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31.
An investigation was undertaken regarding the adsorption of different heavy metal ions from aqueous solutions using ??-diketone-functionalized styrene divinylbenzene resin under different experimental conditions such as initial concentration of metal ions, contact time, pH, and chelating capacity. The functionalization of resin was carried out by the condensation reaction of sodium salt of ??-diketones (pentane-1,3-dione) and chloromethylated styrene?Cdivinylbenzene resin in dichloromethane. Functionalized resin beads were characterized by Fourier transform infrared spectroscopy. The batch method was employed using different metal ions solution from 5 to 15?mg/L at different contact times. The adsorption kinetics was tested for the pseudo-first order, pseudo-second order reaction at different experimental conditions. The rate constant of adsorption kinetic models were also calculated and good correlation coefficient (R 2?>?0.9941) was obtained for pseudo-second order kinetic model. The maximum adsorption value obtain for lead (0.725728?mg/g), chromium (0.9199?mg/g), nickel (0.4974?mg/g), cobalt (0.6196?mg/g) and cadmium (0.6519?mg/g) at equilibrium condition, which shows that ??-diketone-functionalized styrene divinylbenzene resin is an effective adsorbent for toxic metal ions.  相似文献   
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On the planar motion in the full two-body problem with inertial symmetry   总被引:1,自引:0,他引:1  
Relative motion of binary asteroids, modeled as the full two-body planar problem, is studied, taking into account the shape and mass distribution of the bodies. Using the Lagrangian approach, the equations governing the motion are derived. The resulting system of four equations is nonlinear and coupled. These equations are solved numerically. In the particular case where the bodies have inertial symmetry, these equations can be reduced to a single equation, with small nonlinearity. The method of multiple scales is used to obtain a first-order solution for the reduced nonlinear equation. The solution is shown to be sufficient when compared with the numerical solution. Numerical results are provided for different example cases, including truncated-cone-shaped and peanut-shaped bodies.  相似文献   
34.
Source rock screening reveals five laterally extending potential sources (PS) in the Paleogene. The PSs are SR5 and SR6 in dominantly marine early Eocene to late Paleocene Cambay Shale formation, and SR7, SR8/9, and SR11/12 in dominantly freshwater early Paleocene Olpad formation. Only 3 PSs, SR11/12, SR8/9, and SR7 have attained vitrinite reflectance of 0.75% at 45, 7, and 2 mybp, respectively. Chromatographic and isotope data of oils and PS samples suggest that mainly the Olpad source rocks: SR7 and SR8/9 contributed to the discovered oils. The Cambay Shale source rocks, SR5 and SR6, contrary to the prevalent view, possibly have no significant contribution towards the accumulated oils.  相似文献   
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The Lonar impact crater, India, is one of the few known terrestrial impact craters excavated in continental basaltic target rocks (Deccan Traps, ~65 Ma). The impactites reported from the crater to date mainly include centimeter‐ to decimeter‐sized impact‐melt bombs, and aerodynamically shaped millimeter‐ and submillimeter‐sized impact spherules. They occur in situ within the ejecta around the crater rim and show schlieren structure. In contrast, non–in situ glassy objects, loosely strewn around the crater lake and in the ejecta around the crater rim do not show any schlieren structure. These non–in situ fragments appear to be similar to ancient bricks from the Daityasudan temple in the Lonar village. Synthesis of existing and new major and trace element data on the Lonar impact spherules show that (1) the target Lonar basalts incorporated into the spherules had undergone minimal preimpact alteration. Also, the paleosol layer as preserved between the top‐most target basalt flow and the ejecta blanket, even after the impact, was not a source component for the Lonar impactites, (2) the Archean basement below the Deccan traps were unlikely to have contributed material to the impactite parental melts, and (3) the impactor asteroid components (Cr, Co, Ni) were concentrated only within the submillimeter‐sized spherules. Two component mixing calculations using major oxides and Cr, Co, and Ni suggest that the Lonar impactor was a EH‐type chondrite with the submillimeter‐sized spherules containing ~6 wt% impactor components.  相似文献   
37.
A new method of analysis of piles in multi‐layered elastic soil subjected to a torque at the head is developed. The differential equation governing the angle of twist in the pile is derived using the variational principles of mechanics. The method of initial parameters is used to obtain closed‐form solutions of the angle of twist and torque in the pile as a function of depth. The inputs required for the analysis are shear moduli of pile and soil, pile geometry and thickness of soil layers. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
38.
The gravitational instability of an infinite homogeneous self-gravitating and infinitely conducting gas-particle medium is considered in the presence of suspended particles and a variable horizontal magnetic field varying in vertical direction. It is found that the Jeans's criterion of instability remains unaffected even if the effects due to suspended particles and variable horizontal magnetic field are included.  相似文献   
39.
Thermosolutal-convective instability of a stellar atmosphere is considered. The criteria for monotonic instability are derived. The effects of a variable horizontal magnetic field and the simultaneous presence of a uniform rotation and a uniform horizontal magnetic field have been considered on the thermosolutal-convective instability. The criteria derived for monotonic instability are found to hold good in the presence of a variable horizontal magnetic field as well as in the presence of a uniform rotation and a uniform horizontal magnetic field.  相似文献   
40.
Unit regional value (URV) and unit regional weight (URW) are relatively new concepts which are used to measure the intensity of the development of the mineral resources of any particular region. URV and URW of the mineral resources of India have been evaluated by sector, by commodity, as well as by state. The results are compared with values for the U.S.A. established by earlier workers and which can be taken as a standard for comparison with the mineral resources of other regions. URV of India, evaluated through the years 1898–1985, shows that the total mineral resources produced stands at $24.4 billion U.S. (deflated to 1967 value). Log URV of India lies below one standard deviation of the value for the states of the U.S. Like the U.S. India's major contribution to its URV is from fuels, but it is much less compared to that of the U.S. Next to fuels, metals, nonmetals, construction materials, and precious materials follow in that order. Except for two states, viz. Bihar and West Bengal, all other states are just below two standard deviations of the states of the U.S. The state of J&K is even much lower than the two standard deviations mark. It is concluded that India has a high potential for undiscovered mineral resources. However, this will require a large investment in exploration, on the order of Rs. 7760 crores, in the next few years.  相似文献   
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