4414183 Phenolic chelate resin,process for producing the same,and method of recovering heavy metal ions with the same     

Akio Sasaki  Yoshiak Echigo 《Marine pollution bulletin》1984,15(3):121-122

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Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry     

Akio Makishima  Katsura Kobayashi  Eizo Nakamura 《Geostandards and Geoanalytical Research》2002,26(1):41-51

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.  相似文献   

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）     

Sato Minoru Oba Takashi Hosokawa Takao Yamaguchi Toshiyasu Nakano Toshiki Saito Tadao Muramoto Koji Kahara T akashi Funayama Katsura Kobayashi Akio Nakano Takahisa 《中国海洋大学学报(英文版)》2005,4(3):209-213

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.  相似文献   

Future Projections of Precipitation Characteristics in East Asia Simulated by the MRI CGCM2   总被引：7，自引：0，他引：7  

Akio KITOH  Masahiro HOSAKA  Yukimasa ADACHI  Kenji KAMIGUCHI 《大气科学进展》2005,22(4):467-478

Projected changes in precipitation characteristics around the mid-21st century and end-of-the-century are analyzed using the daily precipitation output of the 3-member ensemble Meteorological Research Institute global ocean-atmosphere coupled general circulation model (MRI-CGCM2) simulations under the Special Report on Emissions Scenarios (SRES) A2 and B2 scenarios. It is found that both the frequency and intensity increase in about 40% of the globe, while both the frequency and intensity decrease in about 20% of the globe. These numbers differ only a few percent from decade to decade of the 21st century and between the A2 and B2 scenarios. Over the rest of the globe (about one third), the precipitation frequency decreases but its intensity increases, suggesting a shift of precipitation distribution toward more intense events by global warming. South China is such a region where the summertime wet-day frequency decreases but the precipitation intensity increases. This is related to increased atmospheric moisture content due to global warming and an intensified and more westwardly extended North Pacific subtropical anticyclone, which may be related with an E1 Nin^-o-like mean sea surface temperature change. On the other hand, a decrease in summer precipitation is noted in North China, thus augmenting a south-to-north precipitation contrast more in the future.  相似文献   

Tidal Correction of Altimetric Data in the Japan Sea   总被引：2，自引：0，他引：2  

Akihiko Morimoto  Tetsuo Yanagi  Akio Kaneko 《Journal of Oceanography》2000,56(1):31-41

Satellite altimetric data have been very useful in the study of variation in the eddy field of the ocean. In order to investigate the variation in the eddy field, we have to remove tidal signals from altimetric data. However, global tidal models do not have sufficient accuracy in marginal seas such as the Japan Sea. In this study, we carried out harmonic analysis of temporal fluctuations of sea surface height data in the Japan Sea measured by TOPEX/POSEIDON. We could eliminate the tidal signals from altimetric data of TOPEX/POSEIDON and also from ERS-2 altimetric data with use of the harmonic constants derived from TOPEX/POSEIDON and tide gauge data along the coast. We draw co-tidal and co-range charts in the Japan Sea using the result of the harmonic analysis of TOPEX/POSEIDON altimetric data and tide gauge data along the coast. The results obtained turn out to be very useful for the tidal correction of altimetric data from satellite in the Japan Sea.  相似文献   

Eddy Field in the Japan Sea Derived from Satellite Altimetric Data   总被引：2，自引：0，他引：2  

Akihiko Morimoto  Tetsuo Yanagi  Akio Kaneko 《Journal of Oceanography》2000,56(4):449-462

The Japan Sea is one of the eddy-rich areas in the world. Many researchers have described the variability of the eddy field and its structure in the Tsushima Warm Current region. On the other hand, since there are few data covering the northern part of the Japan Sea, we are not able to understand the detailed variability of the eddy field there. The variation of the eddy field in the Japan Sea is investigated using the temporal fluctuations of sea surface height measured by altimetric data from TOPEX/POSEIDON and ERS-2. Tidal signals are eliminated from the altimetric data on the basis of the results of Morimoto et al. (2000). Distributions of sea surface dynamic height are produced by using the optimal interpolation method every month. The distributions warm and cold eddies that we obtained coincide well with the observed isotherms at 100 m depth measured by the Japan Sea National Fisheries Research Institute and the sea surface temperature measured by satellite. There are areas with high RMS variability of temporal fluctuation of sea surface dynamic height in the Yamato Basin, the Ulleung Basin, east of North Korea, the eastern part of the Yamato Rise, the Tsushima Strait and west of Hokkaido. The characteristics of eddy propagation in the high RMS variability regions are examined using a lag correlation analysis. Seasonal variations in the number of warm and cold eddies are also examined.  相似文献   

New radioisotope-free method for measuring bacterial production using [15N5]-2′-deoxyadenosine and liquid chromatography mass spectrometry (LC–MS) in aquatic environments     

Kenji Tsuchiya  Tomoharu Sano  Nobuyuki Kawasaki  Hideki Fukuda  Noriko Tomioka  Koji Hamasaki  Yuya Tada  Shinji Shimode  Tatsuki Toda  Akio Imai 《Journal of Oceanography》2015,71(6):675-683

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Future climate of the Caribbean from a super-high-resolution atmospheric general circulation model     

Trevor C. Hall  Andrea M. Sealy  Tannecia S. Stephenson  Shoji Kusunoki  Michael A. Taylor  A. Anthony Chen  Akio Kitoh 《Theoretical and Applied Climatology》2013,113(1-2):271-287

Present-day (1979–2003) and future (2075–2099) simulations of mean and extreme rainfall and temperature are examined using data from the Meteorological Research Institute super-high-resolution atmospheric general circulation model. Analyses are performed over the 20-km model grid for (1) a main Caribbean basin, (2) sub-regional zones, and (3) specific Caribbean islands. Though the model’s topography underestimates heights over the eastern Caribbean, it captures well the present-day spatial and temporal variations of seasonal and annual climates. Temperature underestimations range from 0.1 °C to 2 °C with respect to the Japanese Reanalysis and the Climatic Research Unit datasets. The model also captures fairly well sub-regional scale variations in the rainfall climatology. End-of-century projections under the Intergovernmental Panel on Climate Change SRES A1B scenario indicate declines in rainfall amounts by 10–20 % for most of the Caribbean during the early (May–July) and late (August–October) rainy seasons relative to the 1979–2003 baselines. The early dry season (November–January) is also projected to get wetter in the far north and south Caribbean by approximately 10 %. The model also projects a warming of 2–3 °C over the Caribbean region. Analysis of future climate extremes indicate a 5–10 % decrease in the simple daily precipitation intensity but no significant change in the number of consecutive dry days for Cuba, Jamaica, southern Bahamas, and Haiti. There is also indication that the number of hot days and nights will significantly increase over the main Caribbean basin.  相似文献   

Hayabusa‐returned sample curation in the Planetary Material Sample Curation Facility of JAXA     

Toru YADA  Akio FUJIMURA  Masanao ABE  Tomoki NAKAMURA  Takaaki NOGUCHI  Ryuji OKAZAKI  Keisuke NAGAO  Yukihiro ISHIBASHI  Kei SHIRAI  Michael E. ZOLENSKY  Scott SANDFORD  Tatsuaki OKADA  Masayuki UESUGI  Yuzuru KAROUJI  Maho OGAWA  Shogo YAKAME  Munetaka UENO  Toshifumi MUKAI  Makoto YOSHIKAWA  Junichiro KAWAGUCHI 《Meteoritics & planetary science》2014,49(2):135-153

Abstract– The Planetary Material Sample Curation Facility of JAXA (PMSCF/JAXA) was established in Sagamihara, Kanagawa, Japan, to curate planetary material samples returned from space in conditions of minimum terrestrial contaminants. The performances for the curation of Hayabusa‐returned samples had been checked with a series of comprehensive tests and rehearsals. After the Hayabusa spacecraft had accomplished a round‐trip flight to asteroid 25143 Itokawa and returned its reentry capsule to the Earth in June 2010, the reentry capsule was brought back to the PMSCF/JAXA and was put to a series of processes to extract recovered samples from Itokawa. The particles recovered from the sample catcher were analyzed by electron microscope, given their ID, grouped into four categories, and preserved in dimples on quartz slide glasses. Some fraction of them has been distributed for initial analyses at NASA, and will be distributed for international announcement of opportunity (AO), but a certain fraction of them will be preserved in vacuum for future analyses.  相似文献   

Investigation of cutting methods for small samples of Hayabusa and future sample return missions     

Masayuki Uesugi  Ryo Noguchi  Tooru Matsumoto  Junya Matsuno  Takashi Nagano  Akira Tsuchiyama  Shigenori Harada  Kaori Yokoyama  Yoshiaki Yodo  Noboru Takeda  Toru Yada  Shogo Yakame  Yuzuru Karouji  Yukihiro Ishibashi  Masanao Abe  Tatsuaki Okada  Akio Fujimura  Mitsuru Ebihara  Fumio Kitajima  Keisuke Nagao  Tomoki Nakamura  Hiroshi Naraoka  Takaaki Noguchi  Ryuji Okazaki  Hisayoshi Yurimoto 《Meteoritics & planetary science》2014,49(7):1186-1201

We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions.  相似文献