Using GIS and statistics to study influences of geology on probability features of surface soil geochemistry in Northern Ireland     

Crawford Jordan  Chaosheng Zhang  Alex Higgins 《Journal of Geochemical Exploration》2007

The probability features of non-normality and non-lognormality are widely observed in geochemistry due to the influences of multiple factors that are difficult to quantify and model. In Northern Ireland, the pseudo-total concentrations of 14 elements (Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb and Zn) from 6138 topsoils were measured, and GIS mapping showed that the spatial distribution of these data were in line with the spatial distribution of geology in the area. Investigations into the influences of geology on the concentration data and their probability features were carried out using GIS and statistics in this study. The whole raw data sets for each element were positively skewed and none of them followed either normal or lognormal distributions. Logarithmic transformation was found to have “over-transformed” most of the data sets, changing their skewness from positive to negative values. When soil samples were classified by rock type using a GIS overlay function, obvious differences were observed in the chemical concentrations of soils derived from different rock types. Soils in basalt areas displayed the highest concentrations for most elements under study (Ca, Co, Cr, Cu, Fe, Mg, Mn, Na, Ni, P and Zn) but the lowest concentrations for K, while the highest levels for Cd and Pb occurred in the shale areas. Classifying soils by rock type produced more normally distributed data sets, especially for the igneous rock areas. To restrain the influence of soil type and land cover, samples from both gleys and pastures were extracted via a GIS and it was found the data sets then showed generally greater tendencies towards normality. However, many of the data sets would still not pass a test for normality unless the sample size was small (e.g. of the order of a couple of hundreds). Geology, soil type, land cover and sample size all played important roles in determining soil chemical concentrations and their probability features. However, the influences from other factors were still evident. Attempts made in this study show that it remains a challenging task in geochemistry to separate all the factors and to model their influence at the regional scale.  相似文献   

Development and Implementation of a Bayesian-based Aquifer Vulnerability Assessment in Florida   总被引：4，自引：1，他引：4  

Jonathan D. Arthur  H. Alex R. Wood  Alan E. Baker  James R. Cichon  Gary L. Raines 《Natural Resources Research》2007,16(2):93-107

The Florida Aquifer Vulnerability Assessment (FAVA) was designed to provide a tool for environmental, regulatory, resource management, and planning professionals to facilitate protection of groundwater resources from surface sources of contamination. The FAVA project implements weights-of-evidence (WofE), a data-driven, Bayesian-probabilistic model to generate a series of maps reflecting relative aquifer vulnerability of Florida’s principal aquifer systems. The vulnerability assessment process, from project design to map implementation is described herein in reference to the Floridan aquifer system (FAS). The WofE model calculates weighted relationships between hydrogeologic data layers that influence aquifer vulnerability and ambient groundwater parameters in wells that reflect relative degrees of vulnerability. Statewide model input data layers (evidential themes) include soil hydraulic conductivity, density of karst features, thickness of aquifer confinement, and hydraulic head difference between the FAS and the watertable. Wells with median dissolved nitrogen concentrations exceeding statistically established thresholds serve as training points in the WofE model. The resulting vulnerability map (response theme) reflects classified posterior probabilities based on spatial relationships between the evidential themes and training points. The response theme is subjected to extensive sensitivity and validation testing. Among the model validation techniques is calculation of a response theme based on a different water-quality indicator of relative recharge or vulnerability: dissolved oxygen. Successful implementation of the FAVA maps was facilitated by the overall project design, which included a needs assessment and iterative technical advisory committee input and review. Ongoing programs to protect Florida’s springsheds have led to development of larger-scale WofE-based vulnerability assessments. Additional applications of the maps include land-use planning amendments and prioritization of land purchases to protect groundwater resources.  相似文献   

Validating tomographic model with broad-band waveform modelling: an example from the LA RISTRA transect in the southwestern United States   总被引：1，自引：0，他引：1  

Teh-Ru Alex Song  Don. V. Helmberger 《Geophysical Journal International》2007,171(1):244-258

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Multiple-Point Statistics for Training Image Selection   总被引：2，自引：0，他引：2  

Jeff B. Boisvert  Michael J. Pyrcz  Clayton V. Deutsch 《Natural Resources Research》2007,16(4):313-321

Selecting a training image (TI) that is representative of the target spatial phenomenon (reservoir, mineral deposit, soil type, etc.) is essential for an effective application of multiple-point statistics (MPS) simulation. It is often possible to narrow potential TIs to a general subset based on the available geological knowledge; however, this is largely subjective. A method is presented that compares the distribution of runs and the multiple-point density function from available exploration data and TIs. The difference in the MPS can be used to select the TI that is most representative of the data set. This tool may be applied to further narrow a suite of TIs for a more realistic model of spatial uncertainty. In addition, significant differences between the spatial statistics of local conditioning data and a TI may lead to artifacts in MPS. The utilization of this tool will identify contradictions between conditioning data and TIs. TI selection is demonstrated for a deepwater reservoir with 32 wells.  相似文献   

Estimation of fault-zone conductance by calibration of a regional groundwater flow model: Desert Hot Springs,California   总被引：1，自引：2，他引：1  

Alex Mayer  Wesley May  Chad Lukkarila  Jimmy Diehl 《Hydrogeology Journal》2007,15(6):1093-1106

The hydraulic conductance of a large fault zone has been estimated by calibrating a regional groundwater flow model. Drops in groundwater elevations of over 80 m have been observed along a 15-km length of the Mission Creek fault, California, USA. The large drops in elevation are attributed to the reduced hydraulic conductivity of the fault materials. A conceptual and numerical model of the two hydrologic subbasins in Desert Hot Springs, separated by the Mission Creek fault, was developed. The model was used to estimate the hydraulic conductance along the fault. The parameter estimation involved calibrating the model with observed groundwater elevations from over 40 locations over a 60-year period. The fault hydraulic conductances were estimated assuming a linear trend in the fault length, yielding variations in the fault hydraulic conductance of about an order of magnitude along the fault length (2?×?10^?11–4?×?10^?10 1/s). When an average fault thickness of 35 m is assumed, the fault hydraulic conductivity values are estimated to be from three to five orders of magnitude lower than the surrounding materials. A sensitivity analysis indicated that assumptions made in the conceptual model do not significantly affect estimated fault hydraulic conductances.  相似文献   

Zirconium isotope evidence for incomplete admixing of r-process components in the solar nebula     

Maria Schönbächler  Der-Chuen Lee  Alex N. Halliday  Bodo Hattendorf 《Earth and Planetary Science Letters》2003,216(4):467-481

Isotopic anomalies in Mo and Zr have recently been reported for bulk chondrites and iron meteorites and have been interpreted in terms of a primordial nucleosynthetic heterogeneity in the solar nebula. We report precise Zr isotopic measurements of carbonaceous, ordinary and enstatite chondrites, eucrites, mesosiderites and lunar rocks. All bulk rock samples yield isotopic compositions that are identical to the terrestrial standard within the analytical uncertainty. No anomalies in ⁹²Zr are found in any samples including high Nb/Zr eucrites and high and low Nb/Zr calcium-aluminum-rich inclusions (CAIs). These data are consistent with the most recent estimates of <10⁻⁴ for the initial ⁹²Nb/⁹³Nb of the solar system. There exists a trace of isotopic heterogeneity in the form of a small excess of r-process ⁹⁶Zr in some refractory CAIs and some metal-rich phases of Renazzo. A more striking enrichment in ⁹⁶Zr is found in acetic acid leachates of the Allende CV carbonaceous chondrite. These data indicate that the r- and s-process Zr components found in presolar grains were well mixed on a large scale prior to planetary accretion. However, some CAIs formed before mixing was complete, such that they were able to sample a population of r-process-enriched material. The maximum amount of additional r-process component that was added to the otherwise well-mixed Zr in the molecular cloud or disk corresponds to ∼0.01%.  相似文献   

Isotopic exchange of carbon-bound hydrogen over geologic timescales     

Alex L. Sessions  Sean P. Sylva  John M. Hayes 《Geochimica et cosmochimica acta》2004,68(7):1545-1559

The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50-100°C) exchange likely occurs on timescales of 10⁴ to 10⁸ yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (<1 Ma), cool sediments, but strong evidence for exchange in ancient (>350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity.Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D₂O indicate that the number of D atoms incorporated during structural rearrangements can be far less than the number of C-H bonds that are broken. Sample calculations indicate that, for steranes in immature sediments, the D/H ratio imparted by biosynthesis may be largely preserved in spite of significant structural changes.  相似文献   

Citation for presentation of the 2002 Clair C. Patterson Award to Henry Elderfield     

Alex N Halliday 《Geochimica et cosmochimica acta》2003,67(13):2309

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The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes     

Isabel Abad  Gabriel Gutirrez-Alonso  Fernando Nieto  Igor Gertner  Alex Becker  Ana Cabero 《Tectonophysics》2003,365(1-4):103

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.  相似文献   

Precise Determination of Cadmium, Indium and Tellurium Using Multiple Collector ICP-MS   总被引：1，自引：1，他引：0  

Wen Yi  Alex N. Halliday  Der-Chuen Lee  Mark Rehkämper 《Geostandards and Geoanalytical Research》1998,22(2):173-179

New sample preparation and ion-exchange separation methods as well as instrumental measurement protocols were established for the determination of trace-level Cd, In, and Te concentrations in geological materials by isotope-dilution mass spectrometry. High precision isotope ratio measurements were performed with a multiple collector inductively coupled plasma-mass spectrometer (MC-ICP-MS). The mass biases incurred for In and Te were corrected by adding and monitoring Pd and Sb standard solutions, respectively. Mass fractionation of Cd was corrected by using the mass fractionation factor calculated from the measurement of a standard solution. The measurement precision was better than 1 % for Cd, In and Te. Detection limits were < 1 ng g^-1 for Cd, < 0.02 ng g^-1 for In and Te. Using these new analytical techniques, the concentrations of Cd, In and Te were determined in six international geological reference materials. Concentrations could be reproduced within 3% for Cd, 4% for In and 10% for Te. Sample heterogeneity and volatility problems might have been the reason for the relatively large differences between Te replicates. Our results displayed excellent reproducibility compared with those of other techniques and agree well with data from previously published recommended values.  相似文献