volcano and to define volcanic stratifications. In the vicinity of Norikura Volcano, geothermal fields are still active. Subsurface volcanic rocks in this area have been exposed to geothermal activity and altered. To comprehend volcanic stratifications of Norikura and geothermal activity, we conducted audio frequency magneto-telluric (AMT) surveys around Norikura Volcano. AMT survey is useful in clearly defining the resistivity structure related to volcanic regions. The AMT data were acquired over a frequency range 10 Hz–10 kHz. Decomposition analysis was applied to the tensor impedance data. Subsequently, apparent resistivity and phase data were inverted using a two-dimensional magneto-telluric (MT) inversion and a model of Norikura was derived. The final model manifests that the surface resistors are in agreement with andesite lava or dacite lava. As for the deeper structure, a horizontal conductor is situated above resistive basements. The alteration of the conductor was weak, while basement rocks were strongly altered and/or heated through the thermal activity. The existence of these layers seems to indicate the degree of thermal activity of Norikura Volcano.  相似文献   

Overview of NOPACCS (Northwest Pacific Carbon Cycle Study)     

Hiroyuki Tsubota  Joji Ishizaka  Akira Nishimura  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):645-653

The Northwest Pacific Carbon Cycle Study (NOPACCS) was a program aimed at investigating the carbon cycle of the North Pacific Ocean, which can be thought of as a large reservoir of carbon dioxide. NOPACCS was also aimed at estimating the North Pacific's capacity as a carbon sink. Project design, scientific results, and data availability, and subsequent projects resulting from this project are also described in this review. Studies of the upper ocean processes focused on the latitudinal differences in the fugacity of carbon dioxide; and on the detail of plankton community structures. Intermediate water was studied in relation to the formation of North Pacific Intermediate Water and the amount of accumulated anthropogenic carbon. The sedimentation process, past carbon cycle and coral reefs were also studied during the project. A preliminary, overall view of the carbon cycle of the North Pacific was drawn from the results of the project and compared to global values.  相似文献   

Circulation patterns in the lower Arctic Ocean derived from geochemical data     

Motoyoshi Ikeda  Shinichi S. Tanaka  Yutaka W. Watanabe 《Journal of Oceanography》2018,74(5):453-470

Climatological water-mass structures were identified in the Arctic Ocean using the geochemical dataset in the Hydrochemical Atlas of the Arctic Ocean (HAAC) as well as data on a geochemically conserved parameter, PO₄*, based on phosphate and dissolved oxygen. In the upper ocean above a depth of 500 m, the HAAC was found to reliably depict the boundary between Pacific-Origin Water (P-Water) and Atlantic-Origin Water (A-Water), which is aligned 135°E–45°W near the surface but rotates counterclockwise with depth. Thus, the Arctic and Atlantic oceans exchange high-silicate P-Water and low-silicate A-Water. The PO₄* field in the lower ocean below a depth of 1500 m was analyzed statistically, and the results indicated that the Eurasian Basin receives low-PO₄* Nordic Seas Deep Water, which flows along the bottom from the Greenland Sea. The routes from the upper ocean to the lower ocean were determined. Only the southern portion of the Canada Basin, which receives water from the Chukchi and Beaufort Seas, has high PO₄* levels; the rest of the Amerasian Basin receives low-PO₄* water from the Laptev Sea and/or the Barents Sea. The Eurasian Basin receives moderate levels of PO₄* from the Fram Strait and from the intermediate layer. The intermediate-layer water gradually travels up from the lower ocean and returns to the Atlantic, entraining the subsurface portion. It is likely that high-PO₄* water occasionally flows down from the upper ocean along Greenland, making the Eurasian Basin heterogeneous.  相似文献   

Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin   总被引：1，自引：1，他引：0  

Alexey A. Krylov  Oleg M. Khlystov  Akihiro Hachikubo  Hirotsugu Minami  Yutaka Nunokawa  Hitoshi Shoji  Tamara I. Zemskaya  Lieven Naudts  Tatyana V. Pogodaeva  Masato Kida  Gennady V. Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):427-437

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.  相似文献   

Relationship between sinking organic matter and minerals in the shallow zone of the western Subarctic Pacific     

Masahito Shigemitsu  Yutaka W. Watanabe  Yasuhiro Yamanaka  Hajime Kawakami  Makio C. Honda 《Journal of Oceanography》2010,66(5):697-708

We used time-series sediment trap data for four major components, organic matter and ballast minerals (CaCO₃, opal, and lithogenic matter) from 150, 540, and 1000 m in the western subarctic Pacific (WSAP), where opal is the predominant mineral in sinking particles, to develop four simple models for settling particles, including the “ballast model”. The ballast model is based on the concept that most of the organic matter “rain” in the deep sea is carried by the minerals. These four models are designed to simultaneously reproduce the flux of each major component of settling particles at 540 and 1000 m by using the data for each component at 150 m as initial values. Among the four models, the ballast model, which considers the sinking velocity increase with depth, was identified as the best using the Akaike information criterion as a measure of the model fit to data. This model successfully reproduced the flux of organic matter at 540 and 1000 m, indicating that the ballast model concept works well in the shallow zone of the WSAP on a seasonal timescale. This also suggests that ballast minerals not only physically protect the organic matter from degradation during the settling process but also enhance the sinking velocity and reduce the degree of decomposition.  相似文献   

Sedimentary inorganic nitrogen and its isotope ratio in the western subarctic Pacific over the last 145 kyr   总被引：1，自引：0，他引：1  

Masahito Shigemitsu  Yutaka W. Watanabe  Hisashi Narita 《Journal of Oceanography》2009,65(4):541-548

We have measured inorganic nitrogen (IN) content and the isotope ratio of IN (δ¹⁵N_IN) in a sediment core covering the last 145 kyr in the western subarctic Pacific (WSAP). IN content was generally high during glacial periods and shows positive correlations with both eolian dust content and the ratio of organic carbon (C) to organic nitrogen (ON) (C/ON) found in our previous studies. This means that IN was transported from continental areas to the WSAP together with eolian dust and that the IN was not contaminated by volcanic materials, because the eolian dust content was reconstructed using metal components to remove contaminating volcanic materials. Therefore, IN content in the WSAP sediments, the clay fraction of which is not greatly affected by drift deposits seen at the other sites in this region, may potentially be an effective proxy for eolian dust, without the need to consider contamination by volcanic materials. δ¹⁵N_IN was generally low during glacial periods and shows negative correlations with IN, eolian dust, and C/ON. The possible causes of the observed variations in δ¹⁵N_IN are as follows: (1) authigenic fixation of NH₄ ⁺ in water-column and pore water of sea-floor sediments to clay minerals; (2) contamination of measured IN by highly resistant organic matter; or (3) variations in the continental source region of the eolian dust supplied to the WSAP and climatically induced changes in δ¹⁵N of soil organic matter there. The last mechanism shows the potential for δ¹⁵N_IN to be used as a proxy for climate change on land, and is consistent with other published explanations of the spatial distribution of δ¹⁵N_IN in modern sea-floor sediments.  相似文献